1-(2-Furo-yl)-3-(2-meth-oxy-4-nitro-phen-yl)thio-urea.

The asymmetric unit of the title compound, C13H11N3O5S, contains two independent mol-ecules, which are linked by a pair of inter-molecular N-H⋯S hydrogen bonds, forming an R2(2)(8) ring motif. The central thio-urea core forms dihedral angles of 3.02 (12) and 14.00 (10)° with the essentially planar furoyl groups [maximum deviations = 0.030 (2) and 0.057 (2) Å] in the two mol-ecules and dihedral angles of 2.43 (13) and 8.03 (12)° with the benzene rings. The dihedral angles between the furoyl and benzene rings in the two mol-ecules are 3.97 (10) and 5.98 (9)°. The trans-cis geometry of the thio-urea group is stabilized by three intra-molecular N-H⋯O hydrogen bonds involving carbonyl and meth-oxy O atoms with the H atom of the cis-thio-amide group and between furan O atom and the other thio-amide H atom. There is also a weak intra-molecular C-H⋯S inter-action in each mol-ecule.

Related literature

For background to anion receptors, see: Doyle & Jacobsen (2007 ▶); Gale et al. (2008 ▶); Svetlana (2007 ▶). For aroyl thio­ureas as ionophores, see: Wilson et al. (2010 ▶); Pérez et al. (2008 ▶) and as catalysts, see: Yang et al. (2004 ▶); Dai et al. (2004 ▶). For related structures, see: Koch (2001 ▶); Pérez et al. (2008 ▶); Singh et al. (2012a ▶,b ▶,c ▶). For standard bond lengths, see: Allen et al. (1987 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶).

Experimental

Crystal data

C13H11N3O5S

M = 321.31

Triclinic,

a = 7.9474 (6) Å

b = 13.0122 (10) Å

c = 13.4215 (11) Å

α = 87.734 (6)°

β = 77.014 (7)°

γ = 86.945 (7)°

V = 1350.00 (18) Å3

Z = 4

Cu Kα radiation

μ = 2.43 mm−1

T = 123 K

0.69 × 0.21 × 0.04 mm

Data collection

Agilent Xcalibur (Ruby, Gemini) diffractometer

Absorption correction: analytical [CrysAlis PRO (Agilent, 2012 ▶), based on expressions derived by Clark & Reid (1995 ▶)] T min = 0.441, T max = 0.909

9239 measured reflections

5400 independent reflections

4064 reflections with I > 2σ(I)

R int = 0.042

Refinement

R[F 2 > 2σ(F 2)] = 0.046

wR(F 2) = 0.134

S = 1.03

5400 reflections

399 parameters

H-atom parameters constrained

Δρmax = 0.36 e Å−3

Δρmin = −0.34 e Å−3

Data collection: CrysAlis PRO (Agilent, 2012 ▶); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Click here for additional data file.

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536813002894/lh5568sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813002894/lh5568Isup2.hkl

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S1600536813002894/lh5568Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C13H11N3O5S	Z = 4
Mr = 321.31	F(000) = 664
Triclinic, P1	Dx = 1.581 Mg m−3
Hall symbol: -P 1	Cu Kα radiation, λ = 1.54184 Å
a = 7.9474 (6) Å	Cell parameters from 2786 reflections
b = 13.0122 (10) Å	θ = 3.4–75.6°
c = 13.4215 (11) Å	µ = 2.43 mm−1
α = 87.734 (6)°	T = 123 K
β = 77.014 (7)°	Long plate, colorless
γ = 86.945 (7)°	0.69 × 0.21 × 0.04 mm
V = 1350.00 (18) Å3

