Crystal structure of octa-μ3-selenido-(p-toluene-sulfonato-κO)penta-kis-(tri-ethyl-phosphane-κP)-octa-hedro-hexa-rhenium(III) p-toluene-sulfonate di-chloro-methane disolvate.

The title compound, [Re6Se8{O3SC6H4(CH3)}{P(C2H5)3}5](CH3C6H4SO3)·2CH2Cl2, contains the face-capped hexa-nuclear [Re6(μ3-Se)8](2+) cluster core. The [Re6Se8](2+) cluster core displays a non-crystallographic center of symmetry and is bonded through the Re(III) atoms to five tri-ethyl-phosphane ligands and one p-toluene-sulfonate ligand. One p-toluene-sulfonate counter-ion and two di-chloro-methane solvent mol-ecules are also present in the asymmetric unit. One of the ethyl chains of one triethylphos-phane ligand and one of the CH2Cl2 solvent molecules are disordered over two sets of sites (occupancy ratios 0.65:0.35 and 0.5:0.5, respectively). The Re-O(sulfon-ate) bond length of 2.123 (5) Å is similar to other Re-O bond lengths of hexa-nuclear rhenium chalcogenide clusters containing other O-donor ligands such as dimethyl sulfoxide (DMSO), di-methyl-formamide (DMF) and hydroxide.

Related literature

Lindner & Grimmer (1971 ▸) reported the insertion of sulfur trioxide into the Re-alkyl bond of (p-tol­yl)n class="Chemical">Re(CO)5 to generate the first example of a rhenium complex to contain a tosyl­ate moiety. Later, Eremenko et al. (1993 ▸) determined the structure of [Re(P(OiPr)3)2(CO)(NO)(OTs)2] (OTs− = p-toluene­sulfonate anion) which represented the first structural report of a rhenium complex containing tosyl­ate ligands. In the synthesis of octa­hedral rhenium chalcogenide cluster complexes, the substitution of either halide or nitrile ligands has proven an effective means for generating a variety of new cluster complexes (Zheng & Holm, 1997 ▸; Knott et al., 2013 ▸; Yoshimura et al., 2000 ▸). Nitrile ligands are often considered weakly coordinating and substitution of alkyl and aryl nitrile ligands has often been used in single metal chemistry (Endres, 1987 ▸) and in the preparation of [Re6 Q 8]2+ (Q = S or Se) cluster complexes (Zheng & Holm, 1997 ▸; Durham et al., 2012 ▸). However, there have been reports of the hexa­nuclear rhenium selenide cluster core, [Re6Se8]2+, activating nitriles to undergo reactions other than substitution (Orto et al., 2007 ▸; Szczepura et al., 2007 ▸). While structural reports of rhenium chalcogenide clusters containing other oxygen donor ligands have been previously reported (Dorson et al., 2009 ▸; Mironov et al., 2011 ▸; Zheng & Holm, 1997 ▸; Zheng et al., 1999 ▸), this report represents the first example of tosyl­ate coordination to a [Re6 Q 8]2+ cluster core. The average Re—P bond length of the five terminal PEt3 ligands in the title compound [2.479 Å] is similar to that in other rhenium selenide clusters containing PEt3 ligands (Durham et al., 2012 ▸, 2015 ▸; Knott et al., 2013 ▸; Zheng & Holm, 1997 ▸; Zheng et al., 1999 ▸).

Experimental

Crystal data

[Re6Se8(C7H7O3S)(C6H15P)5](C7H7O3S)·2CH2Cl2

M = 2851.85

Triclinic,

a = 11.7432 (10) Å

b = 16.6878 (14) Å

c = 18.9786 (16) Å

α = 93.4729 (11)°

β = 95.9862 (12)°

γ = 100.0851 (11)°

V = 3629.9 (5) Å3

Z = 2

Mo Kα radiation

μ = 14.33 mm−1

T = 193 K

0.48 × 0.28 × 0.10 mm

Data collection

Bruker PLATFORM/SMART 1000 CCD area-detector diffractometer

Absorption correction: integration (SADABS; Sheldrick, 2008 ▸) T min = 0.032, T max = 0.255

31748 measured reflections

16405 independent reflections

11401 reflections with I > 2σ(I)

R int = 0.031

Refinement

R[F 2 > 2σ(F 2)] = 0.036

wR(F 2) = 0.097

S = 1.02

16405 reflections

693 parameters

H-atom parameters constrained

Δρmax = 2.67 e Å−3

Δρmin = −1.26 e Å−3

Data collection: SMART (Bruker, 2006 ▸); cell refinement: SAINT (Bruker, 2006 ▸); data reduction: SAIn class="Chemical">NT; program(s) used to solve structure: DIRDIF99 (Beurskens et al., 2008 ▸); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2015 ▸); molecular graphics: SHELXTL (Sheldrick, 2008 ▸); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) I, isu0804. DOI: 10.1107/S2056989015014334/pj2021sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S2056989015014334/pj2021Isup2.hkl

Click here for additional data file.

6 8 3 5 3 6 4 + . DOI: 10.1107/S2056989015014334/pj2021fig1.tif

Perspective view of the [Re6Se8(PEt3)5(n class="Chemical">O3SC6H4Me)]+ ion showing the atom labelling scheme. Non-hydrogen atoms are represented by Gaussian ellipsoids at the 30% probability level. Hydrogen atoms omitted for clarity.

CCDC reference: 1010097

Additional supporting information: crystallographic information; 3D view; checkCIF report

[Re6Se8(C7H7O3S)(C6H15P)5](C7H7O3S)·2CH2Cl2	Z = 2
Mr = 2851.85	F(000) = 2628
Triclinic, P1	Dx = 2.609 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 11.7432 (10) Å	Cell parameters from 7041 reflections
b = 16.6878 (14) Å	θ = 2.2–27.4°
c = 18.9786 (16) Å	µ = 14.33 mm−1
α = 93.4729 (11)°	T = 193 K
β = 95.9862 (12)°	Prism, orange
γ = 100.0851 (11)°	0.48 × 0.28 × 0.10 mm
V = 3629.9 (5) Å3

