Literature DB >> 19013078

The spontaneous loss of coherence catastrophe in Fourier transform ion cyclotron resonance mass spectrometry.

Konstantin Aizikov1, Raman Mathur, Peter B O'Connor.   

Abstract

The spontaneous loss of coherence catastrophe (SLCC) is a frequently observed, yet poorly studied, space-charge related effect in Fourier-transform ion cyclotron resonance mass spectrometry (FTICR-MS). This manuscript presents an application of the filter diagonalization method (FDM) in the analysis of this phenomenon. The temporal frequency behavior reproduced by frequency shift analysis using the FDM shows the complex nature of the SLCC, which can be explained by a combination of factors occurring concurrently, governed by electrostatics and ion packet trajectories inside the ICR cell.

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Year:  2008        PMID: 19013078      PMCID: PMC2872030          DOI: 10.1016/j.jasms.2008.09.028

Source DB:  PubMed          Journal:  J Am Soc Mass Spectrom        ISSN: 1044-0305            Impact factor:   3.109


  37 in total

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