Agilent Xcalibur (Ruby, Gemini) diffractometer	5400 independent reflections
Radiation source: Enhance (Cu) X-ray Source	4064 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.042
Detector resolution: 10.5081 pixels mm-1	θmax = 75.8°, θmin = 3.4°
ω scans	h = −6→9
Absorption correction: analytical [CrysAlis PRO (Agilent, 2012), based on expressions derived by Clark & Reid (1995)]	k = −15→16
Tmin = 0.441, Tmax = 0.909	l = −15→16
9239 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.046	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.134	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0713P)2] where P = (Fo2 + 2Fc2)/3
5400 reflections	(Δ/σ)max < 0.001
399 parameters	Δρmax = 0.36 e Å−3
0 restraints	Δρmin = −0.34 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
S1A	0.36097 (8)	0.11036 (4)	0.27285 (4)	0.03539 (16)
S1B	0.59249 (8)	0.38403 (4)	0.24534 (4)	0.03632 (16)
O1A	0.5944 (2)	0.35328 (11)	0.46572 (13)	0.0332 (3)
O2A	0.3761 (2)	0.14473 (12)	0.60923 (13)	0.0352 (4)
O3A	0.1883 (2)	−0.06917 (12)	0.63465 (12)	0.0338 (3)
O4A	−0.1054 (3)	−0.37579 (13)	0.55069 (14)	0.0421 (4)
O5A	−0.0861 (3)	−0.36147 (13)	0.38735 (14)	0.0407 (4)
O1B	0.3641 (2)	0.14072 (11)	0.04830 (12)	0.0324 (3)
O2B	0.6346 (2)	0.32954 (12)	−0.09340 (13)	0.0357 (4)
O3B	0.8303 (2)	0.54209 (12)	−0.11942 (12)	0.0347 (4)
O4B	1.0361 (2)	0.85635 (13)	0.13539 (13)	0.0387 (4)
O5B	1.1180 (2)	0.84800 (13)	−0.02921 (13)	0.0398 (4)
N1A	0.4231 (2)	0.18859 (14)	0.43709 (14)	0.0298 (4)
H1AA	0.4660	0.2370	0.3924	0.036*
N2A	0.2838 (2)	0.03587 (13)	0.46879 (14)	0.0283 (4)
H2AA	0.2932	0.0474	0.5314	0.034*
N3A	−0.0598 (2)	−0.33027 (13)	0.46753 (15)	0.0304 (4)
N1B	0.5391 (2)	0.30242 (13)	0.08037 (14)	0.0299 (4)
H1BA	0.4777	0.2607	0.1260	0.036*
N2B	0.6826 (2)	0.45407 (13)	0.04855 (14)	0.0285 (4)
H2BA	0.6776	0.4411	−0.0146	0.034*
N3B	1.0386 (2)	0.81488 (14)	0.05402 (15)	0.0308 (4)
C1A	0.6737 (3)	0.43079 (16)	0.49908 (19)	0.0344 (5)
H1AB	0.7340	0.4830	0.4563	0.041*
C2A	0.6548 (3)	0.42318 (17)	0.6015 (2)	0.0357 (5)
H2AB	0.6978	0.4684	0.6428	0.043*
C3A	0.5584 (3)	0.33487 (18)	0.63570 (19)	0.0344 (5)
H3AA	0.5245	0.3090	0.7041	0.041*
C4A	0.5245 (3)	0.29491 (16)	0.55114 (17)	0.0297 (4)
C5A	0.4348 (3)	0.20312 (16)	0.53730 (17)	0.0288 (4)
C6A	0.3526 (3)	0.10763 (16)	0.39819 (17)	0.0285 (4)
C7A	0.1995 (3)	−0.05422 (15)	0.45914 (17)	0.0269 (4)
C8A	0.1628 (3)	−0.09002 (16)	0.37023 (16)	0.0295 (4)
H8AA	0.1967	−0.0521	0.3076	0.035*
C9A	0.0774 (3)	−0.18036 (16)	0.37248 (17)	0.0302 (4)
H9AA	0.0520	−0.2049	0.3120	0.036*
C10A	0.0297 (3)	−0.23418 (15)	0.46458 (17)	0.0276 (4)
C11A	0.0633 (3)	−0.20163 (16)	0.55529 (17)	0.0288 (4)
H11A	0.0289	−0.2404	0.6174	0.035*
C12A	0.1482 (3)	−0.11100 (16)	0.55243 (16)	0.0274 (4)
C13A	0.1296 (3)	−0.1174 (2)	0.73323 (18)	0.0393 (5)
H13A	0.1554	−0.0746	0.7859	0.059*
H13B	0.1887	−0.1853	0.7353	0.059*
H13C	0.0046	−0.1254	0.7460	0.059*
C1B	0.2969 (3)	0.05868 (16)	0.01333 (19)	0.0340 (5)
H1BB	0.2204	0.0125	0.0550	0.041*
C2B	0.3542 (3)	0.05241 (17)	−0.0883 (2)	0.0361 (5)
H2BB	0.3257	0.0021	−0.1304	0.043*
C3B	0.4655 (3)	0.13491 (18)	−0.12144 (19)	0.0358 (5)
H3BA	0.5265	0.1504	−0.1893	0.043*
C4B	0.4665 (3)	0.18683 (16)	−0.03598 (18)	0.0303 (4)
C5B	0.5544 (3)	0.27857 (16)	−0.02133 (17)	0.0298 (4)
C6B	0.6086 (3)	0.38421 (15)	0.11951 (17)	0.0281 (4)
C7B	0.7665 (3)	0.54421 (15)	0.05886 (17)	0.0266 (4)
C8B	0.7740 (3)	0.58953 (16)	0.15028 (17)	0.0311 (4)
H8BA	0.7187	0.5587	0.2137	0.037*
C9B	0.8613 (3)	0.67881 (16)	0.14927 (17)	0.0313 (4)
H9BA	0.8652	0.7101	0.2114	0.038*
C10B	0.9425 (3)	0.72156 (15)	0.05632 (17)	0.0290 (4)
C11B	0.9372 (3)	0.67978 (16)	−0.03685 (17)	0.0295 (4)
H11B	0.9934	0.7112	−0.0997	0.035*
C12B	0.8477 (3)	0.59132 (16)	−0.03526 (17)	0.0284 (4)
C13B	0.9012 (3)	0.5872 (2)	−0.21823 (18)	0.0390 (5)
H13D	0.8889	0.5406	−0.2715	0.058*
H13E	1.0239	0.5989	−0.2242	0.058*
H13F	0.8392	0.6530	−0.2265	0.058*

