Literature DB >> 15473805

On the Adam-Gibbs-Kirkpatrick-Thirumalai-Wolynes scenario for the viscosity increase in glasses.

Jean-Philippe Bouchaud1, Giulio Biroli.   

Abstract

We reformulate the interpretation of the mean-field glass transition scenario for finite dimensional systems, proposed by Kirkpatrick, Thirumalai, and Wolynes (KTW). This allows us to establish clearly a temperature dependent length xi( *) above which the mean-field glass transition picture has to be modified. We argue in favor of the mosaic state introduced by KTW, which leads to the Adam-Gibbs relation between the viscosity and configurational entropy of glass forming liquids. Our argument is a mixture of thermodynamics and kinetics, partly inspired by the random energy model: small clusters of particles are thermodynamically frozen in low energy states, whereas large clusters are kinetically frozen by large activation energies. The relevant relaxation time is that of the smallest "liquid" clusters. Some physical consequences are discussed.

Year:  2004        PMID: 15473805     DOI: 10.1063/1.1796231

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  22 in total

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7.  Real space renormalization group theory of disordered models of glasses.

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8.  Power law relationship between diffusion coefficients in multi-component glass forming liquids.

Authors:  Anshul D S Parmar; Shiladitya Sengupta; Srikanth Sastry
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9.  On the strength of glasses.

Authors:  Apiwat Wisitsorasak; Peter G Wolynes
Journal:  Proc Natl Acad Sci U S A       Date:  2012-09-17       Impact factor: 11.205

10.  Bond orientational order in liquids: Towards a unified description of water-like anomalies, liquid-liquid transition, glass transition, and crystallization: Bond orientational order in liquids.

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Journal:  Eur Phys J E Soft Matter       Date:  2012-10-31       Impact factor: 1.890

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