Bruker PLATFORM/SMART 1000 CCD area-detector diffractometer	11401 reflections with I > 2σ(I)
Detector resolution: 8.192 pixels mm-1	Rint = 0.031
ω scans	θmax = 27.5°, θmin = 1.7°
Absorption correction: integration (SADABS; Sheldrick, 2008)	h = −15→15
Tmin = 0.032, Tmax = 0.255	k = −21→21
31748 measured reflections	l = −24→24
16405 independent reflections

Refinement on F2	0 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.036	H-atom parameters constrained
wR(F2) = 0.097	w = 1/[σ2(Fo2) + (0.038P)2 + 7.5887P] where P = (Fo2 + 2Fc2)/3
S = 1.02	(Δ/σ)max = 0.001
16405 reflections	Δρmax = 2.67 e Å−3
693 parameters	Δρmin = −1.26 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Re1	0.12366 (2)	0.35432 (2)	0.22926 (2)	0.02007 (6)
Re2	0.16617 (2)	0.29786 (2)	0.10389 (2)	0.02159 (7)
Re3	0.13895 (2)	0.19879 (2)	0.20606 (2)	0.02062 (7)
Re4	0.30352 (2)	0.29772 (2)	0.29017 (2)	0.02004 (6)
Re5	0.33294 (2)	0.39696 (2)	0.18802 (2)	0.02136 (7)
Re6	0.34623 (2)	0.24274 (2)	0.16411 (2)	0.02221 (7)
Se1	−0.02863 (6)	0.25580 (4)	0.14801 (3)	0.02465 (15)
Se2	0.10186 (6)	0.25694 (4)	0.32525 (3)	0.02334 (14)
Se3	0.28647 (6)	0.44606 (4)	0.30833 (3)	0.02378 (14)
Se4	0.15816 (6)	0.44579 (4)	0.12967 (4)	0.02754 (16)
Se5	0.18447 (6)	0.15003 (4)	0.08552 (3)	0.02631 (15)
Se6	0.31453 (6)	0.14981 (4)	0.26240 (4)	0.02578 (15)
Se7	0.49890 (6)	0.33842 (4)	0.24662 (4)	0.02539 (15)
Se8	0.36656 (6)	0.34011 (4)	0.06760 (4)	0.02695 (15)
S1	0.58942 (18)	0.19272 (12)	0.10790 (11)	0.0404 (5)
P1	−0.02451 (16)	0.42936 (10)	0.27116 (10)	0.0267 (4)
P2	0.06449 (18)	0.29468 (11)	−0.01759 (9)	0.0289 (4)
P3	0.01218 (17)	0.06768 (10)	0.22232 (10)	0.0277 (4)
P4	0.39486 (17)	0.29590 (11)	0.41376 (9)	0.0266 (4)
P5	0.47147 (19)	0.52475 (11)	0.17694 (10)	0.0357 (5)
O1	0.4663 (4)	0.1748 (3)	0.1248 (3)	0.0323 (11)
O2	0.6306 (5)	0.2788 (3)	0.1027 (3)	0.0562 (17)
O3	0.6607 (5)	0.1522 (4)	0.1537 (3)	0.0618 (18)
C1	0.5763 (8)	0.1441 (5)	0.0219 (5)	0.046 (2)
C2	0.6345 (11)	0.0810 (7)	0.0078 (6)	0.083 (4)
H2	0.6805	0.0625	0.0456	0.100*
C3	0.6272 (11)	0.0436 (7)	−0.0609 (6)	0.077 (3)
H3	0.6694	0.0011	−0.0697	0.092*
C4	0.5604 (10)	0.0679 (6)	−0.1147 (6)	0.064 (3)
C5	0.4992 (13)	0.1288 (8)	−0.1005 (6)	0.108 (5)
H5	0.4500	0.1456	−0.1375	0.130*
C6	0.5091 (13)	0.1662 (9)	−0.0313 (6)	0.122 (6)
H6	0.4667	0.2085	−0.0224	0.146*
C7	0.5535 (11)	0.0278 (7)	−0.1896 (6)	0.083 (4)
H7A	0.6287	0.0130	−0.1970	0.100*
H7B	0.5344	0.0662	−0.2242	0.100*
H7C	0.4929	−0.0214	−0.1958	0.100*
C11	−0.0042 (7)	0.4563 (4)	0.3667 (4)	0.0351 (17)
H11A	−0.0040	0.4056	0.3910	0.042*
H11B	0.0737	0.4910	0.3791	0.042*
C12	−0.0937 (8)	0.5010 (5)	0.3965 (4)	0.046 (2)
H12A	−0.0747	0.5115	0.4482	0.055*
H12B	−0.1715	0.4672	0.3857	0.055*
H12C	−0.0925	0.5530	0.3749	0.055*
C13	−0.1760 (7)	0.3747 (4)	0.2540 (4)	0.0373 (18)
H13A	−0.2280	0.4115	0.2693	0.045*
H13B	−0.1959	0.3610	0.2022	0.045*
C14	−0.1991 (7)	0.2963 (4)	0.2920 (4)	0.0391 (18)
H14A	−0.2825	0.2732	0.2845	0.047*
H14B	−0.1742	0.3086	0.3430	0.047*
H14C	−0.1552	0.2568	0.2729	0.047*
C15	−0.0325 (7)	0.5260 (4)	0.2323 (4)	0.0377 (18)
H15A	−0.0461	0.5153	0.1800	0.045*
H15B	−0.1008	0.5465	0.2478	0.045*
C16	0.0724 (8)	0.5918 (4)	0.2507 (4)	0.045 (2)
H16A	0.0568	0.6425	0.2316	0.053*
H16B	0.1388	0.5755	0.2301	0.053*
H16C	0.0905	0.6004	0.3025	0.053*
C21	−0.0445 (7)	0.2022 (5)	−0.0443 (4)	0.0394 (19)
H21A	−0.0043	0.1548	−0.0431	0.047*
H21B	−0.0999	0.1961	−0.0082	0.047*
C22	−0.1147 (8)	0.1979 (5)	−0.1174 (4)	0.049 (2)
H22A	−0.1685	0.1454	−0.1261	0.059*
H22B	−0.0616	0.2030	−0.1540	0.059*
H22C	−0.1590	0.2425	−0.1188	0.059*
C23	0.1580 (7)	0.3016 (5)	−0.0883 (4)	0.0392 (19)
H23A	0.1103	0.3071	−0.1333	0.047*
H23B	0.2176	0.3520	−0.0780	0.047*
C24	0.2195 (8)	0.2302 (5)	−0.0994 (4)	0.046 (2)
H24A	0.2675	0.2394	−0.1384	0.055*
H24B	0.1617	0.1800	−0.1111	0.055*
H24C	0.2693	0.2250	−0.0557	0.055*
C25	−0.0151 (7)	0.3782 (5)	−0.0342 (4)	0.0410 (19)
H25A	0.0408	0.4305	−0.0252	0.049*
H25B	−0.0466	0.3727	−0.0850	0.049*
C26	−0.1155 (8)	0.3824 (5)	0.0105 (5)	0.053 (2)
H26A	−0.1515	0.4293	−0.0013	0.064*
H26B	−0.0856	0.3884	0.0611	0.064*
H26C	−0.1737	0.3321	0.0004	0.064*
