| Literature DB >> 29270018 |
Kathleen Ward Brown1, Bemnet Gessesse1, Lindsey J Butler2, David L MacIntosh1,3.
Abstract
Numerous contemporary incidents demonstrate that conventional control strategies for municipal tap water have limited ability to mitigate exposures to chemicals whose sources are within distribution systems, such as lead, and chemicals that are not removed by standard treatment technologies, such as perfluorooctanoic acid (PFOA)/perfluorooctanesulfonic acid (PFOS). In these situations, point-of-use (POU) controls may be effective in mitigating exposures and managing health risks of chemicals in drinking water, but their potential utility has not been extensively examined. As an initial effort to fill this information gap, we conducted a critical review and analysis of the existing literature and data on the effectiveness of POU drinking water treatment technologies for reducing chemical contaminants commonly found in tap water in the United States. We found that many types of water treatment devices available to consumers in the United States have undergone laboratory testing and often certification for removal of chemical contaminants in tap water, but in most cases their efficacy in actual use has yet to be well characterized. In addition, the few studies of POU devices while "in use" focus on traditional contaminants regulated under the Safe Drinking Water Act, but do not generally consider nontraditional contaminants of concern, such as certain novel human carcinogens, industrial chemicals, pesticides, pharmaceuticals, personal care products, and flame retardants. Nevertheless, the limited information available at present suggests that POU devices can be highly effective when used prophylactically and when deployed in response to contamination incidents. Based on these findings, we identify future areas of research for assessing the ability of POU filters to reduce health-related chemical contaminants distributed through public water systems and private wells.Entities:
Keywords: Flint; NSF; Point-of-use (POU) filter; drinking water treatment; faucet-mount filter; filtration
Year: 2017 PMID: 29270018 PMCID: PMC5731620 DOI: 10.1177/1178630217746997
Source DB: PubMed Journal: Environ Health Insights ISSN: 1178-6302
Summary statistics of 208 pairs of water samples with and without a POU filter collected in Flint, MI, January to May 2016.
| Used filter | No filter | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Mean (SD) | Min | P25 | P50 | P95 | Max | Mean (SD) | Min | P25 | P50 | P95 | Max | |
| Al | 0.051 (0.075) | 0.009 | 0.009 | 0.009 | 0.200 | 0.330 | 0.129 (0.300) | 0.009 | 0.021 | 0.043 | 0.370 | 2.62 |
| Cd | 0.452 (0.730) | 0.061 | 0.061 | 0.061 | 2.00 | 2.00 | 0.641 (1.149) | 0.061 | 0.061 | 0.140 | 2.00 | 12.0 |
| Ca | 22 (8) | 0.2 | 22 | 26 | 28 | 32 | 27 (2.7) | 0.24 | 26 | 27 | 29 | 32 |
| Cr | 1.25 (1.97) | 0.20 | 0.20 | 0.20 | 5.00 | 5.00 | 1.35 (2.13) | 0.20 | 0.20 | 0.25 | 5.00 | 14.1 |
| Cu | 2.2 (9.7) | 0.75 | 0.75 | 0.75 | 2.3 | 120 | 92.0 (177) | 0.75 | 14.3 | 36.0 | 349 | 1800 |
| Fe | 0.038 (0.069) | 0.016 | 0.016 | 0.016 | 0.096 | 0.880 | 0.508 (2.86) | 0.016 | 0.043 | 0.084 | 1.10 | 38.5 |
| Pb | 0.25 (0.35) | 0.11 | 0.11 | 0.11 | 0.50 | 2.90 | 18.5 (49.0) | 0.11 | 0.61 | 2.53 | 90.4 | 418 |
| Mg | 7.86 (2.00) | 0.048 | 7.80 | 8.10 | 9.80 | 11.2 | 7.82 (0.688) | 0.048 | 7.69 | 7.87 | 8.4 | 10.1 |
| Mn | 0.004 (0.006) | 0.001 | 0.001 | 0.002 | 0.009 | 0.068 | 0.012 (0.048) | 0.001 | 0.002 | 0.005 | 0.033 | 0.655 |
| Ni | 1.44 (2.25) | 0.23 | 0.23 | 0.31 | 6.00 | 11.6 | 2.25 (2.99) | 0.23 | 0.48 | 0.85 | 6.34 | 19.0 |
| K | 5.32 (10.4) | 0.21 | 0.99 | 1.36 | 32.7 | 70 | 0.99 (0.09) | 0.04 | 0.97 | 0.99 | 1.11 | 1.22 |
| Na | 9.31 (9.98) | 0.98 | 4.80 | 5.39 | 30.3 | 80 | 5.16 (3.96) | 4.1 | 4.6 | 4.8 | 5.27 | 52 |
| Zn | 0.051 (0.075) | 0.009 | 0.009 | 0.009 | 0.200 | 0.330 | 0.129 (0.300) | 0.009 | 0.021 | 0.043 | 0.370 | 2.62 |
Abbreviation: POU, point-of-use.
