Literature DB >> 21327234

Trigonal propeller-shaped [Mn(III)3M(II)Na] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII.

Sanjit Nayak1, Hari Pada Nayek, Stefanie Dehnen, Annie K Powell, Jan Reedijk.   

Abstract

Two new polynuclear heterometallic cluster complexes with [Mn(III)(3)M(II)Na] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [Mn(III)Ca(II)Na] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.

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Year:  2011        PMID： 21327234     DOI： 10.1039/c0dt01463j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  8 in total

1.  Assembly and properties of heterobimetallic Co(II/III)/Ca(II) complexes with aquo and hydroxo ligands.

Authors:  David C Lacy; Young Jun Park; Joseph W Ziller; Junko Yano; A S Borovik
Journal:  J Am Chem Soc       Date:  2012-10-15       Impact factor: 15.419

2.  Heterobimetallic Complexes with MIII-(μ-OH)-MII Cores (MIII = Fe, Mn, Ga; MII = Ca, Sr, and Ba): Structural, Kinetic, and Redox Properties.

Authors:  Young Jun Park; Sarah A Cook; Nathaniel S Sickerman; Yohei Sano; Joseph W Ziller; A S Borovik
Journal:  Chem Sci       Date:  2013-02       Impact factor: 9.825

3.  A CaMn4O2 model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand.

Authors:  Heui Beom Lee; Emily Y Tsui; Theodor Agapie
Journal:  Chem Commun (Camb)       Date:  2017-06-22       Impact factor: 6.222

Review 4.  Lessons from Nature: A Bio-Inspired Approach to Molecular Design.

Authors:  Sarah A Cook; Ethan A Hill; A S Borovik
Journal:  Biochemistry       Date:  2015-06-30       Impact factor: 3.162

5.  The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.

Authors:  Young Jun Park; Joseph W Ziller; A S Borovik
Journal:  J Am Chem Soc       Date:  2011-05-31       Impact factor: 15.419

6.  Structure and magnetism of two chair-shaped hexanuclear dysprosium(iii) complexes exhibiting slow magnetic relaxation.

Authors:  Zi-Yuan Liu; Hua-Hong Zou; Rong Wang; Man-Sheng Chen; Fu-Pei Liang
Journal:  RSC Adv       Date:  2018-01-03       Impact factor: 4.036

7.  Synthetic cluster models of biological and heterogeneous manganese catalysts for O2 evolution.

Authors:  Emily Y Tsui; Jacob S Kanady; Theodor Agapie
Journal:  Inorg Chem       Date:  2013-12-16       Impact factor: 5.165

8.  Redox-inactive metals modulate the reduction potential in heterometallic manganese-oxido clusters.

Authors:  Emily Y Tsui; Rosalie Tran; Junko Yano; Theodor Agapie
Journal:  Nat Chem       Date:  2013-03-03       Impact factor: 24.427
  8 in total

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