Qun Zhao1, Guangrong Meng1, Steven P Nolan2, Michal Szostak1. 1. Department of Chemistry , Rutgers University , 73 Warren Street , Newark , New Jersey 07102 , United States. 2. Department of Chemistry and Center for Sustainable Chemistry , Ghent University , Krijgslaan 281 , 9000 Ghent , Belgium.
Abstract
In this contribution, we provide a comprehensive overview of C-H activation methods promoted by NHC-transition metal complexes, covering the literature since 2002 (the year of the first report on metal-NHC-catalyzed C-H activation) through June 2019, focusing on both NHC ligands and C-H activation methods. This review covers C-H activation reactions catalyzed by group 8 to 11 NHC-metal complexes. Through discussing the role of NHC ligands in promoting challenging C-H activation methods, the reader is provided with an overview of this important area and its crucial role in forging carbon-carbon and carbon-heteroatom bonds by directly engaging ubiquitous C-H bonds.
In this contribution, we provide a comprehensive overview of class="Chemical">C-H activation methods class="Chemical">promoted by class="Chemical">pan class="Chemical">NHC-transition metal complexes, covering the literature since 2002 (the year of the first report on metal-NHC-catalyzed C-H activation) through June 2019, focusing on both NHC ligands and C-H activation methods. This review covers C-H activation reactions catalyzed by group 8 to 11 NHC-metal complexes. Through discussing the role of NHC ligands in promoting challenging C-H activation methods, the reader is provided with an overview of this important area and its crucial role in forging carbon-carbon and carbon-heteroatom bonds by directly engaging ubiquitous C-H bonds.
Authors: Andrew M Romine; Matthew J Demer; Milan Gembicky; Arnold L Rheingold; Keary M Engle Journal: Organometallics Date: 2021-04-30 Impact factor: 3.837
Authors: Shiyi Yang; Tongliang Zhou; Albert Poater; Luigi Cavallo; Steven P Nolan; Michal Szostak Journal: Catal Sci Technol Date: 2021-03-25 Impact factor: 6.119