| Literature DB >> 17458960 |
Peter Orto1, Hugh D Selby, Daniel Ferris, Jenine R Maeyer, Zhiping Zheng.
Abstract
The addition of methanol and ethanol to the previously reported cluster solvates [Re6(mu3-Se)8(PEt3)5(MeCN)](SbF6)2 and trans-[Re6(mu3-Se)8(PEt3)4(CH3CN)2][SbF6]2 afforded three cluster complexes with imino ester ligands: {Re6(mu3-Se)8(PEt3)5[HN=C(OCH3)(CH3)]}(SbF6)2, {Re6(mu3-Se)8(PEt3)5[HN=C(OCH2CH3)(CH3)]}{SbF6}2, and trans-{Re6(mu3-Se)8(PEt3)4[HN=C(OCH3)(CH3)]2}{SbF6}2. In all cases, predominant formation of the Z isomers was observed.Entities:
Year: 2007 PMID： 17458960 DOI： 10.1021/ic7004985
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165