	U11	U22	U33	U12	U13	U23
S1A	0.0491 (3)	0.0307 (3)	0.0268 (3)	−0.0122 (2)	−0.0068 (2)	−0.0023 (2)
S1B	0.0523 (3)	0.0293 (3)	0.0280 (3)	−0.0125 (2)	−0.0078 (2)	−0.0018 (2)
O1A	0.0408 (8)	0.0242 (7)	0.0361 (8)	−0.0058 (6)	−0.0108 (7)	−0.0012 (6)
O2A	0.0453 (9)	0.0306 (8)	0.0303 (8)	−0.0094 (7)	−0.0080 (7)	−0.0025 (6)
O3A	0.0459 (9)	0.0298 (8)	0.0283 (8)	−0.0098 (6)	−0.0120 (7)	−0.0016 (6)
O4A	0.0576 (11)	0.0345 (9)	0.0336 (9)	−0.0177 (7)	−0.0058 (8)	0.0015 (7)
O5A	0.0594 (11)	0.0308 (8)	0.0373 (9)	−0.0141 (7)	−0.0190 (8)	−0.0030 (7)
O1B	0.0398 (8)	0.0245 (7)	0.0338 (8)	−0.0050 (6)	−0.0089 (7)	−0.0034 (6)
O2B	0.0456 (9)	0.0313 (8)	0.0304 (8)	−0.0090 (7)	−0.0064 (7)	−0.0042 (6)
O3B	0.0462 (9)	0.0331 (8)	0.0259 (8)	−0.0107 (7)	−0.0078 (7)	−0.0036 (6)
O4B	0.0550 (10)	0.0313 (8)	0.0334 (8)	−0.0120 (7)	−0.0142 (8)	−0.0050 (6)
O5B	0.0488 (10)	0.0351 (9)	0.0348 (9)	−0.0139 (7)	−0.0054 (7)	−0.0014 (7)
N1A	0.0375 (10)	0.0244 (8)	0.0278 (9)	−0.0058 (7)	−0.0070 (7)	−0.0010 (7)
N2A	0.0377 (9)	0.0239 (8)	0.0247 (8)	−0.0047 (7)	−0.0085 (7)	−0.0045 (6)
N3A	0.0342 (9)	0.0237 (8)	0.0337 (10)	−0.0043 (7)	−0.0073 (8)	−0.0035 (7)
N1B	0.0373 (9)	0.0221 (8)	0.0301 (9)	−0.0049 (7)	−0.0060 (7)	−0.0026 (7)
N2B	0.0364 (9)	0.0235 (8)	0.0272 (8)	−0.0034 (7)	−0.0092 (7)	−0.0048 (7)
N3B	0.0345 (9)	0.0266 (9)	0.0330 (9)	−0.0040 (7)	−0.0106 (8)	−0.0018 (7)
C1A	0.0383 (12)	0.0236 (10)	0.0436 (13)	−0.0042 (8)	−0.0129 (10)	−0.0041 (9)
C2A	0.0397 (12)	0.0258 (10)	0.0433 (13)	−0.0013 (9)	−0.0117 (10)	−0.0096 (9)
C3A	0.0372 (11)	0.0333 (11)	0.0339 (11)	−0.0010 (9)	−0.0090 (9)	−0.0089 (9)
C4A	0.0323 (10)	0.0247 (10)	0.0323 (11)	−0.0014 (8)	−0.0072 (9)	−0.0024 (8)
C5A	0.0302 (10)	0.0250 (10)	0.0319 (11)	−0.0010 (8)	−0.0074 (8)	−0.0064 (8)
C6A	0.0319 (10)	0.0238 (9)	0.0301 (10)	−0.0016 (8)	−0.0066 (8)	−0.0045 (8)
C7A	0.0307 (10)	0.0204 (9)	0.0297 (10)	−0.0021 (7)	−0.0067 (8)	−0.0033 (8)
C8A	0.0386 (11)	0.0232 (10)	0.0259 (10)	−0.0022 (8)	−0.0054 (8)	−0.0020 (7)
C9A	0.0389 (11)	0.0252 (10)	0.0281 (10)	−0.0037 (8)	−0.0098 (9)	−0.0038 (8)
C10A	0.0298 (10)	0.0213 (9)	0.0319 (11)	−0.0033 (7)	−0.0064 (8)	−0.0043 (8)
C11A	0.0329 (10)	0.0243 (10)	0.0286 (10)	−0.0031 (8)	−0.0051 (8)	−0.0019 (8)
C12A	0.0310 (10)	0.0253 (10)	0.0268 (10)	−0.0006 (8)	−0.0078 (8)	−0.0050 (8)
C13A	0.0498 (14)	0.0432 (13)	0.0276 (11)	−0.0134 (11)	−0.0119 (10)	0.0004 (9)
C1B	0.0388 (12)	0.0235 (10)	0.0425 (13)	−0.0049 (8)	−0.0135 (10)	−0.0031 (9)
C2B	0.0419 (12)	0.0285 (11)	0.0417 (12)	−0.0011 (9)	−0.0162 (10)	−0.0073 (9)
C3B	0.0431 (12)	0.0306 (11)	0.0348 (11)	0.0012 (9)	−0.0109 (10)	−0.0069 (9)
C4B	0.0347 (11)	0.0234 (10)	0.0333 (11)	0.0005 (8)	−0.0088 (9)	−0.0036 (8)
C5B	0.0343 (11)	0.0249 (10)	0.0313 (10)	0.0003 (8)	−0.0093 (9)	−0.0056 (8)
C6B	0.0320 (10)	0.0224 (9)	0.0298 (10)	−0.0011 (8)	−0.0065 (8)	−0.0039 (8)
C7B	0.0294 (10)	0.0213 (9)	0.0297 (10)	−0.0013 (7)	−0.0076 (8)	−0.0028 (8)
C8B	0.0415 (12)	0.0253 (10)	0.0262 (10)	−0.0035 (8)	−0.0061 (9)	−0.0007 (8)
C9B	0.0418 (12)	0.0270 (10)	0.0266 (10)	−0.0031 (9)	−0.0101 (9)	−0.0038 (8)
C10B	0.0322 (10)	0.0209 (9)	0.0351 (11)	−0.0021 (8)	−0.0096 (9)	−0.0020 (8)
C11B	0.0329 (10)	0.0255 (10)	0.0299 (10)	−0.0038 (8)	−0.0065 (8)	0.0008 (8)
C12B	0.0323 (10)	0.0254 (10)	0.0280 (10)	0.0007 (8)	−0.0075 (8)	−0.0055 (8)
C13B	0.0496 (14)	0.0418 (13)	0.0260 (11)	−0.0118 (10)	−0.0070 (10)	−0.0017 (9)

