Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 The role of diffusion in bimolecular solution kinetics.

Literature DB >> 5475729

The role of diffusion in bimolecular solution kinetics.

Abstract

An appropriate boundary condition is derived which permits both the bimolecular association and dissociation steps to be simultaneously treated within the framework of the theory of Smoluchowski, Debye, and Collins, and Kimball. Kinetic theory expressions are derived for the intrinsic rate constants. The transient case of the suddenly switched-on reaction is considered as well as the suddenly perturbed equilibrium, but only the time dependence of the rate constants is obtained. The frequency response spectrum for a diffusion-controlled reaction is obtained in the linear approximation and compared with the corresponding Debye relaxation spectrum.

Entities: Disease

Mesh：

Substances：
Solutions

Year: 1970 PMID： 5475729 PMCID： PMC1367933 DOI： 10.1016/S0006-3495(70)86330-5

Source DB: PubMed Journal: Biophys J ISSN： 0006-3495 Impact factor: 4.033

1 in total

Review 1. ELEMENTARY STEPS IN ENZYME REACTIONS (AS STUDIED BY RELAXATION SPECTROMETRY).

Authors: M EIGEN; G G HAMMES
Journal: Adv Enzymol Relat Subj Biochem Date: 1963

1 in total

13 in total

1. Amino acid substitutions and ion channel function. Model-dependent conclusions.

Authors: M D Becker; R E Koeppe; O S Andersen
Journal: Biophys J Date: 1992-04 Impact factor: 4.033

2. Diffusion modifies the connectivity of kinetic schemes for multisite binding and catalysis.

Authors: Irina V Gopich; Attila Szabo
Journal: Proc Natl Acad Sci U S A Date: 2013-11-18 Impact factor: 11.205

3. Site-Specific Polymer Attachment to HR2 Peptide Fusion Inhibitors against HIV-1 Decreases Binding Association Rates and Dissociation Rates Rather Than Binding Affinity.

Authors: Maarten Danial; Angela N Stauffer; Frederik R Wurm; Michael J Root; Harm-Anton Klok
Journal: Bioconjug Chem Date: 2016-10-27 Impact factor: 4.774

9. Theory of antigen-antibody induced particulate aggregation. II. Theoretical analysis and comparison with experimental results.

Authors: K C Chak; H Hart
Journal: Bull Math Biol Date: 1980 Impact factor: 1.758

10. Role of diffusion in ligand binding to macromolecules and cell-bound receptors.

Authors: D Shoup; A Szabo
Journal: Biophys J Date: 1982-10 Impact factor: 4.033

The role of diffusion in bimolecular solution kinetics.

Review 1. ELEMENTARY STEPS IN ENZYME REACTIONS (AS STUDIED BY RELAXATION SPECTROMETRY).

1. Amino acid substitutions and ion channel function. Model-dependent conclusions.

2. Diffusion modifies the connectivity of kinetic schemes for multisite binding and catalysis.

3. Site-Specific Polymer Attachment to HR2 Peptide Fusion Inhibitors against HIV-1 Decreases Binding Association Rates and Dissociation Rates Rather Than Binding Affinity.

4. Recognition kinetics of biomolecules at the surface of different-sized spheres.

5. Surface charge and lanthanum block of calcium current in bullfrog sympathetic neurons.

6. Diffusion-controlled reactions on spherical surfaces. Application to bacteriophage tail fiber attachment.

7. The role of diffusion in enzyme kinetics.

8. Ion movement through gramicidin A channels. Studies on the diffusion-controlled association step.

9. Theory of antigen-antibody induced particulate aggregation. II. Theoretical analysis and comparison with experimental results.

10. Role of diffusion in ligand binding to macromolecules and cell-bound receptors.