Literature DB >> 30074788

Hydrogen Bonds Dictate O2 Capture and Release within a Zinc Tripod.

Eric W Dahl1, John J Kiernicki1, Matthias Zeller2, Nathaniel K Szymczak1.   

Abstract

Six directed hydrogen bonding (H-bonding) interactions allow for the reversible capture and reduction of dioxygen to a trans-1,2-peroxo within a tripodal zinc(II) framework. Spectroscopic studies of the dizinc peroxides, as well as on model zinc diazides, suggest H-bonding contributions serve a dominant role for the binding/activation of these small molecules.

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Year:  2018        PMID： 30074788      PMCID： PMC6093784          DOI： 10.1021/jacs.8b04266

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  40 in total

1.  Copper hydroperoxo species activated by hydrogen-bonding interaction with its distal oxygen.

Authors:  Syuhei Yamaguchi; Shigenori Nagatomo; Teizo Kitagawa; Yasuhiro Funahashi; Tomohiro Ozawa; Koichiro Jitsukawa; Hideki Masuda
Journal:  Inorg Chem       Date:  2003-11-03       Impact factor: 5.165

2.  Mononuclear N3S(thioether)-ligated copper(II) methoxide complexes: synthesis, characterization, and hydrolytic reactivity.

Authors:  Kyle J Tubbs; Amy L Fuller; Brian Bennett; Atta M Arif; Lisa M Berreau
Journal:  Inorg Chem       Date:  2003-08-11       Impact factor: 5.165

3.  Molecular designs for controlling the local environments around metal ions.

Authors:  Sarah A Cook; A S Borovik
Journal:  Acc Chem Res       Date:  2015-07-16       Impact factor: 22.384

4.  Modular Attachment of Appended Boron Lewis Acids to a Ruthenium Pincer Catalyst: Metal-Ligand Cooperativity Enables Selective Alkyne Hydrogenation.

Authors:  Kuei-Nin T Tseng; Jeff W Kampf; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2016-08-11       Impact factor: 15.419

5.  A bioinspired iron catalyst for nitrate and perchlorate reduction.

Authors:  Courtney L Ford; Yun Ji Park; Ellen M Matson; Zachary Gordon; Alison R Fout
Journal:  Science       Date:  2016-11-11       Impact factor: 47.728

6.  Unprecedented Variety of Outcomes in the Oxygenation of Dinuclear Alkylzinc Derivatives of an N,N-Coupled Bis(β-diketimine).

Authors:  Tomasz Pietrzak; Maciej Damian Korzyński; Iwona Justyniak; Karolina Zelga; Arkadiusz Kornowicz; Zbigniew Ochal; Janusz Lewiński
Journal:  Chemistry       Date:  2017-05-22       Impact factor: 5.236

7.  Oxygen insertion reactions of mixed N-heterocyclic carbene-oxazolinylborato zinc alkyl complexes.

Authors:  Songchen Xu; William C Everett; Arkady Ellern; Theresa L Windus; Aaron D Sadow
Journal:  Dalton Trans       Date:  2014-10-14       Impact factor: 4.390

8.  A transition metal Lewis acid/base triad system for cooperative substrate binding.

Authors:  Oscar Tutusaus; Chengbao Ni; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2013-02-25       Impact factor: 15.419

9.  Remarkably robust monomeric alkylperoxyzinc compounds from tris(oxazolinyl)boratozinc alkyls and O2.

Authors:  Debabrata Mukherjee; Arkady Ellern; Aaron D Sadow
Journal:  J Am Chem Soc       Date:  2012-07-30       Impact factor: 15.419

10.  Hydrogen Peroxide Complex of Zinc.

Authors:  Christian M Wallen; John Bacsa; Christopher C Scarborough
Journal:  J Am Chem Soc       Date:  2015-11-17       Impact factor: 15.419
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  11 in total

1.  Examining the Generality of Metal-Ligand Cooperativity Across a Series of First-Row Transition Metals: Capture, Bond Activation, and Stabilization.

Authors:  John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  Inorg Chem       Date:  2020-06-18       Impact factor: 5.165

2.  Catalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups.

Authors:  Khashayar Rajabimoghadam; Yousef Darwish; Umyeena Bashir; Dylan Pitman; Sidney Eichelberger; Maxime A Siegler; Marcel Swart; Isaac Garcia-Bosch
Journal:  J Am Chem Soc       Date:  2018-11-19       Impact factor: 15.419

3.  Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates.

Authors:  Daniel E Diaz; David A Quist; Austin E Herzog; Andrew W Schaefer; Ioannis Kipouros; Mayukh Bhadra; Edward I Solomon; Kenneth D Karlin
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-23       Impact factor: 15.336

4.  Dioxygen-Derived Nonheme Mononuclear FeIII(OH) Complex and Its Reactivity with Carbon Radicals.

Authors:  Vishal Yadav; Jesse B Gordon; Maxime A Siegler; David P Goldberg
Journal:  J Am Chem Soc       Date:  2019-06-20       Impact factor: 15.419

5.  Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions.

Authors:  Andrew W Schaefer; Melanie A Ehudin; David A Quist; Joel A Tang; Kenneth D Karlin; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2019-03-14       Impact factor: 15.419

6.  Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.

Authors:  John J Kiernicki; Emily E Norwine; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2019-10-01       Impact factor: 6.222

7.  Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal-organic framework.

Authors:  Julia Oktawiec; Henry Z H Jiang; Jenny G Vitillo; Douglas A Reed; Lucy E Darago; Benjamin A Trump; Varinia Bernales; Harriet Li; Kristen A Colwell; Hiroyasu Furukawa; Craig M Brown; Laura Gagliardi; Jeffrey R Long
Journal:  Nat Commun       Date:  2020-06-18       Impact factor: 14.919

8.  Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides.

Authors:  John J Kiernicki; James P Shanahan; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Sci       Date:  2019-05-07       Impact factor: 9.825

9.  Early Metal Di(pyridyl) Pyrrolide Complexes with Second Coordination Sphere Arene-π Interactions: Ligand Binding and Ethylene Polymerization.

Authors:  Jessica Sampson; Gyeongshin Choi; Muhammed Naseem Akhtar; E A Jaseer; Rajesh Theravalappil; Nestor Garcia; Theodor Agapie
Journal:  ACS Omega       Date:  2019-09-19

10.  Structure of formylglycine-generating enzyme in complex with copper and a substrate reveals an acidic pocket for binding and activation of molecular oxygen.

Authors:  Dzmitry A Miarzlou; Florian Leisinger; Daniel Joss; Daniel Häussinger; Florian P Seebeck
Journal:  Chem Sci       Date:  2019-06-18       Impact factor: 9.825
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