S1A—C6A	1.668 (2)	C3A—C4A	1.353 (3)
S1B—C6B	1.665 (2)	C3A—H3AA	0.9500
O1A—C1A	1.358 (3)	C4A—C5A	1.462 (3)
O1A—C4A	1.375 (3)	C7A—C8A	1.393 (3)
O2A—C5A	1.226 (3)	C7A—C12A	1.417 (3)
O3A—C12A	1.356 (3)	C8A—C9A	1.385 (3)
O3A—C13A	1.432 (3)	C8A—H8AA	0.9500
O4A—N3A	1.231 (3)	C9A—C10A	1.382 (3)
O5A—N3A	1.229 (3)	C9A—H9AA	0.9500
O1B—C1B	1.363 (3)	C10A—C11A	1.390 (3)
O1B—C4B	1.373 (3)	C11A—C12A	1.385 (3)
O2B—C5B	1.224 (3)	C11A—H11A	0.9500
O3B—C12B	1.357 (3)	C13A—H13A	0.9800
O3B—C13B	1.435 (3)	C13A—H13B	0.9800
O4B—N3B	1.233 (3)	C13A—H13C	0.9800
O5B—N3B	1.227 (3)	C1B—C2B	1.341 (4)
N1A—C5A	1.390 (3)	C1B—H1BB	0.9500
N1A—C6A	1.391 (3)	C2B—C3B	1.421 (3)
N1A—H1AA	0.8800	C2B—H2BB	0.9500
N2A—C6A	1.349 (3)	C3B—C4B	1.356 (3)
N2A—C7A	1.405 (3)	C3B—H3BA	0.9500
N2A—H2AA	0.8800	C4B—C5B	1.456 (3)
N3A—C10A	1.466 (3)	C7B—C8B	1.397 (3)
N1B—C5B	1.389 (3)	C7B—C12B	1.415 (3)
N1B—C6B	1.397 (3)	C8B—C9B	1.383 (3)
N1B—H1BA	0.8800	C8B—H8BA	0.9500
N2B—C6B	1.348 (3)	C9B—C10B	1.380 (3)
N2B—C7B	1.406 (3)	C9B—H9BA	0.9500
N2B—H2BA	0.8800	C10B—C11B	1.393 (3)
N3B—C10B	1.464 (3)	C11B—C12B	1.382 (3)
C1A—C2A	1.349 (4)	C11B—H11B	0.9500
C1A—H1AB	0.9500	C13B—H13D	0.9800
C2A—C3A	1.418 (3)	C13B—H13E	0.9800
C2A—H2AB	0.9500	C13B—H13F	0.9800
C1A—O1A—C4A	106.15 (18)	C12A—C11A—H11A	121.0
C12A—O3A—C13A	118.46 (17)	C10A—C11A—H11A	121.0
C1B—O1B—C4B	106.16 (18)	O3A—C12A—C11A	124.7 (2)
C12B—O3B—C13B	118.39 (18)	O3A—C12A—C7A	114.87 (18)
C5A—N1A—C6A	128.54 (19)	C11A—C12A—C7A	120.42 (19)
C5A—N1A—H1AA	115.7	O3A—C13A—H13A	109.5
C6A—N1A—H1AA	115.7	O3A—C13A—H13B	109.5
C6A—N2A—C7A	130.85 (19)	H13A—C13A—H13B	109.5
C6A—N2A—H2AA	114.6	O3A—C13A—H13C	109.5
C7A—N2A—H2AA	114.6	H13A—C13A—H13C	109.5
O5A—N3A—O4A	123.17 (19)	H13B—C13A—H13C	109.5
O5A—N3A—C10A	118.71 (19)	C2B—C1B—O1B	110.3 (2)
O4A—N3A—C10A	118.12 (18)	C2B—C1B—H1BB	124.8
C5B—N1B—C6B	128.25 (19)	O1B—C1B—H1BB	124.8
C5B—N1B—H1BA	115.9	C1B—C2B—C3B	107.5 (2)
