Literature DB >> 22807319

Continuous-flow hydrogenation of carbon dioxide to pure formic acid using an integrated scCO2 process with immobilized catalyst and base.

Sebastian Wesselbaum1, Ulrich Hintermair, Walter Leitner.   

Abstract

Dual role for CO(2): Pure formic acid can be obtained continuously by hydrogenation of CO(2) in a single processing unit. An immobilized ruthenium organometallic catalyst and a nonvolatile base in an ionic liquid (IL) are combined with supercritical CO(2) as both reactant and extractive phase.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 22807319     DOI： 10.1002/anie.201203185

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

1.  Direct Conversion of Glycerol into Formic Acid via Water Stable Pd(II) Catalyzed Oxidative Carbon-Carbon Bond Cleavage.

Authors:  Prasanna Pullanikat; Joo Ho Lee; Kyung Soo Yoo; Kyung Woon Jung
Journal:  Tetrahedron Lett       Date:  2013-08-14       Impact factor: 2.415

Review 2.  CO2 Hydrogenation Catalyzed by Graphene-Based Materials.

Authors:  Maria Mihet; Monica Dan; Mihaela D Lazar
Journal:  Molecules       Date:  2022-05-24       Impact factor: 4.927

3.  Photocatalytic Formic Acid Conversion on CdS Nanocrystals with Controllable Selectivity for H2 or CO.

Authors:  Moritz F Kuehnel; David W Wakerley; Katherine L Orchard; Erwin Reisner
Journal:  Angew Chem Int Ed Engl       Date:  2015-07-16       Impact factor: 15.336

4.  Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO2 Hydrogenation: Integrated Reaction and Catalyst Separation for CO2 -Scrubbing Solutions.

Authors:  Martin Scott; Beatriz Blas Molinos; Christian Westhues; Giancarlo Franciò; Walter Leitner
Journal:  ChemSusChem       Date:  2017-02-17       Impact factor: 8.928

5.  Integrated CO2 capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow.

Authors:  Niraj K Vishwakarma; Ajay K Singh; Yoon-Ho Hwang; Dong-Hyeon Ko; Jin-Oh Kim; A Giridhar Babu; Dong-Pyo Kim
Journal:  Nat Commun       Date:  2017-03-06       Impact factor: 14.919

Review 6.  CO2 Capture and in situ Catalytic Transformation.

Authors:  Hong-Chen Fu; Fei You; Hong-Ru Li; Liang-Nian He
Journal:  Front Chem       Date:  2019-07-24       Impact factor: 5.221

7.  Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media.

Authors:  Séverine Moret; Paul J Dyson; Gábor Laurenczy
Journal:  Nat Commun       Date:  2014-06-02       Impact factor: 14.919

Review 8.  Unlocking the potential of supported liquid phase catalysts with supercritical fluids: low temperature continuous flow catalysis with integrated product separation.

Authors:  Giancarlo Franciò; Ulrich Hintermair; Walter Leitner
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2015-12-28       Impact factor: 4.226

9.  Selective Hydrogenation of Aldehydes Using a Well-Defined Fe(II) PNP Pincer Complex in Biphasic Medium.

Authors:  Stefan Weber; Julian Brünig; Veronika Zeindlhofer; Christian Schröder; Berthold Stöger; Andreas Limbeck; Karl Kirchner; Katharina Bica
Journal:  ChemCatChem       Date:  2018-08-22       Impact factor: 5.686

10.  Polyol Process Coupled to Cold Plasma as a New and Efficient Nanohydride Processing Method: Nano-Ni2H as a Case Study.

Authors:  Sonia Haj-Khlifa; Sophie Nowak; Patricia Beaunier; Patricia De Rango; Michaël Redolfi; Souad Ammar-Merah
Journal:  Nanomaterials (Basel)       Date:  2020-01-12       Impact factor: 5.076
  10 in total

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