Literature DB >> 28628312

A Mononuclear Nonheme Iron(V)-Imido Complex.

Seungwoo Hong1,2, Kyle D Sutherlin3, Anil Kumar Vardhaman1, James J Yan3, Sora Park1, Yong-Min Lee1, Soojeong Jang1, Xiaoyan Lu1, Takehiro Ohta4, Takashi Ogura4, Edward I Solomon3,5, Wonwoo Nam1,6.   

Abstract

Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]- (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) Å, and an Fe-N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.

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Year:  2017        PMID： 28628312      PMCID： PMC5843466          DOI： 10.1021/jacs.7b04695

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  32 in total

1.  Long-range electron transfer triggers mechanistic differences between iron(IV)-oxo and iron(IV)-imido oxidants.

Authors:  Suresh Kumar; Abayomi S Faponle; Prasenjit Barman; Anil Kumar Vardhaman; Chivukula V Sastri; Devesh Kumar; Sam P de Visser
Journal:  J Am Chem Soc       Date:  2014-11-25       Impact factor: 15.419

Review 2.  High-valent iron and manganese complexes of corrole and porphyrin in atom transfer and dioxygen evolving catalysis.

Authors:  Mahdi M Abu-Omar
Journal:  Dalton Trans       Date:  2011-01-31       Impact factor: 4.390

3.  Molecular designs for controlling the local environments around metal ions.

Authors:  Sarah A Cook; A S Borovik
Journal:  Acc Chem Res       Date:  2015-07-16       Impact factor: 22.384

4.  Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds.

Authors:  Mark P Mehn; Steven D Brown; David M Jenkins; Jonas C Peters; Lawrence Que
Journal:  Inorg Chem       Date:  2006-09-04       Impact factor: 5.165

5.  Homogeneous photochemical water oxidation by biuret-modified Fe-TAML: evidence of Fe(V)(O) intermediate.

Authors:  Chakadola Panda; Joyashish Debgupta; David Díaz Díaz; Kundan K Singh; Sayam Sen Gupta; Basab B Dhar
Journal:  J Am Chem Soc       Date:  2014-08-25       Impact factor: 15.419

Review 6.  Selective functionalisation of saturated C-H bonds with metalloporphyrin catalysts.

Authors:  Chi-Ming Che; Vanessa Kar-Yan Lo; Cong-Ying Zhou; Jie-Sheng Huang
Journal:  Chem Soc Rev       Date:  2011-03-09       Impact factor: 54.564

7.  A diiron(III,IV) imido species very active in nitrene-transfer reactions.

Authors:  Eric Gouré; Frédéric Avenier; Patrick Dubourdeaux; Olivier Sénèque; Florian Albrieux; Colette Lebrun; Martin Clémancey; Pascale Maldivi; Jean-Marc Latour
Journal:  Angew Chem Int Ed Engl       Date:  2014-01-13       Impact factor: 15.336

8.  Nonheme iron-mediated amination of C(sp3)-H bonds. Quinquepyridine-supported iron-imide/nitrene intermediates by experimental studies and DFT calculations.

Authors:  Yungen Liu; Xiangguo Guan; Ella Lai-Ming Wong; Peng Liu; Jie-Sheng Huang; Chi-Ming Che
Journal:  J Am Chem Soc       Date:  2013-05-02       Impact factor: 15.419

9.  Complex N-heterocycle synthesis via iron-catalyzed, direct C-H bond amination.

Authors:  Elisabeth T Hennessy; Theodore A Betley
Journal:  Science       Date:  2013-05-03       Impact factor: 47.728

10.  Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.

Authors:  Mayank Puri; Lawrence Que
Journal:  Acc Chem Res       Date:  2015-07-15       Impact factor: 22.384
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  13 in total

1.  A Manganese(V)-Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies.

Authors:  Deepika G Karmalkar; Xiao-Xi Li; Mi Sook Seo; Muniyandi Sankaralingam; Takehiro Ohta; Ritimukta Sarangi; Seungwoo Hong; Wonwoo Nam
Journal:  Chemistry       Date:  2018-11-19       Impact factor: 5.236

2.  A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450.

Authors:  Xiaoyan Lu; Xiao-Xi Li; Mi Sook Seo; Yong-Min Lee; Martin Clémancey; Pascale Maldivi; Jean-Marc Latour; Ritimukta Sarangi; Shunichi Fukuzumi; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2018-12-20       Impact factor: 15.419

3.  Direct Comparison of C-H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl.

Authors:  Matthew J T Wilding; Diana A Iovan; Alexandra T Wrobel; James T Lukens; Samantha N MacMillan; Kyle M Lancaster; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2017-10-09       Impact factor: 15.419

4.  Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex.

Authors:  Seungwoo Hong; Xiaoyan Lu; Yong-Min Lee; Mi Sook Seo; Takehiro Ohta; Takashi Ogura; Martin Clémancey; Pascale Maldivi; Jean-Marc Latour; Ritimukta Sarangi; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2017-10-04       Impact factor: 15.419

5.  Nitrogen Reduction to Ammonia on a Biomimetic Mononuclear Iron Centre: Insights into the Nitrogenase Enzyme.

Authors:  Monika A Kaczmarek; Abheek Malhotra; G Alex Balan; Amy Timmins; Sam P de Visser
Journal:  Chemistry       Date:  2017-12-14       Impact factor: 5.236

6.  Sulfonylimino Group Transfer Reaction Using Imino-λ³-iodanes with I₂ as Catalyst Under Metal-free Conditions.

Authors:  Akira Yoshimura; Cody L Makitalo; Melissa E Jarvi; Michael T Shea; Pavel S Postnikov; Gregory T Rohde; Viktor V Zhdankin; Akio Saito; Mekhman S Yusubov
Journal:  Molecules       Date:  2019-03-11       Impact factor: 4.411

7.  Uncatalyzed Oxidative C-H Amination of 9,10-Dihydro-9-Heteroanthracenes: A Mechanistic Study.

Authors:  Nicolaas P van Leest; Lars Grooten; Jarl Ivar van der Vlugt; Bas de Bruin
Journal:  Chemistry       Date:  2019-03-29       Impact factor: 5.236

8.  Ligand Redox Noninnocence in [CoIII(TAML)]0/- Complexes Affects Nitrene Formation.

Authors:  Nicolaas P van Leest; Martijn A Tepaske; Jean-Pierre H Oudsen; Bas Venderbosch; Niels R Rietdijk; Maxime A Siegler; Moniek Tromp; Jarl Ivar van der Vlugt; Bas de Bruin
Journal:  J Am Chem Soc       Date:  2019-12-30       Impact factor: 15.419

9.  Catalytic Chemoselective Sulfimidation with an Electrophilic [CoIII (TAML)]- -Nitrene Radical Complex*.

Authors:  Nicolaas P van Leest; Jarl Ivar van der Vlugt; Bas de Bruin
Journal:  Chemistry       Date:  2020-11-19       Impact factor: 5.236

10.  A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N-O Reagent as the "Amino" Source and "Oxidant".

Authors:  Sayanti Chatterjee; Ingolf Harden; Giovanni Bistoni; Rebeca G Castillo; Sonia Chabbra; Maurice van Gastel; Alexander Schnegg; Eckhard Bill; James A Birrell; Bill Morandi; Frank Neese; Serena DeBeer
Journal:  J Am Chem Soc       Date:  2022-02-04       Impact factor: 15.419
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