C6B—N1B—H1BA	115.9	C1B—C2B—H2BB	126.3
C6B—N2B—C7B	130.55 (19)	C3B—C2B—H2BB	126.3
C6B—N2B—H2BA	114.7	C4B—C3B—C2B	105.6 (2)
C7B—N2B—H2BA	114.7	C4B—C3B—H3BA	127.2
O5B—N3B—O4B	123.18 (19)	C2B—C3B—H3BA	127.2
O5B—N3B—C10B	118.14 (19)	C3B—C4B—O1B	110.5 (2)
O4B—N3B—C10B	118.68 (19)	C3B—C4B—C5B	131.3 (2)
C2A—C1A—O1A	110.5 (2)	O1B—C4B—C5B	118.24 (19)
C2A—C1A—H1AB	124.7	O2B—C5B—N1B	123.56 (19)
O1A—C1A—H1AB	124.7	O2B—C5B—C4B	122.1 (2)
C1A—C2A—C3A	106.9 (2)	N1B—C5B—C4B	114.33 (19)
C1A—C2A—H2AB	126.5	N2B—C6B—N1B	114.56 (19)
C3A—C2A—H2AB	126.5	N2B—C6B—S1B	127.98 (16)
C4A—C3A—C2A	106.0 (2)	N1B—C6B—S1B	117.46 (16)
C4A—C3A—H3AA	127.0	C8B—C7B—N2B	126.6 (2)
C2A—C3A—H3AA	127.0	C8B—C7B—C12B	119.26 (19)
C3A—C4A—O1A	110.37 (19)	N2B—C7B—C12B	114.10 (19)
C3A—C4A—C5A	131.5 (2)	C9B—C8B—C7B	120.6 (2)
O1A—C4A—C5A	118.06 (19)	C9B—C8B—H8BA	119.7
O2A—C5A—N1A	123.84 (19)	C7B—C8B—H8BA	119.7
O2A—C5A—C4A	121.8 (2)	C10B—C9B—C8B	118.8 (2)
N1A—C5A—C4A	114.39 (19)	C10B—C9B—H9BA	120.6
N2A—C6A—N1A	114.52 (19)	C8B—C9B—H9BA	120.6
N2A—C6A—S1A	127.94 (16)	C9B—C10B—C11B	122.7 (2)
N1A—C6A—S1A	117.54 (16)	C9B—C10B—N3B	119.4 (2)
C8A—C7A—N2A	126.9 (2)	C11B—C10B—N3B	117.8 (2)
C8A—C7A—C12A	119.44 (19)	C12B—C11B—C10B	118.2 (2)
N2A—C7A—C12A	113.62 (18)	C12B—C11B—H11B	120.9
C9A—C8A—C7A	120.5 (2)	C10B—C11B—H11B	120.9
C9A—C8A—H8AA	119.7	O3B—C12B—C11B	125.0 (2)
C7A—C8A—H8AA	119.7	O3B—C12B—C7B	114.55 (18)
C10A—C9A—C8A	118.63 (19)	C11B—C12B—C7B	120.5 (2)
C10A—C9A—H9AA	120.7	O3B—C13B—H13D	109.5
C8A—C9A—H9AA	120.7	O3B—C13B—H13E	109.5
C9A—C10A—C11A	123.01 (19)	H13D—C13B—H13E	109.5
C9A—C10A—N3A	118.99 (19)	O3B—C13B—H13F	109.5
C11A—C10A—N3A	118.00 (19)	H13D—C13B—H13F	109.5
C12A—C11A—C10A	118.0 (2)	H13E—C13B—H13F	109.5
C4A—O1A—C1A—C2A	−0.4 (3)	C4B—O1B—C1B—C2B	0.3 (3)
O1A—C1A—C2A—C3A	0.4 (3)	O1B—C1B—C2B—C3B	0.2 (3)
C1A—C2A—C3A—C4A	−0.3 (3)	C1B—C2B—C3B—C4B	−0.5 (3)
