Literature DB >> 28960973

Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex.

Seungwoo Hong1,2, Xiaoyan Lu1, Yong-Min Lee1, Mi Sook Seo1, Takehiro Ohta3, Takashi Ogura3, Martin Clémancey4, Pascale Maldivi5, Jean-Marc Latour4, Ritimukta Sarangi6, Wonwoo Nam1,7.   

Abstract

A mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [FeV(NTs)(TAML)]- (1), was oxidized by one-electron oxidants, affording formation of an iron(V)-imido TAML cation radical species, [FeV(NTs)(TAML+•)] (2); 2 is a diamagnetic (S = 0) complex, resulting from the antiferromagnetic coupling of the low-spin iron(V) ion (S = 1/2) with the one-electron oxidized ligand (TAML+•). 2 is a competent oxidant in C-H bond functionalization and nitrene transfer reaction, showing that the reactivity of 2 is greater than that of 1.

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Year:  2017        PMID： 28960973      PMCID： PMC5711427          DOI： 10.1021/jacs.7b08161

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  29 in total

1.  Long-range electron transfer triggers mechanistic differences between iron(IV)-oxo and iron(IV)-imido oxidants.

Authors:  Suresh Kumar; Abayomi S Faponle; Prasenjit Barman; Anil Kumar Vardhaman; Chivukula V Sastri; Devesh Kumar; Sam P de Visser
Journal:  J Am Chem Soc       Date:  2014-11-25       Impact factor: 15.419

2.  Molecular designs for controlling the local environments around metal ions.

Authors:  Sarah A Cook; A S Borovik
Journal:  Acc Chem Res       Date:  2015-07-16       Impact factor: 22.384

3.  Oxo-transfer reaction from a bis(mu-oxo)dicopper(III) complex to sulfides.

Authors:  Masayasu Taki; Shinobu Itoh; Shunichi Fukuzumi
Journal:  J Am Chem Soc       Date:  2002-02-13       Impact factor: 15.419

4.  Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds.

Authors:  Mark P Mehn; Steven D Brown; David M Jenkins; Jonas C Peters; Lawrence Que
Journal:  Inorg Chem       Date:  2006-09-04       Impact factor: 5.165

5.  O2 Activation by Non-Heme Iron Enzymes.

Authors:  Edward I Solomon; Serra Goudarzi; Kyle D Sutherlin
Journal:  Biochemistry       Date:  2016-11-14       Impact factor: 3.162

6.  Metal-catalyzed nitrogen-atom transfer methods for the oxidation of aliphatic C-H bonds.

Authors:  Jennifer L Roizen; Mark Edwin Harvey; J Du Bois
Journal:  Acc Chem Res       Date:  2012-04-30       Impact factor: 22.384

7.  Tuning reactivity and mechanism in oxidation reactions by mononuclear nonheme iron(IV)-oxo complexes.

Authors:  Wonwoo Nam; Yong-Min Lee; Shunichi Fukuzumi
Journal:  Acc Chem Res       Date:  2014-02-13       Impact factor: 22.384

8.  X-ray absorption near-edge spectroscopy in bioinorganic chemistry: Application to M-O2 systems.

Authors:  Ritimukta Sarangi
Journal:  Coord Chem Rev       Date:  2012-07-03       Impact factor: 22.315

9.  Nonheme iron-mediated amination of C(sp3)-H bonds. Quinquepyridine-supported iron-imide/nitrene intermediates by experimental studies and DFT calculations.

Authors:  Yungen Liu; Xiangguo Guan; Ella Lai-Ming Wong; Peng Liu; Jie-Sheng Huang; Chi-Ming Che
Journal:  J Am Chem Soc       Date:  2013-05-02       Impact factor: 15.419

10.  Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.

Authors:  Mayank Puri; Lawrence Que
Journal:  Acc Chem Res       Date:  2015-07-15       Impact factor: 22.384
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  9 in total

1.  A Manganese(V)-Oxo Tetraamido Macrocyclic Ligand (TAML) Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies.

Authors:  Deepika G Karmalkar; Xiao-Xi Li; Mi Sook Seo; Muniyandi Sankaralingam; Takehiro Ohta; Ritimukta Sarangi; Seungwoo Hong; Wonwoo Nam
Journal:  Chemistry       Date:  2018-11-19       Impact factor: 5.236

2.  A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450.

Authors:  Xiaoyan Lu; Xiao-Xi Li; Mi Sook Seo; Yong-Min Lee; Martin Clémancey; Pascale Maldivi; Jean-Marc Latour; Ritimukta Sarangi; Shunichi Fukuzumi; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2018-12-20       Impact factor: 15.419

3.  Uncatalyzed Oxidative C-H Amination of 9,10-Dihydro-9-Heteroanthracenes: A Mechanistic Study.

Authors:  Nicolaas P van Leest; Lars Grooten; Jarl Ivar van der Vlugt; Bas de Bruin
Journal:  Chemistry       Date:  2019-03-29       Impact factor: 5.236

4.  Ligand Redox Noninnocence in [CoIII(TAML)]0/- Complexes Affects Nitrene Formation.

Authors:  Nicolaas P van Leest; Martijn A Tepaske; Jean-Pierre H Oudsen; Bas Venderbosch; Niels R Rietdijk; Maxime A Siegler; Moniek Tromp; Jarl Ivar van der Vlugt; Bas de Bruin
Journal:  J Am Chem Soc       Date:  2019-12-30       Impact factor: 15.419

5.  Electronically Asynchronous Transition States for C-N Bond Formation by Electrophilic [CoIII(TAML)]-Nitrene Radical Complexes Involving Substrate-to-Ligand Single-Electron Transfer and a Cobalt-Centered Spin Shuttle.

Authors:  Nicolaas P van Leest; Martijn A Tepaske; Bas Venderbosch; Jean-Pierre H Oudsen; Moniek Tromp; Jarl Ivar van der Vlugt; Bas de Bruin
Journal:  ACS Catal       Date:  2020-06-12       Impact factor: 13.700

6.  C-H activation and nucleophilic substitution in a photochemically generated high valent iron complex.

Authors:  Jia Hui Lim; Xenia Engelmann; Sacha Corby; Rakesh Ganguly; Kallol Ray; Han Sen Soo
Journal:  Chem Sci       Date:  2018-03-23       Impact factor: 9.825

7.  Catalytic Chemoselective Sulfimidation with an Electrophilic [CoIII (TAML)]- -Nitrene Radical Complex*.

Authors:  Nicolaas P van Leest; Jarl Ivar van der Vlugt; Bas de Bruin
Journal:  Chemistry       Date:  2020-11-19       Impact factor: 5.236

8.  Understanding the differences between iron and palladium in cross-coupling reactions.

Authors:  Xiaobo Sun; Marcus V J Rocha; Trevor A Hamlin; Jordi Poater; F Matthias Bickelhaupt
Journal:  Phys Chem Chem Phys       Date:  2019-05-15       Impact factor: 3.676

9.  A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N-O Reagent as the "Amino" Source and "Oxidant".

Authors:  Sayanti Chatterjee; Ingolf Harden; Giovanni Bistoni; Rebeca G Castillo; Sonia Chabbra; Maurice van Gastel; Alexander Schnegg; Eckhard Bill; James A Birrell; Bill Morandi; Frank Neese; Serena DeBeer
Journal:  J Am Chem Soc       Date:  2022-02-04       Impact factor: 15.419
  9 in total

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