C31	−0.0210 (8)	−0.0054 (4)	0.1442 (4)	0.042 (2)
H31A	0.0532	−0.0123	0.1263	0.051*
H31B	−0.0572	−0.0588	0.1592	0.051*
C32	−0.0993 (9)	0.0163 (5)	0.0844 (4)	0.058 (3)
H32A	−0.1149	−0.0281	0.0464	0.069*
H32B	−0.0618	0.0666	0.0660	0.069*
H32C	−0.1728	0.0244	0.1013	0.069*
C33	−0.1291 (7)	0.0800 (5)	0.2480 (4)	0.0395 (19)
H33A	−0.1165	0.1133	0.2941	0.047*
H33B	−0.1665	0.1110	0.2123	0.047*
C34	−0.2127 (8)	0.0017 (5)	0.2552 (5)	0.055 (2)
H34A	−0.2861	0.0147	0.2687	0.066*
H34B	−0.1784	−0.0288	0.2918	0.066*
H34C	−0.2277	−0.0315	0.2097	0.066*
C35	0.0707 (7)	0.0060 (4)	0.2885 (4)	0.0348 (17)
H35A	0.0161	−0.0467	0.2865	0.042*
H35B	0.1452	−0.0060	0.2745	0.042*
C36	0.0925 (8)	0.0420 (5)	0.3650 (4)	0.046 (2)
H36A	0.1228	0.0031	0.3953	0.055*
H36B	0.0193	0.0531	0.3805	0.055*
H36C	0.1494	0.0930	0.3687	0.055*
C41	0.5134 (7)	0.3820 (5)	0.4418 (4)	0.0407 (19)
H41A	0.5739	0.3808	0.4093	0.049*
H41B	0.4827	0.4330	0.4357	0.049*
C42	0.5712 (8)	0.3856 (5)	0.5176 (4)	0.050 (2)
H42A	0.6305	0.4353	0.5275	0.060*
H42B	0.6080	0.3377	0.5236	0.060*
H42C	0.5124	0.3861	0.5506	0.060*
C43	0.4584 (7)	0.2066 (4)	0.4322 (4)	0.0375 (19)
H43A	0.4822	0.2090	0.4840	0.045*
H43B	0.3972	0.1575	0.4197	0.045*
C44	0.5638 (8)	0.1958 (5)	0.3935 (5)	0.049 (2)
H44A	0.5945	0.1483	0.4098	0.059*
H44B	0.6244	0.2448	0.4039	0.059*
H44C	0.5399	0.1874	0.3422	0.059*
C45	0.2999 (7)	0.2951 (5)	0.4839 (4)	0.0393 (19)
H45A	0.2359	0.2473	0.4733	0.047*
H45B	0.3451	0.2874	0.5292	0.047*
C46	0.2465 (8)	0.3717 (5)	0.4943 (4)	0.045 (2)
H46A	0.1957	0.3650	0.5322	0.054*
H46B	0.2008	0.3799	0.4500	0.054*
H46C	0.3087	0.4192	0.5075	0.054*
C51	0.6216 (9)	0.5128 (6)	0.1577 (5)	0.064 (3)
H51A	0.6737	0.5665	0.1691	0.076*
H51B	0.6495	0.4747	0.1907	0.076*
C52	0.6356 (9)	0.4832 (6)	0.0850 (5)	0.070 (3)
H52A	0.7187	0.4872	0.0802	0.085*
H52B	0.6011	0.5165	0.0509	0.085*
H52C	0.5964	0.4261	0.0756	0.085*
C53	0.5125 (10)	0.5942 (5)	0.2573 (5)	0.068 (3)
H53A	0.5558	0.6466	0.2444	0.081*
H53B	0.4406	0.6054	0.2758	0.081*
C54	0.5877 (9)	0.5626 (6)	0.3171 (5)	0.067 (3)
H54A	0.6022	0.6021	0.3588	0.080*
H54B	0.6620	0.5556	0.3008	0.080*
H54C	0.5466	0.5101	0.3297	0.080*
C55	0.4257 (12)	0.5886 (6)	0.1134 (6)	0.089 (4)
H55A	0.4962	0.6185	0.0958	0.107*	0.65
H55B	0.3803	0.5530	0.0727	0.107*	0.65
H55C	0.4270	0.5578	0.0673	0.107*	0.35
H55D	0.3422	0.5864	0.1187	0.107*	0.35
C56A	0.3580 (17)	0.6468 (11)	0.1335 (10)	0.085 (5)*	0.65
H56A	0.3389	0.6772	0.0926	0.102*	0.65
H56B	0.4024	0.6848	0.1721	0.102*	0.65
H56C	0.2859	0.6187	0.1495	0.102*	0.65
C56B	0.466 (3)	0.672 (2)	0.1006 (19)	0.094 (11)*	0.35
H56D	0.4193	0.6859	0.0591	0.112*	0.35
H56E	0.5481	0.6785	0.0915	0.112*	0.35
H56F	0.4598	0.7074	0.1423	0.112*	0.35
S2	0.1203 (2)	0.25430 (12)	0.69762 (10)	0.0397 (5)
O4	0.2051 (6)	0.3129 (3)	0.7426 (3)	0.0593 (18)
O5	0.0437 (5)	0.2020 (3)	0.7371 (3)	0.0578 (17)
O6	0.0570 (8)	0.2922 (4)	0.6441 (4)	0.085 (3)
C61	0.1949 (7)	0.1916 (4)	0.6514 (4)	0.0346 (17)
C62	0.1339 (8)	0.1340 (5)	0.5971 (4)	0.0409 (19)
H62	0.0527	0.1310	0.5847	0.049*
C63	0.1924 (9)	0.0821 (5)	0.5618 (5)	0.053 (2)
H63	0.1498	0.0432	0.5257	0.064*
C64	0.3105 (9)	0.0847 (5)	0.5772 (5)	0.050 (2)
C65	0.3699 (8)	0.1410 (5)	0.6309 (5)	0.055 (2)
H65	0.4511	0.1438	0.6432	0.066*
C66	0.3122 (8)	0.1937 (5)	0.6671 (5)	0.046 (2)
H66	0.3551	0.2321	0.7035	0.055*
C67	0.3712 (11)	0.0272 (5)	0.5381 (6)	0.081 (4)
H67A	0.3421	0.0223	0.4874	0.097*
H67B	0.3559	−0.0266	0.5569	0.097*
H67C	0.4552	0.0483	0.5443	0.097*
Cl1S	0.1511 (3)	0.67463 (18)	0.49345 (15)	0.0790 (8)
Cl2S	0.1300 (3)	0.8404 (2)	0.53900 (19)	0.0944 (10)
C1S	0.0595 (10)	0.7443 (7)	0.5080 (6)	0.079 (3)
H1SA	0.0109	0.7478	0.4629	0.094*
H1SB	0.0065	0.7231	0.5427	0.094*
Cl3S	0.2826 (7)	0.8779 (5)	0.3829 (4)	0.105 (3)*	0.5
Cl4S	0.3255 (6)	0.7327 (4)	0.3274 (3)	0.0828 (17)*	0.5
Cl5S	0.3045 (6)	0.9045 (4)	0.3569 (4)	0.0836 (19)*	0.5
Cl6S	0.3205 (7)	0.7571 (5)	0.2778 (4)	0.109 (2)*	0.5
C2S	0.2295 (12)	0.8018 (8)	0.3232 (8)	0.109 (5)
H2SA	0.2221	0.8218	0.2752	0.131*	0.5
H2SB	0.1515	0.7749	0.3332	0.131*	0.5
H2SC	0.2069	0.7694	0.3632	0.131*	0.5
H2SD	0.1580	0.8048	0.2916	0.131*	0.5

