| Literature DB >> 21711032 |
K C Nicolaou1, J L Kiappes, Weiwei Tian, Vijaya B Gondi, Jochen Becker.
Abstract
A synthetic route to the carboline disaccharide domain (2) of shishijimicin A (1) has been developed. The convergent synthesis relies on a novel application of the Reetz-Müller-Starke reaction to form the central, sulfur-bearing quaternary carbon center and addition of the carboline structural motif as a dianion to a disaccharide aldehyde fragment.Entities:
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Year: 2011 PMID： 21711032 PMCID： PMC3146563 DOI： 10.1021/ol201444t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005