Literature DB >> 15099073

Double C-H activation in a Rh-NHC complex leading to the isolation of a 14-electron Rh(III) complex.

Reto Dorta1, Edwin D Stevens, Steven P Nolan.   

Abstract

The solvent-dependent interaction of ItBu with a Rh(I)-olefin complex leads to the isolation of two precursors en route to a unique double cyclometalation process. Abstraction of the chloride ligand from the resulting complex enables the isolation of a "bare" 14-electron Rh(III) complex.

Entities:  

Year:  2004        PMID： 15099073     DOI： 10.1021/ja049545+

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Air/Water-Stable Tridentate NHC-Pd Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D(2)O.

Authors:  Joo Ho Lee; Kyung Soo Yoo; Chan Pil Park; Janet M Olsen; Satoshi Sakaguchi; G K Surya Prakash; Thomas Mathew; Kyung Woon Jung
Journal:  Adv Synth Catal       Date:  2009-03-01       Impact factor: 5.837

Review 2.  C-H activation-annulation on the N-heterocyclic carbene platform.

Authors:  Champak Dutta; Joyanta Choudhury
Journal:  RSC Adv       Date:  2018-08-06       Impact factor: 4.036

Review 3.  N-Heterocyclic Carbene Complexes in C-H Activation Reactions.

Authors:  Qun Zhao; Guangrong Meng; Steven P Nolan; Michal Szostak
Journal:  Chem Rev       Date:  2020-01-22       Impact factor: 60.622

4.  Half-sandwich nickel(II) complexes bearing 1,3-di(cycloalkyl)imidazol-2-ylidene ligands.

Authors:  Johnathon Yau; Kaarel E Hunt; Laura McDougall; Alan R Kennedy; David J Nelson
Journal:  Beilstein J Org Chem       Date:  2015-11-12       Impact factor: 2.883

5.  Tungsten(VI) N-Heterocyclic Carbene Complexes: Synthetic, Structural, and Computational Study.

Authors:  Christopher A Dodds; Mark D Spicer; Tell Tuttle
Journal:  Organometallics       Date:  2011-11-03       Impact factor: 3.876

6.  Solution, Solid-State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low-Coordinate Rhodium(III) and Iridium(III) Complexes.

Authors:  Richard C Knighton; Jack Emerson-King; Jonathan P Rourke; C André Ohlin; Adrian B Chaplin
Journal:  Chemistry       Date:  2018-02-28       Impact factor: 5.236
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.