Literature DB >> 23721290

A mononuclear non-heme high-spin iron(III)-hydroperoxo complex as an active oxidant in sulfoxidation reactions.

Yun Mi Kim1, Kyung-Bin Cho, Jaeheung Cho, Binju Wang, Chunsen Li, Sason Shaik, Wonwoo Nam.   

Abstract

We report the first direct experimental evidence showing that a high-spin iron(III)-hydroperoxo complex bearing an N-methylated cyclam ligand can oxidize thioanisoles. DFT calculations showed that the reaction pathway involves heterolytic O-O bond cleavage and that the choice of the heterolytic pathway versus the homolytic pathway is dependent on the spin state and the number of electrons in the d(xz) orbital of the Fe(III)-OOH species.

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Year:  2013        PMID： 23721290     DOI： 10.1021/ja404152q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

Review 1.  Mono- and binuclear non-heme iron chemistry from a theoretical perspective.

Authors:  Tibor András Rokob; Jakub Chalupský; Daniel Bím; Prokopis C Andrikopoulos; Martin Srnec; Lubomír Rulíšek
Journal:  J Biol Inorg Chem       Date:  2016-05-26       Impact factor: 3.358

2.  Nuclear Resonance Vibrational Spectroscopic Definition of Peroxy Intermediates in Nonheme Iron Sites.

Authors:  Kyle D Sutherlin; Lei V Liu; Yong-Min Lee; Yeonju Kwak; Yoshitaka Yoda; Makina Saito; Masayuki Kurokuzu; Yasuhiro Kobayashi; Makoto Seto; Lawrence Que; Wonwoo Nam; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2016-10-19       Impact factor: 15.419

3.  Arene activation by a nonheme iron(III)-hydroperoxo complex: pathways leading to phenol and ketone products.

Authors:  Abayomi S Faponle; Frédéric Banse; Sam P de Visser
Journal:  J Biol Inorg Chem       Date:  2016-04-20       Impact factor: 3.358

4.  Reactivity of a Cobalt(III)-Hydroperoxo Complex in Electrophilic Reactions.

Authors:  Bongki Shin; Kyle D Sutherlin; Takehiro Ohta; Takashi Ogura; Edward I Solomon; Jaeheung Cho
Journal:  Inorg Chem       Date:  2016-11-15       Impact factor: 5.165

5.  NRVS Studies of the Peroxide Shunt Intermediate in a Rieske Dioxygenase and Its Relation to the Native FeII O2 Reaction.

Authors:  Kyle D Sutherlin; Brent S Rivard; Lars H Böttger; Lei V Liu; Melanie S Rogers; Martin Srnec; Kiyoung Park; Yoshitaka Yoda; Shinji Kitao; Yasuhiro Kobayashi; Makina Saito; Makoto Seto; Michael Hu; Jiyong Zhao; John D Lipscomb; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2018-04-11       Impact factor: 15.419

6.  Dioxygen Activation and O-O Bond Formation Reactions by Manganese Corroles.

Authors:  Mian Guo; Yong-Min Lee; Ranjana Gupta; Mi Sook Seo; Takehiro Ohta; Hua-Hua Wang; Hai-Yang Liu; Sunder N Dhuri; Ritimukta Sarangi; Shunichi Fukuzumi; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2017-10-31       Impact factor: 15.419

7.  Synthesis, characterization, and reactivity of cobalt(III)-oxygen complexes bearing a macrocyclic N-tetramethylated cyclam ligand.

Authors:  Doyeon Kim; Jaeheung Cho; Yong-Min Lee; Ritimukta Sarangi; Wonwoo Nam
Journal:  Chemistry       Date:  2013-09-03       Impact factor: 5.236

8.  Spectroscopic characterization and reactivity studies of a mononuclear nonheme Mn(III)-hydroperoxo complex.

Authors:  Hee So; Young Jun Park; Kyung-Bin Cho; Yong-Min Lee; Mi Sook Seo; Jaeheung Cho; Ritimukta Sarangi; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2014-08-20       Impact factor: 15.419

9.  Differences and comparisons of the properties and reactivities of iron(III)-hydroperoxo complexes with saturated coordination sphere.

Authors:  Abayomi S Faponle; Matthew G Quesne; Chivukula V Sastri; Frédéric Banse; Sam P de Visser
Journal:  Chemistry       Date:  2014-11-14       Impact factor: 5.236

Review 10.  Applications of density functional theory to iron-containing molecules of bioinorganic interest.

Authors:  Hajime Hirao; Nandun Thellamurege; Xi Zhang
Journal:  Front Chem       Date:  2014-04-29       Impact factor: 5.221
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