Literature DB >> 23997315

Direct Conversion of Glycerol into Formic Acid via Water Stable Pd(II) Catalyzed Oxidative Carbon-Carbon Bond Cleavage.

Prasanna Pullanikat1, Joo Ho Lee, Kyung Soo Yoo, Kyung Woon Jung.   

Abstract

Using our tridentate NHC-amidate-alkoxide Pd(II) complex, we developed a catalytic method for oxidative C-C bond cleavage of glycerol. The glycerol was degraded exclusively to formic acid and CO2. Two possible degradation pathways were proposed through 13C labeled studies.

Entities:  

Keywords:  Degradation of glycerol; Formic acid; NHC amidate ligand; Oxidative catalysis; Palladium catalyst

Year:  2013        PMID： 23997315      PMCID： PMC3755462          DOI： 10.1016/j.tetlet.2013.06.041

Source DB:  PubMed          Journal:  Tetrahedron Lett        ISSN： 0040-4039            Impact factor:   2.415


  12 in total

1.  Silyl cation mediated conversion of CO2 into benzoic acid, formic acid, and methanol.

Authors:  André Schäfer; Wolfgang Saak; Detlev Haase; Thomas Müller
Journal:  Angew Chem Int Ed Engl       Date:  2012-02-06       Impact factor: 15.336

2.  Ruthenium-catalyzed hydrogenation of bicarbonate in water.

Authors:  Christopher Federsel; Ralf Jackstell; Albert Boddien; Gabor Laurenczy; Matthias Beller
Journal:  ChemSusChem       Date:  2010-09-24       Impact factor: 8.928

Review 3.  From glycerol to value-added products.

Authors:  Mario Pagliaro; Rosaria Ciriminna; Hiroshi Kimura; Michele Rossi; Cristina Della Pina
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

Review 4.  Commodity chemicals derived from glycerol, an important biorefinery feedstock.

Authors:  Yuguo Zheng; Xiaolong Chen; Yinchu Shen
Journal:  Chem Rev       Date:  2008-12       Impact factor: 60.622

5.  Hydrogen peroxide-coupled cis-diol formation catalyzed by naphthalene 1,2-dioxygenase.

Authors:  Matt D Wolfe; John D Lipscomb
Journal:  J Biol Chem       Date:  2002-10-25       Impact factor: 5.157

6.  Continuous-flow hydrogenation of carbon dioxide to pure formic acid using an integrated scCO2 process with immobilized catalyst and base.

Authors:  Sebastian Wesselbaum; Ulrich Hintermair; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2012-07-13       Impact factor: 15.336

7.  Air/Water-Stable Tridentate NHC-Pd Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D(2)O.

Authors:  Joo Ho Lee; Kyung Soo Yoo; Chan Pil Park; Janet M Olsen; Satoshi Sakaguchi; G K Surya Prakash; Thomas Mathew; Kyung Woon Jung
Journal:  Adv Synth Catal       Date:  2009-03-01       Impact factor: 5.837

8.  Copper-catalyzed formic acid synthesis from CO2 with hydrosilanes and H2O.

Authors:  Ken Motokura; Daiki Kashiwame; Akimitsu Miyaji; Toshihide Baba
Journal:  Org Lett       Date:  2012-04-27       Impact factor: 6.005

9.  Palladium(II)-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Molecular Oxygen.

Authors:  Takahiro Nishimura; Tomoaki Onoue; Kouichi Ohe; Sakae Uemura
Journal:  J Org Chem       Date:  1999-09-03       Impact factor: 4.354

10.  Mechanism for activation of molecular oxygen by cis- and trans-(pyridine)2Pd(OAc)H: Pd(0) versus direct insertion.

Authors:  Jason M Keith; William A Goddard
Journal:  J Am Chem Soc       Date:  2009-02-04       Impact factor: 15.419
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  2 in total

1.  Conversion of Saccharides into Formic Acid using Hydrogen Peroxide and a Recyclable Palladium(II) Catalyst in Aqueous Alkaline Media at Ambient Temperatures.

Authors:  N Zargari; Y Kim; K W Jung
Journal:  Green Chem       Date:  2015-03-03       Impact factor: 10.182

2.  Selective photocatalytic C-C bond cleavage under ambient conditions with earth abundant vanadium complexes.

Authors:  Sarifuddin Gazi; Wilson Kwok Hung Ng; Rakesh Ganguly; Adhitya Mangala Putra Moeljadi; Hajime Hirao; Han Sen Soo
Journal:  Chem Sci       Date:  2015-09-14       Impact factor: 9.825
  2 in total

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