Literature DB >> 21595481

The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.

Young Jun Park1, Joseph W Ziller, A S Borovik.   

Abstract

Rate enhancements for the reduction of dioxygen by a Mn(II) complex were observed in the presence of redox-inactive group 2 metal ions. The rate changes were correlated with an increase in the Lewis acidity of the group 2 metal ions. These studies led to the isolation of heterobimetallic complexes containing Mn(III)-(μ-OH)-M(II) cores (M(II) = Ca(II), Ba(II)) in which the hydroxo oxygen atom is derived from O(2). This type of core structure has relevance to the oxygen-evolving complex within photosystem II.

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Year:  2011        PMID： 21595481      PMCID： PMC3116078          DOI： 10.1021/ja203458d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  48 in total

1.  Catalytic reduction of dioxygen to water with a monomeric manganese complex at room temperature.

Authors:  Ryan L Shook; Sonja M Peterson; John Greaves; Curtis Moore; Arnold L Rheingold; A S Borovik
Journal:  J Am Chem Soc       Date:  2011-03-22       Impact factor: 15.419

2.  A series of new structural models for the OEC in photosystem II.

Authors:  Ian J Hewitt; Jin-Kui Tang; N T Madhu; Rodolphe Clérac; Gernot Buth; Christopher E Anson; Annie K Powell
Journal:  Chem Commun (Camb)       Date:  2006-03-02       Impact factor: 6.222

3.  Where water is oxidized to dioxygen: structure of the photosynthetic Mn4Ca cluster.

Authors:  Junko Yano; Jan Kern; Kenneth Sauer; Matthew J Latimer; Yulia Pushkar; Jacek Biesiadka; Bernhard Loll; Wolfram Saenger; Johannes Messinger; Athina Zouni; Vittal K Yachandra
Journal:  Science       Date:  2006-11-03       Impact factor: 47.728

Review 4.  Control of redox reactivity of flavin and pterin coenzymes by metal ion coordination and hydrogen bonding.

Authors:  Shunichi Fukuzumi; Takahiko Kojima
Journal:  J Biol Inorg Chem       Date:  2008-02-13       Impact factor: 3.358

5.  Role of the secondary coordination sphere in metal-mediated dioxygen activation.

Authors:  Ryan L Shook; A S Borovik
Journal:  Inorg Chem       Date:  2010-04-19       Impact factor: 5.165

6.  Structure/activity study of tris(2-aminoethyl)amine-derived translocases for phosphatidylcholine.

Authors:  J Middleton Boon; Timothy N Lambert; Bradley D Smith; Alicia M Beatty; Vesela Ugrinova; Seth N Brown
Journal:  J Org Chem       Date:  2002-04-05       Impact factor: 4.354

7.  Trigonal propeller-shaped [Mn(III)3M(II)Na] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII.

Authors:  Sanjit Nayak; Hari Pada Nayek; Stefanie Dehnen; Annie K Powell; Jan Reedijk
Journal:  Dalton Trans       Date:  2011-02-15       Impact factor: 4.390

8.  Quantitative evaluation of Lewis acidity of metal ions with different ligands and counterions in relation to the promoting effects of Lewis acids on electron transfer reduction of oxygen.

Authors:  Kei Ohkubo; Saija C Menon; Akihiro Orita; Junzo Otera; Shunichi Fukuzumi
Journal:  J Org Chem       Date:  2003-06-13       Impact factor: 4.354

9.  Cyanobacterial photosystem II at 2.9-A resolution and the role of quinones, lipids, channels and chloride.

Authors:  Albert Guskov; Jan Kern; Azat Gabdulkhakov; Matthias Broser; Athina Zouni; Wolfram Saenger
Journal:  Nat Struct Mol Biol       Date:  2009-02-15       Impact factor: 15.369

10.  Three-coordinate and four-coordinate cobalt hydride complexes that react with dinitrogen.

Authors:  Keying Ding; William W Brennessel; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2009-08-12       Impact factor: 15.419
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  43 in total

1.  Unsymmetrical bimetallic complexes with M(II)-(μ-OH)-M(III) cores (M(II)M(III) = Fe(II)Fe(III), Mn(II)Fe(III), Mn(II)Mn(III)): structural, magnetic, and redox properties.

Authors:  Yohei Sano; Andrew C Weitz; Joseph W Ziller; Michael P Hendrich; A S Borovik
Journal:  Inorg Chem       Date:  2013-08-30       Impact factor: 5.165

2.  Light-driven, proton-controlled, catalytic aerobic C-H oxidation mediated by a Mn(III) porphyrinoid complex.

Authors:  Heather M Neu; Jieun Jung; Regina A Baglia; Maxime A Siegler; Kei Ohkubo; Shunichi Fukuzumi; David P Goldberg
Journal:  J Am Chem Soc       Date:  2015-04-03       Impact factor: 15.419

3.  Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate.

Authors:  Feifei Li; Katherine M Van Heuvelen; Katlyn K Meier; Eckard Münck; Lawrence Que
Journal:  J Am Chem Soc       Date:  2013-07-02       Impact factor: 15.419

4.  Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.

Authors:  Nathaniel S Sickerman; Sonja M Peterson; Joseph W Ziller; A S Borovik
Journal:  Chem Commun (Camb)       Date:  2014-01-24       Impact factor: 6.222

5.  Sulfonamido tripods: tuning redox potentials via ligand modifications.

Authors:  Nathanael Lau; Joseph W Ziller; A S Borovik
Journal:  Polyhedron       Date:  2015-01-08       Impact factor: 3.052

6.  Modular bimetallic complexes with a sulfonamido-based ligand.

Authors:  Nathanael Lau; Yohei Sano; Joseph W Ziller; A S Borovik
Journal:  Dalton Trans       Date:  2018-09-11       Impact factor: 4.390

7.  Molecular designs for controlling the local environments around metal ions.

Authors:  Sarah A Cook; A S Borovik
Journal:  Acc Chem Res       Date:  2015-07-16       Impact factor: 22.384

8.  Synthetic cluster models of biological and heterogeneous manganese catalysts for O2 evolution.

Authors:  Emily Y Tsui; Jacob S Kanady; Theodor Agapie
Journal:  Inorg Chem       Date:  2013-12-16       Impact factor: 5.165

9.  Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with MII-(μ-OH)-FeIII Cores.

Authors:  Yohei Sano; Nathanael Lau; Andrew C Weitz; Joseph W Ziller; Michael P Hendrich; A S Borovik
Journal:  Inorg Chem       Date:  2017-11-07       Impact factor: 5.165

10.  Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.

Authors:  Jieun Jung; Heather M Neu; Pannee Leeladee; Maxime A Siegler; Kei Ohkubo; David P Goldberg; Shunichi Fukuzumi
Journal:  Inorg Chem       Date:  2016-03-14       Impact factor: 5.165
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