	U11	U22	U33	U12	U13	U23
Re1	0.02175 (14)	0.01753 (12)	0.02081 (13)	0.00464 (10)	0.00118 (11)	−0.00026 (9)
Re2	0.02488 (15)	0.01949 (13)	0.01971 (13)	0.00389 (11)	0.00088 (11)	−0.00048 (10)
Re3	0.02332 (15)	0.01668 (12)	0.02117 (13)	0.00340 (10)	0.00110 (11)	−0.00064 (9)
Re4	0.02163 (14)	0.01778 (13)	0.02046 (13)	0.00447 (10)	0.00114 (11)	−0.00061 (9)
Re5	0.02378 (15)	0.01844 (13)	0.02146 (14)	0.00346 (11)	0.00243 (11)	−0.00009 (10)
Re6	0.02424 (15)	0.01994 (13)	0.02252 (14)	0.00545 (11)	0.00282 (11)	−0.00207 (10)
Se1	0.0241 (4)	0.0240 (3)	0.0248 (3)	0.0040 (3)	−0.0001 (3)	−0.0005 (3)
Se2	0.0249 (4)	0.0217 (3)	0.0231 (3)	0.0036 (3)	0.0033 (3)	0.0007 (2)
Se3	0.0261 (4)	0.0196 (3)	0.0246 (3)	0.0035 (3)	0.0019 (3)	−0.0027 (2)
Se4	0.0326 (4)	0.0225 (3)	0.0278 (4)	0.0069 (3)	0.0012 (3)	0.0029 (3)
Se5	0.0310 (4)	0.0220 (3)	0.0246 (3)	0.0045 (3)	0.0014 (3)	−0.0044 (3)
Se6	0.0291 (4)	0.0202 (3)	0.0285 (4)	0.0072 (3)	0.0008 (3)	0.0011 (3)
Se7	0.0235 (4)	0.0252 (3)	0.0271 (4)	0.0050 (3)	0.0021 (3)	−0.0010 (3)
Se8	0.0302 (4)	0.0275 (3)	0.0227 (3)	0.0037 (3)	0.0047 (3)	0.0000 (3)
S1	0.0315 (11)	0.0419 (11)	0.0480 (12)	0.0094 (9)	0.0045 (9)	−0.0030 (9)
P1	0.0279 (10)	0.0244 (9)	0.0291 (9)	0.0091 (8)	0.0029 (8)	0.0005 (7)
P2	0.0353 (11)	0.0283 (9)	0.0227 (9)	0.0068 (8)	0.0001 (8)	0.0017 (7)
P3	0.0296 (10)	0.0206 (8)	0.0299 (10)	−0.0010 (8)	−0.0001 (8)	0.0008 (7)
P4	0.0301 (10)	0.0268 (9)	0.0226 (9)	0.0065 (8)	0.0000 (8)	0.0013 (7)
P5	0.0435 (13)	0.0264 (10)	0.0342 (11)	−0.0022 (9)	0.0063 (9)	0.0013 (8)
O1	0.030 (3)	0.025 (2)	0.041 (3)	0.005 (2)	0.004 (2)	−0.002 (2)
O2	0.046 (4)	0.040 (3)	0.074 (4)	−0.012 (3)	0.015 (3)	−0.012 (3)
O3	0.037 (4)	0.090 (5)	0.062 (4)	0.030 (4)	−0.006 (3)	0.007 (4)
C1	0.040 (5)	0.046 (5)	0.050 (5)	0.010 (4)	0.007 (4)	−0.004 (4)
C2	0.103 (10)	0.093 (9)	0.072 (8)	0.061 (8)	0.018 (7)	0.009 (7)
C3	0.094 (9)	0.070 (7)	0.078 (8)	0.043 (7)	0.020 (7)	−0.003 (6)
C4	0.078 (8)	0.052 (6)	0.064 (7)	0.014 (6)	0.027 (6)	−0.008 (5)
C5	0.147 (13)	0.145 (12)	0.056 (7)	0.106 (11)	0.000 (8)	−0.019 (7)
C6	0.184 (16)	0.161 (13)	0.048 (6)	0.143 (13)	−0.023 (8)	−0.027 (7)
C7	0.102 (10)	0.074 (7)	0.078 (8)	0.023 (7)	0.036 (7)	−0.022 (6)
C11	0.036 (5)	0.034 (4)	0.038 (4)	0.014 (3)	0.008 (4)	−0.002 (3)
C12	0.062 (6)	0.045 (5)	0.034 (4)	0.021 (4)	0.006 (4)	−0.001 (4)
C13	0.042 (5)	0.037 (4)	0.034 (4)	0.017 (4)	−0.008 (4)	0.000 (3)
C14	0.030 (4)	0.042 (4)	0.044 (5)	0.002 (4)	0.008 (4)	0.005 (4)
C15	0.045 (5)	0.029 (4)	0.044 (5)	0.018 (4)	0.008 (4)	0.009 (3)
C16	0.056 (6)	0.028 (4)	0.051 (5)	0.011 (4)	0.013 (4)	0.004 (4)
