Literature DB >> 26041404

Organometallic rhenium(III) chalcogenide clusters: coordination of N-heterocyclic carbenes.

Jessica L Durham1, Wade B Wilson, Daniel N Huh, Robert McDonald, Lisa F Szczepura.   

Abstract

The preparation of rhenium based octahedral clusters containing N-heterocyclic carbenes is described. These represent the first examples of [M6(μ3-Q)8](n+) or [M6(μ3-X)8](n+) clusters to contain a carbene ligand of any type (NHC, Fischer or Schrock). Surprisingly, the NHC ligands attenuate their luminescent properties.

Entities:  

Year:  2015        PMID: 26041404     DOI: 10.1039/c5cc03215f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Crystal structure of octa-μ3-selenido-(p-toluene-sulfonato-κO)penta-kis-(tri-ethyl-phosphane-κP)-octa-hedro-hexa-rhenium(III) p-toluene-sulfonate di-chloro-methane disolvate.

Authors:  Julia A Edwards; Robert McDonald; Lisa F Szczepura
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-08-06
  1 in total

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