Ky Mickelsen1, Sean Zabawa1, Tom Livinghouse1. 1. Department of Chemistry and Biochemistry, 103 CBB, Montana State University, Bozeman, MT 59717, USA livinghouse@chemistry.montana.edu.
Abstract
Metalloamination-alkylation of representative N,N-dimethyl-hydrazinoalkenes has been shown to be effectively catalyzed by CuBr-SMe2, CuCN, and Cul. The current method obviates the use of stoichiometric CuCN(LiCl)2 as a promoter for the electrophilic functionalization event.
Metalloamination-alkylation of representative N,N-dimethyl-hydrazinoalkenes has been shown to be effectively catalyzed by n class="Chemical">CuBr-SMe2, CuCN, and Cul. The current method obviates the use of stoichiometric CuCN(LiCl)2 as a promoter for the electrophilic functionalization event.
Authors: Jean-Grégoire Roveda; Christian Clavette; Ashley D Hunt; Serge I Gorelsky; Christopher J Whipp; André M Beauchemin Journal: J Am Chem Soc Date: 2009-07-01 Impact factor: 15.419