C21	0.040 (5)	0.040 (4)	0.036 (4)	0.006 (4)	0.000 (4)	0.000 (3)
C22	0.044 (5)	0.056 (5)	0.043 (5)	0.009 (4)	−0.006 (4)	−0.005 (4)
C23	0.051 (5)	0.040 (4)	0.024 (4)	−0.001 (4)	0.006 (4)	0.002 (3)
C24	0.050 (6)	0.053 (5)	0.036 (5)	0.009 (4)	0.011 (4)	−0.002 (4)
C25	0.051 (5)	0.040 (4)	0.032 (4)	0.013 (4)	−0.005 (4)	0.007 (3)
C26	0.058 (6)	0.051 (5)	0.053 (5)	0.030 (5)	−0.010 (5)	0.004 (4)
C31	0.054 (6)	0.025 (4)	0.043 (5)	−0.002 (4)	0.002 (4)	−0.005 (3)
C32	0.067 (7)	0.055 (6)	0.040 (5)	−0.007 (5)	−0.013 (5)	0.000 (4)
C33	0.035 (5)	0.038 (4)	0.043 (5)	−0.001 (4)	0.002 (4)	0.007 (3)
C34	0.042 (5)	0.046 (5)	0.076 (7)	−0.001 (4)	0.004 (5)	0.018 (5)
C35	0.035 (4)	0.022 (3)	0.046 (5)	0.002 (3)	0.004 (4)	0.009 (3)
C36	0.058 (6)	0.037 (4)	0.040 (5)	0.005 (4)	−0.005 (4)	0.012 (4)
C41	0.041 (5)	0.041 (4)	0.039 (4)	0.008 (4)	−0.001 (4)	0.001 (4)
C42	0.050 (6)	0.045 (5)	0.047 (5)	0.003 (4)	−0.013 (4)	−0.012 (4)
C43	0.050 (5)	0.033 (4)	0.034 (4)	0.020 (4)	0.000 (4)	0.008 (3)
C44	0.048 (5)	0.047 (5)	0.057 (5)	0.023 (4)	0.002 (4)	0.003 (4)
C45	0.039 (5)	0.049 (5)	0.031 (4)	0.012 (4)	0.004 (4)	0.004 (3)
C46	0.047 (5)	0.056 (5)	0.034 (4)	0.014 (4)	0.008 (4)	−0.008 (4)
C51	0.060 (7)	0.059 (6)	0.067 (7)	−0.009 (5)	0.010 (5)	0.020 (5)
C52	0.071 (8)	0.053 (6)	0.082 (8)	−0.010 (5)	0.029 (6)	−0.010 (5)
C53	0.090 (8)	0.044 (5)	0.051 (6)	−0.022 (5)	−0.012 (6)	−0.005 (4)
C54	0.070 (7)	0.066 (6)	0.048 (6)	−0.028 (5)	0.004 (5)	−0.005 (5)
C55	0.122 (11)	0.049 (6)	0.087 (8)	0.004 (7)	−0.023 (8)	0.025 (6)
S2	0.0549 (14)	0.0320 (10)	0.0315 (10)	0.0047 (9)	0.0068 (10)	0.0020 (8)
O4	0.069 (5)	0.044 (3)	0.058 (4)	−0.013 (3)	0.025 (3)	−0.013 (3)
O5	0.053 (4)	0.046 (3)	0.074 (4)	−0.002 (3)	0.031 (4)	−0.008 (3)
O6	0.134 (7)	0.088 (5)	0.056 (4)	0.083 (5)	0.015 (4)	0.001 (4)
C61	0.040 (5)	0.026 (4)	0.036 (4)	0.003 (3)	0.001 (4)	0.009 (3)
C62	0.049 (5)	0.040 (4)	0.033 (4)	0.008 (4)	0.004 (4)	0.000 (3)
C63	0.080 (8)	0.038 (5)	0.042 (5)	0.010 (5)	0.013 (5)	−0.004 (4)
C64	0.062 (7)	0.031 (4)	0.057 (6)	0.006 (4)	0.017 (5)	0.004 (4)
C65	0.043 (5)	0.039 (5)	0.088 (7)	0.012 (4)	0.013 (5)	0.021 (5)
C66	0.045 (5)	0.034 (4)	0.054 (5)	−0.001 (4)	0.001 (4)	−0.003 (4)
C67	0.118 (10)	0.045 (6)	0.101 (9)	0.042 (6)	0.058 (8)	0.019 (6)
Cl1S	0.085 (2)	0.0841 (19)	0.0724 (18)	0.0330 (17)	0.0007 (16)	0.0012 (15)
Cl2S	0.084 (2)	0.080 (2)	0.114 (3)	0.0180 (18)	−0.008 (2)	−0.0070 (19)
C1S	0.067 (8)	0.101 (9)	0.068 (7)	0.022 (7)	0.000 (6)	0.005 (7)
C2S	0.077 (10)	0.109 (11)	0.135 (12)	0.022 (8)	−0.012 (9)	−0.020 (9)

