Literature DB >> 31528878

Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.

John J Kiernicki1, Emily E Norwine1, Matthias Zeller2, Nathaniel K Szymczak1.   

Abstract

We present the preparation of a nitrogen-based bidentate ligand featuring an appended boron Lewis acid as well as its tetrahedral Fe2+ and Zn2+ complexes. These complexes act as platforms for hydrazine and hydroxylamine capture and reduction chemistry.

Entities:  

Year:  2019        PMID： 31528878      PMCID： PMC6776999          DOI： 10.1039/c9cc05720j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  27 in total

1.  Nitrite, a new substrate for nitrogenase.

Authors:  S A Vaughn; B K Burgess
Journal:  Biochemistry       Date:  1989-01-24       Impact factor: 3.162

2.  Modular Attachment of Appended Boron Lewis Acids to a Ruthenium Pincer Catalyst: Metal-Ligand Cooperativity Enables Selective Alkyne Hydrogenation.

Authors:  Kuei-Nin T Tseng; Jeff W Kampf; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2016-08-11       Impact factor: 15.419

3.  Hydrazine Capture and N-N Bond Cleavage at Iron Enabled by Flexible Appended Lewis Acids.

Authors:  John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2017-12-11       Impact factor: 15.419

4.  A T-Shaped Nickel(I) Metalloradical Species.

Authors:  Changho Yoo; Yunho Lee
Journal:  Angew Chem Int Ed Engl       Date:  2017-06-07       Impact factor: 15.336

5.  High-Resolution ENDOR Spectroscopy Combined with Quantum Chemical Calculations Reveals the Structure of Nitrogenase Janus Intermediate E4(4H).

Authors:  Veronika Hoeke; Laura Tociu; David A Case; Lance C Seefeldt; Simone Raugei; Brian M Hoffman
Journal:  J Am Chem Soc       Date:  2019-07-16       Impact factor: 15.419

6.  X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor.

Authors:  Kyle M Lancaster; Michael Roemelt; Patrick Ettenhuber; Yilin Hu; Markus W Ribbe; Frank Neese; Uwe Bergmann; Serena DeBeer
Journal:  Science       Date:  2011-11-18       Impact factor: 47.728

7.  Evidence for interstitial carbon in nitrogenase FeMo cofactor.

Authors:  Thomas Spatzal; Müge Aksoyoglu; Limei Zhang; Susana L A Andrade; Erik Schleicher; Stefan Weber; Douglas C Rees; Oliver Einsle
Journal:  Science       Date:  2011-11-18       Impact factor: 47.728

8.  A transition metal Lewis acid/base triad system for cooperative substrate binding.

Authors:  Oscar Tutusaus; Chengbao Ni; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2013-02-25       Impact factor: 15.419

9.  Disproportionation of hydroxylamine by water-soluble iron(III) porphyrinate compounds.

Authors:  Sara E Bari; Valentín T Amorebieta; María M Gutiérrez; José A Olabe; Fabio Doctorovich
Journal:  J Inorg Biochem       Date:  2009-10-01       Impact factor: 4.155

10.  Climbing nitrogenase: toward a mechanism of enzymatic nitrogen fixation.

Authors:  Brian M Hoffman; Dennis R Dean; Lance C Seefeldt
Journal:  Acc Chem Res       Date:  2009-05-19       Impact factor: 22.384
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  4 in total

1.  Examining the Generality of Metal-Ligand Cooperativity Across a Series of First-Row Transition Metals: Capture, Bond Activation, and Stabilization.

Authors:  John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  Inorg Chem       Date:  2020-06-18       Impact factor: 5.165

2.  Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding.

Authors:  John J Kiernicki; Emily E Norwine; Myles A Lovasz; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2020-10-05       Impact factor: 6.222

3.  An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes.

Authors:  Vishal Chugh; Basujit Chatterjee; Wei-Chieh Chang; Hanna H Cramer; Carsten Hindemith; Helena Randel; Thomas Weyhermüller; Christophe Farès; Christophe Werlé
Journal:  Angew Chem Int Ed Engl       Date:  2022-08-01       Impact factor: 16.823

4.  Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate.

Authors:  Lucie Nurdin; Yan Yang; Peter G N Neate; Warren E Piers; Laurent Maron; Michael L Neidig; Jian-Bin Lin; Benjamin S Gelfand
Journal:  Chem Sci       Date:  2020-12-22       Impact factor: 9.825
  4 in total

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