Literature DB >> 23421523

A transition metal Lewis acid/base triad system for cooperative substrate binding.

Oscar Tutusaus1, Chengbao Ni, Nathaniel K Szymczak.   

Abstract

A frustrated Lewis pair accessory functionality is positioned in the secondary coordination sphere of a terpyridine ligand (Tpy(BN) = 6-morpholino-2,2':6',2″-terpyridine-6″-boronic acid pinacol ester) to promote directed Lewis acid/base interactions. Following metalation with VCl3, the utility of the metal Lewis acid/base triad (LABT) is highlighted with N2H4 as a cooperatively coordinated substrate, affording the first η(2)-[N2H3](-) vanadium complex.

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Year:  2013        PMID： 23421523     DOI： 10.1021/ja400962h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

1.  Molecular designs for controlling the local environments around metal ions.

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Review 2.  Biological and Bioinspired Inorganic N-N Bond-Forming Reactions.

Authors:  Christina Ferousi; Sean H Majer; Ida M DiMucci; Kyle M Lancaster
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3.  Hydrazine Capture and N-N Bond Cleavage at Iron Enabled by Flexible Appended Lewis Acids.

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Journal:  J Am Chem Soc       Date:  2017-12-11       Impact factor: 15.419

4.  Hydrogen Bonds Dictate O2 Capture and Release within a Zinc Tripod.

Authors:  Eric W Dahl; John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2018-08-03       Impact factor: 15.419

5.  Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding.

Authors:  John J Kiernicki; Emily E Norwine; Myles A Lovasz; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2020-10-05       Impact factor: 6.222

6.  Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.

Authors:  John J Kiernicki; Emily E Norwine; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2019-10-01       Impact factor: 6.222

7.  Exploring secondary-sphere interactions in Fe-N x H y complexes relevant to N2 fixation.

Authors:  Sidney E Creutz; Jonas C Peters
Journal:  Chem Sci       Date:  2016-12-08       Impact factor: 9.825

8.  Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides.

Authors:  John J Kiernicki; James P Shanahan; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Sci       Date:  2019-05-07       Impact factor: 9.825

9.  Early Metal Di(pyridyl) Pyrrolide Complexes with Second Coordination Sphere Arene-π Interactions: Ligand Binding and Ethylene Polymerization.

Authors:  Jessica Sampson; Gyeongshin Choi; Muhammed Naseem Akhtar; E A Jaseer; Rajesh Theravalappil; Nestor Garcia; Theodor Agapie
Journal:  ACS Omega       Date:  2019-09-19

10.  Vanadium(IV) Complexes with Methyl-Substituted 8-Hydroxyquinolines: Catalytic Potential in the Oxidation of Hydrocarbons and Alcohols with Peroxides and Biological Activity.

Authors:  Joanna Palion-Gazda; André Luz; Luis R Raposo; Katarzyna Choroba; Jacek E Nycz; Alina Bieńko; Agnieszka Lewińska; Karol Erfurt; Pedro V Baptista; Barbara Machura; Alexandra R Fernandes; Lidia S Shul'pina; Nikolay S Ikonnikov; Georgiy B Shul'pin
Journal:  Molecules       Date:  2021-10-21       Impact factor: 4.411
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