Re1—P1	2.4818 (18)	P2—C25	1.833 (7)
Re1—Se2	2.5171 (7)	P3—C33	1.819 (8)
Re1—Se3	2.5199 (7)	P3—C31	1.825 (7)
Re1—Se4	2.5218 (7)	P3—C35	1.825 (7)
Re1—Se1	2.5232 (7)	P4—C43	1.816 (7)
Re1—Re2	2.6341 (4)	P4—C45	1.822 (7)
Re1—Re3	2.6464 (4)	P4—C41	1.826 (8)
Re1—Re4	2.6480 (4)	P5—C55	1.760 (10)
Re1—Re5	2.6486 (4)	P5—C53	1.827 (9)
Re2—P2	2.4765 (18)	P5—C51	1.880 (10)
Re2—Se4	2.5074 (7)	C1—C6	1.327 (13)
Re2—Se8	2.5150 (8)	C1—C2	1.380 (12)
Re2—Se1	2.5168 (7)	C2—C3	1.399 (14)
Re2—Se5	2.5201 (7)	C3—C4	1.347 (14)
Re2—Re3	2.6320 (4)	C4—C5	1.372 (13)
Re2—Re6	2.6321 (4)	C4—C7	1.523 (13)
Re2—Re5	2.6482 (4)	C5—C6	1.403 (14)
Re3—P3	2.4771 (17)	C11—C12	1.526 (10)
Re3—Se6	2.5097 (7)	C13—C14	1.529 (10)
Re3—Se1	2.5144 (7)	C15—C16	1.495 (11)
Re3—Se2	2.5170 (7)	C21—C22	1.528 (10)
Re3—Se5	2.5227 (7)	C23—C24	1.512 (10)
Re3—Re4	2.6322 (4)	C25—C26	1.532 (11)
Re3—Re6	2.6356 (4)	C31—C32	1.487 (11)
Re4—P4	2.4796 (18)	C33—C34	1.513 (10)
Re4—Se7	2.5152 (7)	C35—C36	1.515 (10)
Re4—Se2	2.5167 (7)	C41—C42	1.520 (10)
Re4—Se6	2.5209 (7)	C43—C44	1.535 (11)
Re4—Se3	2.5242 (7)	C45—C46	1.530 (10)
Re4—Re5	2.6360 (4)	C51—C52	1.471 (13)
Re4—Re6	2.6387 (4)	C53—C54	1.540 (13)
Re5—P5	2.4798 (19)	C55—C56A	1.418 (19)
Re5—Se4	2.5148 (8)	C55—C56B	1.43 (3)
Re5—Se7	2.5171 (7)	S2—O4	1.435 (6)
Re5—Se8	2.5171 (7)	S2—O6	1.438 (7)
Re5—Se3	2.5243 (7)	S2—O5	1.441 (6)
Re5—Re6	2.6206 (4)	S2—C61	1.733 (8)
Re6—O1	2.123 (5)	C61—C66	1.373 (11)
Re6—Se6	2.5131 (7)	C61—C62	1.409 (10)
Re6—Se7	2.5149 (7)	C62—C63	1.380 (11)
Re6—Se5	2.5154 (7)	C63—C64	1.380 (13)
Re6—Se8	2.5236 (7)	C64—C65	1.384 (12)
S1—O3	1.426 (6)	C64—C67	1.497 (11)
S1—O2	1.445 (6)	C65—C66	1.391 (11)
S1—O1	1.497 (5)	Cl1S—C1S	1.746 (11)
S1—C1	1.759 (9)	Cl2S—C1S	1.709 (12)
P1—C11	1.821 (7)	Cl3S—C2S	1.639 (14)
P1—C15	1.826 (7)	Cl4S—C2S	1.747 (14)
P1—C13	1.838 (8)	Cl5S—C2S	1.829 (14)
P2—C23	1.818 (7)	Cl6S—C2S	1.684 (14)
P2—C21	1.832 (8)
P1—Re1—Se2	92.64 (4)	Se7—Re5—Re4	58.377 (17)
P1—Re1—Se3	92.22 (5)	Se8—Re5—Re4	119.023 (19)
Se2—Re1—Se3	89.78 (2)	Se3—Re5—Re4	58.524 (17)
P1—Re1—Se4	92.08 (4)	Re6—Re5—Re4	60.260 (10)
Se2—Re1—Se4	175.28 (2)	P5—Re5—Re2	136.47 (5)
Se3—Re1—Se4	89.95 (2)	Se4—Re5—Re2	58.040 (18)
P1—Re1—Se1	91.99 (5)	Se7—Re5—Re2	118.484 (19)
Se2—Re1—Se1	89.41 (2)	Se8—Re5—Re2	58.208 (19)
Se3—Re1—Se1	175.74 (2)	Se3—Re5—Re2	117.88 (2)
Se4—Re1—Se1	90.52 (2)	Re6—Re5—Re2	59.939 (10)
P1—Re1—Re2	134.53 (4)	Re4—Re5—Re2	89.800 (12)
Se2—Re1—Re2	118.069 (18)	P5—Re5—Re1	137.68 (5)
Se3—Re1—Re2	118.568 (19)	Se4—Re5—Re1	58.401 (18)
Se4—Re1—Re2	58.149 (17)	Se7—Re5—Re1	118.507 (19)
Se1—Re1—Re2	58.373 (17)	Se8—Re5—Re1	117.85 (2)
P1—Re1—Re3	135.44 (4)	Se3—Re5—Re1	58.245 (17)
Se2—Re1—Re3	58.284 (16)	Re6—Re5—Re1	90.185 (11)
Se3—Re1—Re3	118.027 (19)	Re4—Re5—Re1	60.143 (10)
Se4—Re1—Re3	117.904 (19)	Re2—Re5—Re1	59.644 (11)
Se1—Re1—Re3	58.147 (17)	O1—Re6—Se6	91.02 (13)
Re2—Re1—Re3	59.793 (9)	O1—Re6—Se7	94.31 (13)
P1—Re1—Re4	135.62 (4)	Se6—Re6—Se7	89.57 (2)
Se2—Re1—Re4	58.255 (17)	O1—Re6—Se5	88.99 (13)
Se3—Re1—Re4	58.415 (17)	Se6—Re6—Se5	89.52 (2)
Se4—Re1—Re4	117.82 (2)	Se7—Re6—Se5	176.59 (2)
Se1—Re1—Re4	117.766 (18)	O1—Re6—Se8	92.75 (13)
