Literature DB >> 24457593

Synthesis, structure and reactivity of Fe(II/III)-NH3 complexes bearing a tripodal sulfonamido ligand.

Nathaniel S Sickerman1, Sonja M Peterson, Joseph W Ziller, A S Borovik.   

Abstract

Complexes [M(n)MST(NH3)](n-3) (M(n) = Fe(II), Fe(III), Ga(III)) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the Fe(III)-NH3 complex afforded a putative [Fe(III)MST(NH2)](-) species whose reactivity has been explored.

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Year:  2014        PMID： 24457593      PMCID： PMC3954711          DOI： 10.1039/c3cc48804g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  18 in total

1.  A five-coordinate phosphino/acetate iron(II) scaffold that binds N2, N2H2, N2H4, and NH3 in the sixth site.

Authors:  Caroline T Saouma; Curtis E Moore; Arnold L Rheingold; Jonas C Peters
Journal:  Inorg Chem       Date:  2011-10-17       Impact factor: 5.165

2.  Extension of the self-consistent spectrophotometric basicity scale in acetonitrile to a full span of 28 pKa units: unification of different basicity scales.

Authors:  Ivari Kaljurand; Agnes Kütt; Lilli Sooväli; Toomas Rodima; Vahur Mäemets; Ivo Leito; Ilmar A Koppel
Journal:  J Org Chem       Date:  2005-02-04       Impact factor: 4.354

3.  Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent.

Authors:  Amanda C Bowman; Suzanne C Bart; Frank W Heinemann; Karsten Meyer; Paul J Chirik
Journal:  Inorg Chem       Date:  2009-07-06       Impact factor: 5.165

4.  Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands.

Authors:  David C Lacy; Young Jun Park; Joseph W Ziller; Junko Yano; A S Borovik
Journal:  J Am Chem Soc       Date:  2012-10-15       Impact factor: 15.419

5.  Heterobimetallic Complexes with MIII-(μ-OH)-MII Cores (MIII = Fe, Mn, Ga; MII = Ca, Sr, and Ba): Structural, Kinetic, and Redox Properties.

Authors:  Young Jun Park; Sarah A Cook; Nathaniel S Sickerman; Yohei Sano; Joseph W Ziller; A S Borovik
Journal:  Chem Sci       Date:  2013-02       Impact factor: 9.825

6.  The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.

Authors:  Young Jun Park; Joseph W Ziller; A S Borovik
Journal:  J Am Chem Soc       Date:  2011-05-31       Impact factor: 15.419

7.  Conversion of Fe-NH2 to Fe-N2 with release of NH3.

Authors:  John S Anderson; Marc-Etienne Moret; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2013-01-08       Impact factor: 15.419

Review 8.  Mechanism of Mo-dependent nitrogenase.

Authors:  Lance C Seefeldt; Brian M Hoffman; Dennis R Dean
Journal:  Annu Rev Biochem       Date:  2009       Impact factor: 23.643

9.  Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron.

Authors:  K Cory Macleod; Patrick L Holland
Journal:  Nat Chem       Date:  2013-05-26       Impact factor: 24.427

10.  Catalytic conversion of nitrogen to ammonia by an iron model complex.

Authors:  John S Anderson; Jonathan Rittle; Jonas C Peters
Journal:  Nature       Date:  2013-09-05       Impact factor: 49.962
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  8 in total

Review 1.  Activation of Dinitrogen by Polynuclear Metal Complexes.

Authors:  Devender Singh; William R Buratto; Juan F Torres; Leslie J Murray
Journal:  Chem Rev       Date:  2020-05-04       Impact factor: 60.622

2.  Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with MII-(μ-OH)-FeIII Cores.

Authors:  Yohei Sano; Nathanael Lau; Andrew C Weitz; Joseph W Ziller; Michael P Hendrich; A S Borovik
Journal:  Inorg Chem       Date:  2017-11-07       Impact factor: 5.165

3.  Effects of Noncovalent Interactions on High-Spin Fe(IV)-Oxido Complexes.

Authors:  Victoria F Oswald; Justin L Lee; Saborni Biswas; Andrew C Weitz; Kaustuv Mittra; Ruixi Fan; Jikun Li; Jiyong Zhao; Michael Y Hu; Esen E Alp; Emile L Bominaar; Yisong Guo; Michael T Green; Michael P Hendrich; A S Borovik
Journal:  J Am Chem Soc       Date:  2020-06-24       Impact factor: 15.419

4.  Manganese-Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand.

Authors:  Victoria F Oswald; Andrew C Weitz; Saborni Biswas; Joseph W Ziller; Michael P Hendrich; A S Borovik
Journal:  Inorg Chem       Date:  2018-10-09       Impact factor: 5.165

5.  Exploring secondary-sphere interactions in Fe-N x H y complexes relevant to N2 fixation.

Authors:  Sidney E Creutz; Jonas C Peters
Journal:  Chem Sci       Date:  2016-12-08       Impact factor: 9.825

6.  Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity.

Authors:  Sarah A Cook; Justin A Bogart; Noam Levi; Andrew C Weitz; Curtis Moore; Arnold L Rheingold; Joseph W Ziller; Michael P Hendrich; A S Borovik
Journal:  Chem Sci       Date:  2018-07-02       Impact factor: 9.825

7.  Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate.

Authors:  Lucie Nurdin; Yan Yang; Peter G N Neate; Warren E Piers; Laurent Maron; Michael L Neidig; Jian-Bin Lin; Benjamin S Gelfand
Journal:  Chem Sci       Date:  2020-12-22       Impact factor: 9.825

8.  Investigation of iron-ammine and amido complexes within a C3-symmetrical phosphinic amido tripodal ligand.

Authors:  Chen Sun; Victoria F Oswald; Ethan A Hill; Joseph W Ziller; A S Borovik
Journal:  Dalton Trans       Date:  2021-08-02       Impact factor: 4.569
  8 in total

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