2-Amino-4,6-dimethyl-pyrimidin-1-ium chloride.

In the title compound, C6H10N3(+)·Cl(-), the cation is essentially planar with an r.m.s. deviations of the fitted atoms of 0.008 Å. In the crystal, adjacent ions are linked by weak N-H⋯Cl hydrogen bonds involving the pyrimidine and amine N atoms, forming a three-dimensional network. C-H⋯π inter-actions between the methyl and pyrimidine groups and π-π stacking [centroid-centroid distance = 3.474 (1) Å] between parallel pyrimidine ring systems are also observed.

Related literature

For the crystal structures of 2-amino­pyrimidinium salts with other anions, see: Cheng et al. (2010) ▶; Eshtiagh-Hosseini et al. (2010 ▶); Hu & Yeh (2012 ▶).

Experimental

Crystal data

C6H10N3 +·Cl−

M = 159.62

Monoclinic,

a = 16.372 (4) Å

b = 8.795 (2) Å

c = 12.007 (3) Å

β = 108.133 (5)°

V = 1642.9 (8) Å3

Z = 8

Mo Kα radiation

μ = 0.40 mm−1

T = 273 K

0.4 × 0.4 × 0.3 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2000 ▶) T min = 0.869, T max = 0.982

5044 measured reflections

1620 independent reflections

1008 reflections with I > 2σ(I)

R int = 0.046

Refinement

R[F 2 > 2σ(F 2)] = 0.039

wR(F 2) = 0.105

S = 0.90

1620 reflections

93 parameters

H-atom parameters constrained

Δρmax = 0.18 e Å−3

Δρmin = −0.17 e Å−3

Data collection: APEX2 (Bruker, 2010 ▶); cell refinement: SAINT (Bruker, 2010 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008) ▶; program(s) used to refine structure: SHELXL97 (Sheldrick, 2008) ▶; molecular graphics: DIAMOND (Brandenburg, 2010 ▶); software used to prepare material for publication: SHELXL97.

Click here for additional data file.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536812046569/gw2128sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812046569/gw2128Isup2.hkl

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S1600536812046569/gw2128Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C6H10N3+·Cl−	F(000) = 672
Mr = 159.62	Dx = 1.291 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 1118 reflections
a = 16.372 (4) Å	θ = 2.7–22.9°
b = 8.795 (2) Å	µ = 0.40 mm−1
c = 12.007 (3) Å	T = 273 K
β = 108.133 (5)°	Block, yellow
V = 1642.9 (8) Å3	0.4 × 0.4 × 0.3 mm
Z = 8

Bruker APEXII CCD area-detector diffractometer	1620 independent reflections
Radiation source: fine-focus sealed tube	1008 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.046
phi and ω scans	θmax = 26.0°, θmin = 2.6°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −19→20
Tmin = 0.869, Tmax = 0.982	k = −10→10
5044 measured reflections	l = −14→11

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.039	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.105	H-atom parameters constrained
S = 0.90	w = 1/[σ2(Fo2) + (0.0545P)2] where P = (Fo2 + 2Fc2)/3
1620 reflections	(Δ/σ)max < 0.001
93 parameters	Δρmax = 0.18 e Å−3
0 restraints	Δρmin = −0.17 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cl	0.06044 (4)	0.20186 (8)	0.63062 (5)	0.0635 (3)
C1	0.19281 (13)	0.0360 (3)	0.9384 (2)	0.0456 (6)
C2	0.28190 (14)	0.1835 (2)	0.8578 (2)	0.0476 (6)
C3	0.35098 (14)	0.1274 (3)	0.9429 (2)	0.0524 (6)
H3A	0.4063	0.1584	0.9477	0.063*
C4	0.33775 (13)	0.0227 (3)	1.0228 (2)	0.0490 (6)
C5	0.28542 (16)	0.2952 (3)	0.7666 (2)	0.0639 (7)
H5A	0.2522	0.3834	0.7718	0.096*
H5B	0.2623	0.2499	0.6905	0.096*
H5C	0.3440	0.3244	0.7785	0.096*
C6	0.41211 (15)	−0.0414 (3)	1.1175 (2)	0.0682 (8)
H6A	0.3997	−0.0390	1.1906	0.102*
H6B	0.4625	0.0183	1.1242	0.102*
H6C	0.4219	−0.1445	1.0987	0.102*
N1	0.11391 (11)	−0.0037 (2)	0.93458 (18)	0.0598 (6)
H1A	0.1063	−0.0665	0.9853	0.072*
H1B	0.0703	0.0334	0.8814	0.072*
N2	0.20317 (11)	0.1349 (2)	0.85719 (15)	0.0470 (5)
H2N	0.1585	0.1678	0.8037	0.056*
N3	0.25965 (11)	−0.0223 (2)	1.02128 (16)	0.0480 (5)

