Literature DB >> 20221298

Air/Water-Stable Tridentate NHC-Pd Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D(2)O.

Joo Ho Lee1, Kyung Soo Yoo, Chan Pil Park, Janet M Olsen, Satoshi Sakaguchi, G K Surya Prakash, Thomas Mathew, Kyung Woon Jung.   

Abstract

While developing novel catalysts for carbon-carbon or carbon-heteroatom coupling (N, O, or F), we were able to introduce tridentate NHC-amidate-alkoxide palladium(II) complexes. In aqueous solution, these NHC-Pd(II) complexes showed high ability for C-H activation of various hydrocarbons (cyclohexane, cyclopentane, dimethyl ether, THF, acetone, and toluene) under mild conditions.

Entities:  

Year:  2009        PMID： 20221298      PMCID： PMC2835316          DOI： 10.1002/adsc.200800698

Source DB:  PubMed          Journal:  Adv Synth Catal        ISSN： 1615-4150            Impact factor:   5.837


  21 in total

1.  Double C-H activation in a Rh-NHC complex leading to the isolation of a 14-electron Rh(III) complex.

Authors:  Reto Dorta; Edwin D Stevens; Steven P Nolan
Journal:  J Am Chem Soc       Date:  2004-04-28       Impact factor: 15.419

2.  A unifying mechanism for all high-temperature Heck reactions. The role of palladium colloids and anionic species.

Authors:  Johannes G de Vries
Journal:  Dalton Trans       Date:  2005-08-24       Impact factor: 4.390

3.  Efficient h/d exchange reactions of alkyl-substituted benzene derivatives by means of the Pd/C-H(2)-D(2)O system.

Authors:  Hiroyoshi Esaki; Fumiyo Aoki; Miho Umemura; Masatsugu Kato; Tomohiro Maegawa; Yasunari Monguchi; Hironao Sajiki
Journal:  Chemistry       Date:  2007       Impact factor: 5.236

4.  C-H activation reactions of ruthenium N-heterocyclic carbene complexes: application in a catalytic tandem reaction involving C-C bond formation from alcohols.

Authors:  Suzanne Burling; Belinda M Paine; Devendrababu Nama; Victoria S Brown; Mary F Mahon; Timothy J Prior; Paul S Pregosin; Michael K Whittlesey; Jonathan M J Williams
Journal:  J Am Chem Soc       Date:  2007-01-27       Impact factor: 15.419

5.  Highly stable Cp*-Ir(III) complexes with N-heterocyclic carbene ligands as C-H activation catalysts for the deuteration of organic molecules.

Authors:  Rosa Corberán; Mercedes Sanaú; Eduardo Peris
Journal:  J Am Chem Soc       Date:  2006-03-29       Impact factor: 15.419

6.  Synthesis and characterisation of benzyl phosphino-thioether and -thiolato Pd(II) complexes and their applications in Suzuki coupling reactions.

Authors:  Athanasia Dervisi; Despina Koursarou; Li-Ling Ooi; Peter N Horton; Michael B Hursthouse
Journal:  Dalton Trans       Date:  2006-10-18       Impact factor: 4.390

Review 7.  Understanding and exploiting C-H bond activation.

Authors:  Jay A Labinger; John E Bercaw
Journal:  Nature       Date:  2002-05-30       Impact factor: 49.962

8.  Interaction of a bulky N-heterocyclic carbene ligand with Rh(I) and Ir(I). Double C-H activation and isolation of bare 14-electron Rh(III) and Ir(III) complexes.

Authors:  Natalie M Scott; Reto Dorta; Edwin D Stevens; Andrea Correa; Luigi Cavallo; Steven P Nolan
Journal:  J Am Chem Soc       Date:  2005-03-16       Impact factor: 15.419

9.  Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group.

Authors:  Javier A Cabeza; Ignacio del Río; Daniel Miguel; M Gabriela Sánchez-Vega
Journal:  Chem Commun (Camb)       Date:  2005-07-05       Impact factor: 6.222

10.  Alkane C-H activation and catalysis by an O-donor ligated iridium complex.

Authors:  Antek G Wong-Foy; Gaurav Bhalla; Xiang Yang Liu; Roy A Periana
Journal:  J Am Chem Soc       Date:  2003-11-26       Impact factor: 15.419
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  5 in total

1.  Direct Conversion of Glycerol into Formic Acid via Water Stable Pd(II) Catalyzed Oxidative Carbon-Carbon Bond Cleavage.

Authors:  Prasanna Pullanikat; Joo Ho Lee; Kyung Soo Yoo; Kyung Woon Jung
Journal:  Tetrahedron Lett       Date:  2013-08-14       Impact factor: 2.415

2.  Conversion of Saccharides into Formic Acid using Hydrogen Peroxide and a Recyclable Palladium(II) Catalyst in Aqueous Alkaline Media at Ambient Temperatures.

Authors:  N Zargari; Y Kim; K W Jung
Journal:  Green Chem       Date:  2015-03-03       Impact factor: 10.182

Review 3.  N-Heterocyclic Carbene Complexes in C-H Activation Reactions.

Authors:  Qun Zhao; Guangrong Meng; Steven P Nolan; Michal Szostak
Journal:  Chem Rev       Date:  2020-01-22       Impact factor: 60.622

4.  Chemoselective hydroamination of vinyl arenes catalyzed by an NHC-amidate-alkoxide Pd(II) complex and p-TsOH.

Authors:  Richard Giles; Justin O'Neill; Joo Ho Lee; Michael K Chiu; Kyung Woon Jung
Journal:  Tetrahedron Lett       Date:  2013-07-31       Impact factor: 2.415

5.  H-D exchange in deuterated trifluoroacetic acid via ligand-directed NHC-palladium catalysis: a powerful method for deuteration of aromatic ketones, amides, and amino acids.

Authors:  Richard Giles; Green Ahn; Kyung Woon Jung
Journal:  Tetrahedron Lett       Date:  2015-11-04       Impact factor: 2.415
  5 in total

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