Units are in milligram per liter for all elements except Cr, Cu, Ni and Pb, which are in microgram per liter.
Summary statistics of differences in elemental levels for 208 pairs of water samples with and without a POU filter collected in Flint, MI, January to May 2016.
| Element | Mean (SD) | Min | Max | P25 | Median | P95 |
|---|---|---|---|---|---|---|
| Al | −0.1 (0.3) | −2.6 | 0.3 | −0.044 | −0.014 | 0.005 |
| Cd | −0.2 (0.9) | −11.4 | 0.32 | −0.1 | 0 | 0 |
| Ca | −4.2 (8.2) | −29.3 | 21.4 | −4.0 | −1.0 | 2.0 |
| Cr | −0.1 (0.6) | −9.1 | 0.48 | −0.1 | 0 | 0 |
| Cu | −89.8 (177) | −1799 | 47.25 | −98.1 | −34.3 | −3.3 |
| Fe | −0.5 (2.9) | −38.4 | 0.9 | −0.184 | −0.051 | 0 |
| Pb | −18.2 (49.0) | −418 | 0.7 | −9.9 | −2.3 | 0 |
| Mg | −0.04 (1.95) | −8.1 | 3.4 | −0.1 | 0.3 | 1.9 |
| Mn | −0.008 (0.048) | −0.647 | 0.064 | −0.005 | −0.001 | 0.004 |
| Ni | −0.001 (0.002) | −0.019 | 0.006 | −0.001 | 0 | 0 |
| K | 4.3 (10.4) | −0.7 | 69.0 | 0 | 0.4 | 31.7 |
| Na | 4.1 (9.9) | −32.4 | 75.2 | 0 | 0.6 | 25.0 |
| Zn | −0.13 (0.51) | −6.5 | 0.09 | −0.094 | −0.024 | 0.009 |
Abbreviation: POU, point-of-use.
Units are in milligram per liter for all elements except Cr, Cu and Pb, which are in microgram per liter.
Figure 1.Boxplots of Pb and Cu concentrations from matched water samples collected in 208 homes and commercial locations in Flint, MI, January to March 2016. (The upper and lower parts of the boxplot are the 75th and 25th percentile values. The upper and lower whiskers are the 90th and 10th percentile values. The median is in the center of the box and the dotted line is the mean. Outlier points are shown as dots above or below the whiskers.)
Data on health-based violations of inorganic and organic contaminant rules from USEPA ECHO database, 2010-2014.
| SDW rule/category | Contaminant(s) | Health-based violations | Total violations | Type of POU to treat | NSF/ANSI certification(s) | ||
|---|---|---|---|---|---|---|---|
| Number of violations | Size of population potentially affected | Number of violations | Size of population potentially affected | ||||
| LCR | Pb, Cu | 290 | 241 675 | 6189 | 14 461 735 | Carbon block | Standard 53 |
| Chemical | SOC, VOCs, other inorganics,[ | 473 | 774 390 | 5101 | 17 704 590 | Carbon block | Standard 53 |
| DBPs | THMs, HAAs, chlorite, bromate | 1442 | 8 837 437 | 8999 | 40 026 297 | Carbon block | Standard 53 |
| Arsenic | Arsenic | 708 | 1 074 179 | 1685 | 3 550 325 | RO | Standard 58 |
| Nitrates | Nitrate/Nitrite | 669 | 454 532 | 9165 | 9 397 203 | RO | Standard 58 |
| RO | Standard 58 | ||||||
Abbreviations: DBP, disinfection by-product; ECHO, Enforcement and Compliance History Online; HAAs, haloacetic acids; LCR, Lead and Copper Rule; RO, reverse osmosis; SOC, synthetic organic chemicals (includes 25 individual pesticides, ethylene dibromide, polychlorinated biphenyls, benzo(a)pyrene, di(ethylhexyl)-adipate, di(ethylhexyl)-phthalate, dioxin); THMs, trihalomethanes; USEPA, US Environmental Protection Agency; VOC = volatile organic compounds.
Other inorganics include asbestos, Ba, Cd, Cr, F, Hg, Se, Sb, Be, cyanide, and Tl.