Literature DB >> 19462649

Selective functionalisation of Re6 cluster anionic units: from hexa-hydroxo [Re6Q8(OH)6]4- (Q = S, Se) to neutral trans-[Re6Q8L4L'2] hybrid building blocks.

Frédérick Dorson1, Yann Molard, Stéphane Cordier, Bruno Fabre, Olga Efremova, David Rondeau, Yuri Mironov, Viorel Cîrcu, Nikolay Naumov, Christiane Perrin.   

Abstract

The reaction of [Re6Q(i)8(OH)(a)6]4- (Q = S, Se) with p-tert-butylpyridine (TBP) in water leads to neutral trans-[Re6Q8(TBP)4(OH)2] whose hydroxyl reactivity with carboxylic acid and TBP exchange reaction with functional pyridine have been investigated.

Entities:  

Year:  2009        PMID： 19462649     DOI： 10.1039/b822105g

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  5 in total

1.  Crystal structure of octa-μ3-selenido-(p-toluene-sulfonato-κO)penta-kis-(tri-ethyl-phosphane-κP)-octa-hedro-hexa-rhenium(III) p-toluene-sulfonate di-chloro-methane disolvate.

Authors:  Julia A Edwards; Robert McDonald; Lisa F Szczepura
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-08-06

2.  One-dimensional lead iodide hybrid stabilized by inorganic hexarhenium cluster cations as a new broad-band emitter.

Authors:  Giang Thi Ly; Jun Choi; Youngmee Kim; Yuna Kim; Sujin Kim; So-Hyeon Yang; Sung-Jin Kim
Journal:  RSC Adv       Date:  2021-07-13       Impact factor: 4.036

3.  Tuning the Ground- and Excited-State Redox Potentials of Octahedral Hexanuclear Rhenium(III) Complexes by the Combination of Terminal Halide and N-Heteroaromatic Ligands.

Authors:  Takashi Yoshimura; Hayato Nishizawa; Kojiro Nagata; Akitaka Ito; Eri Sakuda; Shoji Ishizaka; Noboru Kitamura; Atsushi Shinohara
Journal:  ACS Omega       Date:  2022-07-21

4.  Supramolecular Frameworks Based on Rhenium Clusters Using the Synthons Approach.

Authors:  Nathalie Audebrand; Antoine Demont; Racha El Osta; Yuri V Mironov; Nikolay G Naumov; Stéphane Cordier
Journal:  Molecules       Date:  2021-05-01       Impact factor: 4.411

5.  Octa-μ3-selenido-penta-kis-(tri-ethyl-phos-phane-κP)(tri-methyl-aceto-nitrile-κN)-octa-hedro-hexa-rhenium(III) bis-(hexa-fluorido-anti-monate) tri-methyl-aceto-nitrile monosolvate.

Authors:  YiXin Ren; Andrea M Bruck; Lisa F Szczepura
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-06-04
  5 in total

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