Literature DB >> 26421000

Conversion of Saccharides into Formic Acid using Hydrogen Peroxide and a Recyclable Palladium(II) Catalyst in Aqueous Alkaline Media at Ambient Temperatures.

N Zargari1, Y Kim1, K W Jung1.   

Abstract

We have developed an effective method that converts a variety of mono- and disaccharides into formic acid predominantly. Our recyclable NHC-amidate palladium(II) catalyst facilitated oxidative degradation of carbohydrates without using excess oxidant. Stoichiometric amounts of hydrogen peroxide and sodium hydroxide were employed at ambient temperatures.

Entities:  

Year:  2015        PMID： 26421000      PMCID： PMC4584152          DOI： 10.1039/C4GC02362E

Source DB:  PubMed          Journal:  Green Chem        ISSN： 1463-9262            Impact factor:   10.182


  8 in total

1.  Direct Conversion of Glycerol into Formic Acid via Water Stable Pd(II) Catalyzed Oxidative Carbon-Carbon Bond Cleavage.

Authors:  Prasanna Pullanikat; Joo Ho Lee; Kyung Soo Yoo; Kyung Woon Jung
Journal:  Tetrahedron Lett       Date:  2013-08-14       Impact factor: 2.415

2.  Controlling hydrothermal reaction pathways to improve acetic acid production from carbohydrate biomass.

Authors:  Fangming Jin; Zhouyu Zhou; Takehiko Moriya; Hisanori Kishida; Hisao Higashijima; Heiji Enomoto
Journal:  Environ Sci Technol       Date:  2005-03-15       Impact factor: 9.028

Review 3.  Conversion of biomass to selected chemical products.

Authors:  Pierre Gallezot
Journal:  Chem Soc Rev       Date:  2011-09-12       Impact factor: 54.564

4.  Air/Water-Stable Tridentate NHC-Pd Complex; Catalytic C-H Activation of Hydrocarbons via H/D Exchange Process in D(2)O.

Authors:  Joo Ho Lee; Kyung Soo Yoo; Chan Pil Park; Janet M Olsen; Satoshi Sakaguchi; G K Surya Prakash; Thomas Mathew; Kyung Woon Jung
Journal:  Adv Synth Catal       Date:  2009-03-01       Impact factor: 5.837

5.  Free energy landscape for glucose condensation reactions.

Authors:  Dajiang Liu; Mark R Nimlos; David K Johnson; Michael E Himmel; Xianghong Qian
Journal:  J Phys Chem A       Date:  2010-11-18       Impact factor: 2.781

6.  Uncatalysed wet oxidation of D-glucose with hydrogen peroxide and its combination with hydrothermal electrolysis.

Authors:  Teresa Moreno; Goushi Kouzaki; Mitsuru Sasaki; Motonobu Goto; María José Cocero
Journal:  Carbohydr Res       Date:  2011-12-14       Impact factor: 2.104

7.  Oxidative damage due to copper ion and hydrogen peroxide induces GlcNAc-specific cleavage of an Asn-linked oligosaccharide.

Authors:  Hironobu Eguchi; Yoshitaka Ikeda; Souichi Koyota; Koichi Honke; Keiichiro Suzuki; John M C Gutteridge; Naoyuki Taniguchi
Journal:  J Biochem       Date:  2002-03       Impact factor: 3.387

8.  Modeling sucrose hydrolysis in dilute sulfuric acid solutions at pretreatment conditions for lignocellulosic biomass.

Authors:  Shane Bower; Ranil Wickramasinghe; Nicholas J Nagle; Daniel J Schell
Journal:  Bioresour Technol       Date:  2007-07-09       Impact factor: 9.642
  8 in total

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