Re2—Re1—Re4	89.846 (12)	Se6—Re6—Se8	176.16 (2)
Re3—Re1—Re4	59.625 (10)	Se7—Re6—Se8	90.87 (2)
P1—Re1—Re5	135.03 (4)	Se5—Re6—Se8	89.82 (2)
Se2—Re1—Re5	117.935 (19)	O1—Re6—Re5	137.09 (13)
Se3—Re1—Re5	58.408 (17)	Se6—Re6—Re5	118.684 (18)
Se4—Re1—Re5	58.147 (18)	Se7—Re6—Re5	58.655 (17)
Se1—Re1—Re5	118.510 (19)	Se5—Re6—Re5	119.115 (19)
Re2—Re1—Re5	60.172 (10)	Se8—Re6—Re5	58.553 (17)
Re3—Re1—Re5	89.532 (11)	O1—Re6—Re2	133.56 (13)
Re4—Re1—Re5	59.693 (11)	Se6—Re6—Re2	118.24 (2)
P2—Re2—Se4	92.27 (4)	Se7—Re6—Re2	119.176 (19)
P2—Re2—Se8	94.73 (5)	Se5—Re6—Re2	58.571 (17)
Se4—Re2—Se8	88.80 (2)	Se8—Re6—Re2	58.348 (18)
P2—Re2—Se1	88.81 (5)	Re5—Re6—Re2	60.551 (10)
Se4—Re2—Se1	91.00 (2)	O1—Re6—Re3	132.52 (13)
Se8—Re2—Se1	176.46 (2)	Se6—Re6—Re3	58.289 (18)
P2—Re2—Se5	91.59 (4)	Se7—Re6—Re3	118.238 (19)
Se4—Re2—Se5	176.02 (3)	Se5—Re6—Re3	58.592 (18)
Se8—Re2—Se5	89.92 (2)	Se8—Re6—Re3	118.29 (2)
Se1—Re2—Se5	90.05 (2)	Re5—Re6—Re3	90.372 (12)
P2—Re2—Re3	132.58 (5)	Re2—Re6—Re3	59.953 (11)
Se4—Re2—Re3	118.978 (19)	O1—Re6—Re4	136.22 (13)
Se8—Re2—Re3	118.744 (19)	Se6—Re6—Re4	58.533 (17)
Se1—Re2—Re3	58.412 (17)	Se7—Re6—Re4	58.365 (17)
Se5—Re2—Re3	58.587 (17)	Se5—Re6—Re4	118.46 (2)
P2—Re2—Re6	136.88 (5)	Se8—Re6—Re4	118.677 (19)
Se4—Re2—Re6	117.82 (2)	Re5—Re6—Re4	60.158 (9)
Se8—Re2—Re6	58.667 (18)	Re2—Re6—Re4	90.092 (12)
Se1—Re2—Re6	118.490 (19)	Re3—Re6—Re4	59.875 (10)
Se5—Re2—Re6	58.400 (18)	Re3—Se1—Re2	63.085 (19)
Re3—Re2—Re6	60.089 (10)	Re3—Se1—Re1	63.381 (19)
P2—Re2—Re1	132.79 (5)	Re2—Se1—Re1	63.019 (19)
Se4—Re2—Re1	58.681 (17)	Re4—Se2—Re3	63.055 (17)
Se8—Re2—Re1	118.468 (19)	Re4—Se2—Re1	63.477 (17)
Se1—Re2—Re1	58.608 (17)	Re3—Se2—Re1	63.431 (18)
Se5—Re2—Re1	118.907 (18)	Re1—Se3—Re4	63.332 (17)
Re3—Re2—Re1	60.335 (11)	Re1—Se3—Re5	63.346 (18)
Re6—Re2—Re1	90.250 (12)	Re4—Se3—Re5	62.950 (16)
P2—Re2—Re5	137.53 (5)	Re2—Se4—Re5	63.646 (18)
Se4—Re2—Re5	58.314 (18)	Re2—Se4—Re1	63.170 (17)
Se8—Re2—Re5	58.284 (18)	Re5—Se4—Re1	63.452 (18)
Se1—Re2—Re5	118.757 (19)	Re6—Se5—Re2	63.029 (18)
Se5—Re2—Re5	117.90 (2)	Re6—Se5—Re3	63.085 (18)
Re3—Re2—Re5	89.848 (12)	Re2—Se5—Re3	62.925 (17)
Re6—Re2—Re5	59.510 (11)	Re3—Se6—Re6	63.300 (18)
Re1—Re2—Re5	60.184 (11)	Re3—Se6—Re4	63.097 (17)
P3—Re3—Se6	91.08 (5)	Re6—Se6—Re4	63.225 (17)
P3—Re3—Se1	92.48 (5)	Re6—Se7—Re4	63.279 (19)
Se6—Re3—Se1	176.42 (2)	Re6—Se7—Re5	62.771 (19)
P3—Re3—Se2	90.40 (5)	Re4—Se7—Re5	63.177 (19)
Se6—Re3—Se2	90.67 (2)	Re2—Se8—Re5	63.508 (18)
Se1—Re3—Se2	89.61 (2)	Re2—Se8—Re6	62.985 (18)
P3—Re3—Se5	93.57 (5)	Re5—Se8—Re6	62.651 (18)
Se6—Re3—Se5	89.43 (2)	O3—S1—O2	116.5 (4)
Se1—Re3—Se5	90.05 (2)	O3—S1—O1	109.9 (3)
Se2—Re3—Se5	176.03 (2)	O2—S1—O1	112.6 (3)
P3—Re3—Re2	136.60 (4)	O3—S1—C1	107.8 (4)
Se6—Re3—Re2	118.36 (2)	O2—S1—C1	107.2 (4)
Se1—Re3—Re2	58.503 (17)	O1—S1—C1	101.5 (4)
Se2—Re3—Re2	118.150 (18)	C11—P1—C15	104.1 (3)
Se5—Re3—Re2	58.489 (17)	C11—P1—C13	103.7 (4)
P3—Re3—Re4	133.15 (4)	C15—P1—C13	102.5 (4)
Se6—Re3—Re4	58.659 (17)	C11—P1—Re1	113.8 (2)
Se1—Re3—Re4	118.683 (19)	C15—P1—Re1	115.6 (3)
Se2—Re3—Re4	58.467 (18)	C13—P1—Re1	115.5 (2)
Se5—Re3—Re4	118.44 (2)	C23—P2—C21	104.3 (4)