C2A—C3A—C4A—O1A	0.0 (3)	C2B—C3B—C4B—O1B	0.7 (3)
C2A—C3A—C4A—C5A	178.1 (2)	C2B—C3B—C4B—C5B	−179.2 (2)
C1A—O1A—C4A—C3A	0.2 (3)	C1B—O1B—C4B—C3B	−0.6 (2)
C1A—O1A—C4A—C5A	−178.12 (19)	C1B—O1B—C4B—C5B	179.31 (19)
C6A—N1A—C5A—O2A	−2.6 (4)	C6B—N1B—C5B—O2B	−0.4 (4)
C6A—N1A—C5A—C4A	177.3 (2)	C6B—N1B—C5B—C4B	179.5 (2)
C3A—C4A—C5A—O2A	−1.4 (4)	C3B—C4B—C5B—O2B	6.9 (4)
O1A—C4A—C5A—O2A	176.6 (2)	O1B—C4B—C5B—O2B	−173.0 (2)
C3A—C4A—C5A—N1A	178.8 (2)	C3B—C4B—C5B—N1B	−173.1 (2)
O1A—C4A—C5A—N1A	−3.2 (3)	O1B—C4B—C5B—N1B	7.0 (3)
C7A—N2A—C6A—N1A	178.6 (2)	C7B—N2B—C6B—N1B	−179.1 (2)
C7A—N2A—C6A—S1A	−0.9 (4)	C7B—N2B—C6B—S1B	0.4 (4)
C5A—N1A—C6A—N2A	1.7 (3)	C5B—N1B—C6B—N2B	8.1 (3)
C5A—N1A—C6A—S1A	−178.79 (18)	C5B—N1B—C6B—S1B	−171.41 (18)
C6A—N2A—C7A—C8A	−1.7 (4)	C6B—N2B—C7B—C8B	−8.5 (4)
C6A—N2A—C7A—C12A	178.8 (2)	C6B—N2B—C7B—C12B	172.3 (2)
N2A—C7A—C8A—C9A	−179.6 (2)	N2B—C7B—C8B—C9B	−179.9 (2)
C12A—C7A—C8A—C9A	−0.2 (3)	C12B—C7B—C8B—C9B	−0.7 (3)
C7A—C8A—C9A—C10A	−0.1 (3)	C7B—C8B—C9B—C10B	−0.8 (3)
C8A—C9A—C10A—C11A	0.2 (3)	C8B—C9B—C10B—C11B	1.5 (4)
C8A—C9A—C10A—N3A	−179.6 (2)	C8B—C9B—C10B—N3B	−178.69 (19)
O5A—N3A—C10A—C9A	1.8 (3)	O5B—N3B—C10B—C9B	175.9 (2)
O4A—N3A—C10A—C9A	−178.1 (2)	O4B—N3B—C10B—C9B	−4.1 (3)
O5A—N3A—C10A—C11A	−178.0 (2)	O5B—N3B—C10B—C11B	−4.3 (3)
O4A—N3A—C10A—C11A	2.1 (3)	O4B—N3B—C10B—C11B	175.7 (2)
C9A—C10A—C11A—C12A	0.1 (3)	C9B—C10B—C11B—C12B	−0.6 (3)
N3A—C10A—C11A—C12A	179.86 (19)	N3B—C10B—C11B—C12B	179.55 (19)
C13A—O3A—C12A—C11A	−4.4 (3)	C13B—O3B—C12B—C11B	−3.6 (3)
C13A—O3A—C12A—C7A	175.4 (2)	C13B—O3B—C12B—C7B	176.9 (2)
C10A—C11A—C12A—O3A	179.4 (2)	C10B—C11B—C12B—O3B	179.6 (2)
C10A—C11A—C12A—C7A	−0.3 (3)	C10B—C11B—C12B—C7B	−0.9 (3)
C8A—C7A—C12A—O3A	−179.34 (19)	C8B—C7B—C12B—O3B	−178.96 (19)
N2A—C7A—C12A—O3A	0.1 (3)	N2B—C7B—C12B—O3B	0.4 (3)
C8A—C7A—C12A—C11A	0.4 (3)	C8B—C7B—C12B—C11B	1.5 (3)
N2A—C7A—C12A—C11A	179.88 (19)	N2B—C7B—C12B—C11B	−179.13 (19)

