Literature DB >> 16043706

Space-time thermodynamics of the glass transition.

Mauro Merolle1, Juan P Garrahan, David Chandler.   

Abstract

We consider the probability distribution for fluctuations in dynamical action and similar quantities related to dynamic heterogeneity. We argue that the so-called "glass transition" is a manifestation of low action tails in these distributions where the entropy of trajectory space is subextensive in time. These low action tails are a consequence of dynamic heterogeneity and an indication of phase coexistence in trajectory space. The glass transition, where the system falls out of equilibrium, is then an order-disorder phenomenon in space-time occurring at a temperature T(g), which is a weak function of measurement time. We illustrate our perspective ideas with facilitated lattice models and note how these ideas apply more generally.

Year:  2005        PMID: 16043706      PMCID: PMC1182452          DOI: 10.1073/pnas.0504820102

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  14 in total

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2.  Spatially heterogeneous dynamics in supercooled liquids.

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5.  Coarse-grained microscopic model of glass formers.

Authors:  Juan P Garrahan; David Chandler
Journal:  Proc Natl Acad Sci U S A       Date:  2003-08-04       Impact factor: 11.205

6.  Geometrical explanation and scaling of dynamical heterogeneities in glass forming systems.

Authors:  Juan P Garrahan; David Chandler
Journal:  Phys Rev Lett       Date:  2002-07-01       Impact factor: 9.161

7.  Excitation lines and the breakdown of Stokes-Einstein relations in supercooled liquids.

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8.  On the Adam-Gibbs-Kirkpatrick-Thirumalai-Wolynes scenario for the viscosity increase in glasses.

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9.  Out-of-equilibrium dynamical fluctuations in glassy systems.

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Journal:  J Chem Phys       Date:  2004-11-22       Impact factor: 3.488

10.  Formation of glasses from liquids and biopolymers.

Authors:  C A Angell
Journal:  Science       Date:  1995-03-31       Impact factor: 47.728

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  14 in total

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Authors:  Yael S Elmatad; Robert L Jack; David Chandler; Juan P Garrahan
Journal:  Proc Natl Acad Sci U S A       Date:  2010-07-02       Impact factor: 11.205

2.  Transport properties of glass-forming liquids suggest that dynamic crossover temperature is as important as the glass transition temperature.

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Journal:  Proc Natl Acad Sci U S A       Date:  2010-12-08       Impact factor: 11.205

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Journal:  Proc Natl Acad Sci U S A       Date:  2007-11-28       Impact factor: 11.205

4.  Spatiotemporal structures in aging and rejuvenating glasses.

Authors:  Peter G Wolynes
Journal:  Proc Natl Acad Sci U S A       Date:  2009-02-02       Impact factor: 11.205

5.  Anomalous yet Brownian.

Authors:  Bo Wang; Stephen M Anthony; Sung Chul Bae; Steve Granick
Journal:  Proc Natl Acad Sci U S A       Date:  2009-07-30       Impact factor: 11.205

6.  Asynchronous Replica Exchange Software for Grid and Heterogeneous Computing.

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Journal:  Comput Phys Commun       Date:  2015-11       Impact factor: 4.390

7.  Bond orientational order in liquids: Towards a unified description of water-like anomalies, liquid-liquid transition, glass transition, and crystallization: Bond orientational order in liquids.

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Journal:  Eur Phys J E Soft Matter       Date:  2012-10-31       Impact factor: 1.890

8.  Emergence of glass-like behavior in Markov state models of protein folding dynamics.

Authors:  Jeffrey K Weber; Robert L Jack; Vijay S Pande
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9.  Dynamical phase transitions reveal amyloid-like states on protein folding landscapes.

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10.  Limiting Energy Dissipation Induces Glassy Kinetics in Single-Cell High-Precision Responses.

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Journal:  Biophys J       Date:  2016-03-08       Impact factor: 4.033

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