Literature DB >> 33016291

Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding.

John J Kiernicki1, Emily E Norwine, Myles A Lovasz, Matthias Zeller, Nathaniel K Szymczak.   

Abstract

Distance dependence of appended Lewis acids in N2H4 binding and deprotonation was evaluated within a series of zinc complexes. Variation of spacer-length to a tethered trialkylborane Lewis acid revealed distinct preferences for binding and stabilization of the resulting deprotonated N2H3- unit.

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Year:  2020        PMID: 33016291      PMCID: PMC7606458          DOI: 10.1039/d0cc05121g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  24 in total

1.  Recent Advances in Zinc Enzymology.

Authors:  William N. Lipscomb; Norbert Sträter
Journal:  Chem Rev       Date:  1996-11-07       Impact factor: 60.622

2.  The hydrogen bond in the solid state.

Authors:  Thomas Steiner
Journal:  Angew Chem Int Ed Engl       Date:  2002-01-04       Impact factor: 15.336

3.  Structural evidence for a dynamic metallocofactor during N2 reduction by Mo-nitrogenase.

Authors:  Wonchull Kang; Chi Chung Lee; Andrew J Jasniewski; Markus W Ribbe; Yilin Hu
Journal:  Science       Date:  2020-06-19       Impact factor: 47.728

4.  Requirements for Lewis Acid-Mediated Capture and N-N Bond Cleavage of Hydrazine at Iron.

Authors:  John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  Inorg Chem       Date:  2019-01-10       Impact factor: 5.165

5.  Crystal structure and kinetic studies of a tetrameric type II β-carbonic anhydrase from the pathogenic bacterium Vibrio cholerae.

Authors:  Marta Ferraroni; Sonia Del Prete; Daniela Vullo; Clemente Capasso; Claudiu T Supuran
Journal:  Acta Crystallogr D Biol Crystallogr       Date:  2015-11-26

Review 6.  Achieving Site-Selectivity for C-H Activation Processes Based on Distance and Geometry: A Carpenter's Approach.

Authors:  Guangrong Meng; Nelson Y S Lam; Erika L Lucas; Tyler G Saint-Denis; Pritha Verma; Nikita Chekshin; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2020-06-05       Impact factor: 15.419

7.  A transition metal Lewis acid/base triad system for cooperative substrate binding.

Authors:  Oscar Tutusaus; Chengbao Ni; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2013-02-25       Impact factor: 15.419

8.  Periodic trends and index of boron LEwis acidity.

Authors:  Joshua A Plumley; Jeffrey D Evanseck
Journal:  J Phys Chem A       Date:  2009-05-21       Impact factor: 2.781

9.  Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.

Authors:  John J Kiernicki; Emily E Norwine; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2019-10-01       Impact factor: 6.222

10.  Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides.

Authors:  John J Kiernicki; James P Shanahan; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Sci       Date:  2019-05-07       Impact factor: 9.825

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