Re2—Re3—Re4	90.236 (12)	C23—P2—C25	101.6 (4)
P3—Re3—Re6	135.68 (5)	C21—P2—C25	104.0 (4)
Se6—Re3—Re6	58.412 (18)	C23—P2—Re2	115.3 (3)
Se1—Re3—Re6	118.449 (19)	C21—P2—Re2	114.2 (3)
Se2—Re3—Re6	118.558 (19)	C25—P2—Re2	115.9 (3)
Se5—Re3—Re6	58.323 (18)	C33—P3—C31	104.8 (4)
Re2—Re3—Re6	59.958 (10)	C33—P3—C35	105.1 (4)
Re4—Re3—Re6	60.120 (11)	C31—P3—C35	101.1 (3)
P3—Re3—Re1	134.37 (5)	C33—P3—Re3	113.3 (2)
Se6—Re3—Re1	118.850 (19)	C31—P3—Re3	115.3 (3)
Se1—Re3—Re1	58.472 (17)	C35—P3—Re3	115.8 (2)
Se2—Re3—Re1	58.286 (16)	C43—P4—C45	100.0 (3)
Se5—Re3—Re1	118.346 (18)	C43—P4—C41	104.2 (4)
Re2—Re3—Re1	59.872 (10)	C45—P4—C41	104.4 (4)
Re4—Re3—Re1	60.217 (10)	C43—P4—Re4	115.6 (3)
Re6—Re3—Re1	89.907 (11)	C45—P4—Re4	117.0 (3)
P4—Re4—Se7	91.66 (5)	C41—P4—Re4	113.8 (3)
P4—Re4—Se2	92.20 (5)	C55—P5—C53	102.8 (5)
Se7—Re4—Se2	176.14 (2)	C55—P5—C51	105.0 (6)
P4—Re4—Se6	91.66 (4)	C53—P5—C51	98.4 (5)
Se7—Re4—Se6	89.39 (2)	C55—P5—Re5	115.9 (4)
Se2—Re4—Se6	90.42 (2)	C53—P5—Re5	116.1 (3)
P4—Re4—Se3	92.64 (4)	C51—P5—Re5	116.3 (3)
Se7—Re4—Se3	90.21 (2)	S1—O1—Re6	136.5 (3)
Se2—Re4—Se3	89.69 (2)	C6—C1—C2	118.0 (9)
Se6—Re4—Se3	175.69 (2)	C6—C1—S1	121.1 (7)
P4—Re4—Re3	134.62 (4)	C2—C1—S1	120.9 (8)
Se7—Re4—Re3	118.358 (19)	C1—C2—C3	121.2 (10)
Se2—Re4—Re3	58.478 (17)	C4—C3—C2	120.1 (10)
Se6—Re4—Re3	58.244 (18)	C3—C4—C5	118.9 (10)
Se3—Re4—Re3	118.399 (19)	C3—C4—C7	120.0 (9)
P4—Re4—Re5	135.26 (4)	C5—C4—C7	121.1 (11)
Se7—Re4—Re5	58.446 (17)	C4—C5—C6	120.1 (11)
Se2—Re4—Re5	118.418 (18)	C1—C6—C5	121.7 (10)
Se6—Re4—Re5	117.818 (19)	C12—C11—P1	116.8 (6)
Se3—Re4—Re5	58.526 (17)	C14—C13—P1	113.7 (5)
Re3—Re4—Re5	90.112 (12)	C16—C15—P1	115.6 (6)
P4—Re4—Re6	134.67 (4)	C22—C21—P2	117.0 (6)
Se7—Re4—Re6	58.355 (17)	C24—C23—P2	115.5 (5)
Se2—Re4—Re6	118.454 (18)	C26—C25—P2	115.4 (5)
Se6—Re4—Re6	58.243 (17)	C32—C31—P3	116.0 (6)
Se3—Re4—Re6	118.087 (18)	C34—C33—P3	115.7 (6)
Re3—Re4—Re6	60.005 (11)	C36—C35—P3	117.2 (5)
Re5—Re4—Re6	59.582 (11)	C42—C41—P4	116.5 (6)
P4—Re4—Re1	135.52 (4)	C44—C43—P4	116.2 (5)
Se7—Re4—Re1	118.598 (19)	C46—C45—P4	115.5 (5)
Se2—Re4—Re1	58.268 (17)	C52—C51—P5	117.6 (8)
Se6—Re4—Re1	118.376 (19)	C54—C53—P5	114.8 (7)
Se3—Re4—Re1	58.254 (17)	C56A—C55—P5	119.1 (12)
Re3—Re4—Re1	60.158 (11)	C56B—C55—P5	133.1 (18)
Re5—Re4—Re1	60.164 (10)	O4—S2—O6	112.0 (4)
Re6—Re4—Re1	89.807 (12)	O4—S2—O5	112.8 (4)
P5—Re5—Se4	94.95 (5)	O6—S2—O5	112.1 (5)
P5—Re5—Se7	89.06 (5)	O4—S2—C61	107.5 (4)
Se4—Re5—Se7	175.97 (2)	O6—S2—C61	105.4 (4)
P5—Re5—Se8	90.90 (5)	O5—S2—C61	106.5 (3)
Se4—Re5—Se8	88.59 (2)	C66—C61—C62	117.8 (7)
Se7—Re5—Se8	90.97 (2)	C66—C61—S2	122.5 (6)
P5—Re5—Se3	93.06 (5)	C62—C61—S2	119.7 (6)
Se4—Re5—Se3	90.01 (2)	C63—C62—C61	119.9 (8)
Se7—Re5—Se3	90.17 (2)	C62—C63—C64	122.4 (9)
Se8—Re5—Se3	175.91 (2)	C63—C64—C65	117.5 (8)
P5—Re5—Re6	132.11 (5)	C63—C64—C67	121.0 (9)
Se4—Re5—Re6	117.978 (19)	C65—C64—C67	121.5 (10)
Se7—Re5—Re6	58.574 (17)	C64—C65—C66	120.9 (9)
Se8—Re5—Re6	58.797 (17)	C61—C66—C65	121.6 (8)
Se3—Re5—Re6	118.763 (18)	Cl2S—C1S—Cl1S	114.6 (7)
P5—Re5—Re4	133.61 (5)	Cl3S—C2S—Cl4S	107.5 (8)
Se4—Re5—Re4	118.52 (2)	Cl6S—C2S—Cl5S	108.3 (8)