	U11	U22	U33	U12	U13	U23
Cl	0.0469 (4)	0.0883 (5)	0.0535 (4)	0.0071 (3)	0.0131 (3)	0.0016 (3)
C1	0.0433 (12)	0.0489 (13)	0.0451 (14)	−0.0002 (11)	0.0144 (11)	−0.0052 (11)
C2	0.0516 (13)	0.0483 (13)	0.0459 (13)	−0.0037 (11)	0.0193 (11)	−0.0071 (11)
C3	0.0415 (12)	0.0603 (15)	0.0579 (16)	−0.0074 (11)	0.0190 (11)	−0.0044 (13)
C4	0.0447 (13)	0.0536 (14)	0.0469 (14)	0.0019 (11)	0.0117 (11)	−0.0066 (11)
C5	0.0717 (16)	0.0674 (16)	0.0581 (16)	−0.0057 (14)	0.0280 (13)	0.0069 (14)
C6	0.0487 (13)	0.0823 (19)	0.0663 (19)	0.0064 (14)	0.0073 (13)	0.0103 (15)
N1	0.0407 (11)	0.0734 (15)	0.0629 (15)	−0.0037 (10)	0.0129 (10)	0.0083 (10)
N2	0.0434 (10)	0.0530 (11)	0.0428 (11)	0.0034 (9)	0.0107 (8)	0.0017 (9)
N3	0.0425 (10)	0.0528 (12)	0.0467 (12)	0.0015 (9)	0.0110 (9)	0.0027 (9)

C1—N1	1.325 (3)	C5—H5A	0.9600
C1—N3	1.331 (3)	C5—H5B	0.9600
C1—N2	1.356 (3)	C5—H5C	0.9600
C2—N2	1.356 (3)	C6—H6A	0.9600
C2—C3	1.359 (3)	C6—H6B	0.9600
C2—C5	1.486 (3)	C6—H6C	0.9600
C3—C4	1.395 (3)	N1—H1A	0.8600
C3—H3A	0.9300	N1—H1B	0.8600
C4—N3	1.333 (3)	N2—H2N	0.8600
C4—C6	1.494 (3)
N1—C1—N3	119.3 (2)	H5A—C5—H5C	109.5
N1—C1—N2	118.9 (2)	H5B—C5—H5C	109.5
N3—C1—N2	121.8 (2)	C4—C6—H6A	109.5
N2—C2—C3	117.2 (2)	C4—C6—H6B	109.5
N2—C2—C5	117.3 (2)	H6A—C6—H6B	109.5
C3—C2—C5	125.4 (2)	C4—C6—H6C	109.5
C2—C3—C4	119.0 (2)	H6A—C6—H6C	109.5
C2—C3—H3A	120.5	H6B—C6—H6C	109.5
C4—C3—H3A	120.5	C1—N1—H1A	120.0
N3—C4—C3	122.7 (2)	C1—N1—H1B	120.0
N3—C4—C6	116.7 (2)	H1A—N1—H1B	120.0
C3—C4—C6	120.6 (2)	C2—N2—C1	121.99 (18)
C2—C5—H5A	109.5	C2—N2—H2N	119.0
C2—C5—H5B	109.5	C1—N2—H2N	119.0
H5A—C5—H5B	109.5	C1—N3—C4	117.2 (2)
C2—C5—H5C	109.5

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1A···Cli	0.86	2.42	3.260 (2)	167
N1—H1B···Clii	0.86	2.57	3.262 (2)	138
N2—H2N···Cl	0.86	2.22	3.042 (2)	161
C5—H5A···Cg1iii	0.96	3.00	3.446 (3)	110

Table 1

Hydrogen-bond geometry (Å, °)

Cg1 is the centroid of the C1–C4/N2/N3 ring.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1A⋯Cli	0.86	2.42	3.260 (2)	167
N1—H1B⋯Clii	0.86	2.57	3.262 (2)	138
N2—H2N⋯Cl	0.86	2.22	3.042 (2)	161
C5—H5A⋯Cg1iii	0.96	3.00	3.446 (3)	110

Symmetry codes: (i) ; (ii) ; (iii) .