D—H···A	D—H	H···A	D···A	D—H···A
N1A—H1AA···O1A	0.88	2.24	2.684 (2)	111
N2A—H2AA···O2A	0.88	1.91	2.654 (2)	142
N2A—H2AA···O3A	0.88	2.09	2.552 (2)	112
N1B—H1BA···O1B	0.88	2.25	2.683 (2)	111
N2B—H2BA···O2B	0.88	1.92	2.653 (2)	140
N2B—H2BA···O3B	0.88	2.11	2.554 (2)	111
C8A—H8AA···S1A	0.95	2.52	3.198 (2)	129
C8B—H8BA···S1B	0.95	2.52	3.189 (2)	128

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1A—H1AA⋯O1A	0.88	2.24	2.684 (2)	111
N2A—H2AA⋯O2A	0.88	1.91	2.654 (2)	142
N2A—H2AA⋯O3A	0.88	2.09	2.552 (2)	112
N1B—H1BA⋯O1B	0.88	2.25	2.683 (2)	111
N2B—H2BA⋯O2B	0.88	1.92	2.653 (2)	140
N2B—H2BA⋯O3B	0.88	2.11	2.554 (2)	111
C8A—H8AA⋯S1A	0.95	2.52	3.198 (2)	129
C8B—H8BA⋯S1B	0.95	2.52	3.189 (2)	128