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Literature DB >> 18368158

Protein scaffold of a designed metalloenzyme enhances the chemoselectivity in sulfoxidation of thioanisole.

Jun-Long Zhang¹, Dewain K Garner, Lei Liang, Qian Chen, Yi Lu.

Abstract

We demonstrate that incorporation of MnSalen into a protein scaffold enhances the chemoselectivity in sulfoxidation of thioanisole and find that both the polarity and hydrogen bonding of the protein scaffold play an important role in tuning the chemoselectivity.

Entities: Chemical

Mesh：

Substances：

Year: 2008 PMID： 18368158 PMCID： PMC2775416 DOI： 10.1039/b718915j

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

21 in total

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7 in total

1. Covalent Anchor Positions Play an Important Role in Tuning Catalytic Properties of a Rationally Designed MnSalen-containing Metalloenzyme.

Authors: Dewain K Garner; Lei Liang; David A Barrios; Jun-Long Zhang; Yi Lu
Journal: ACS Catal Date: 2011-09-02 Impact factor: 13.084

Review 2. Protein design: toward functional metalloenzymes.

Authors: Fangting Yu; Virginia M Cangelosi; Melissa L Zastrow; Matteo Tegoni; Jefferson S Plegaria; Alison G Tebo; Catherine S Mocny; Leela Ruckthong; Hira Qayyum; Vincent L Pecoraro
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Review 3. Design and engineering of artificial oxygen-activating metalloenzymes.

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4. Understanding and Modulating Metalloenzymes with Unnatural Amino Acids, Non-Native Metal Ions, and Non-Native Metallocofactors.

Authors: Evan N Mirts; Ambika Bhagi-Damodaran; Yi Lu
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Authors: Yi Lu; Natasha Yeung; Nathan Sieracki; Nicholas M Marshall
Journal: Nature Date: 2009-08-13 Impact factor: 49.962

6. Noncovalent modulation of pH-dependent reactivity of a Mn-salen cofactor in myoglobin with hydrogen peroxide.

Authors: Jun-Long Zhang; Dewain K Garner; Lei Liang; David A Barrios; Yi Lu
Journal: Chemistry Date: 2009-07-27 Impact factor: 5.236

Review 7. Schiff base complex conjugates of bovine serum albumin as artificial metalloenzymes for eco-friendly enantioselective sulfoxidation.

Authors: Jie Tang; Pengfei Yao; Lina Wang; Hedong Bian; Meiyi Luo; Fuping Huang
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7 in total