Literature DB >> 18270755

Control of redox reactivity of flavin and pterin coenzymes by metal ion coordination and hydrogen bonding.

Shunichi Fukuzumi1, Takahiko Kojima.   

Abstract

The electron-transfer activities of flavin and pterin coenzymes can be fine-tuned by coordination of metal ions, protonation and hydrogen bonding. Formation of hydrogen bonds with a hydrogen-bond receptor in metal-flavin complexes is made possible depending on the type of coordination bond that can leave the hydrogen-bonding sites. The electron-transfer catalytic functions of flavin and pterin coenzymes are described by showing a number of examples of both thermal and photochemical redox reactions, which proceed by controlling the electron-transfer reactivity of coenzymes with metal ion binding, protonation and hydrogen bonding.

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Year:  2008        PMID： 18270755     DOI： 10.1007/s00775-008-0343-1

Source DB:  PubMed          Journal:  J Biol Inorg Chem        ISSN： 0949-8257            Impact factor:   3.358


  19 in total

1.  Crystal structure of DMSO reductase: redox-linked changes in molybdopterin coordination.

Authors:  H Schindelin; C Kisker; J Hilton; K V Rajagopalan; D C Rees
Journal:  Science       Date:  1996-06-14       Impact factor: 47.728

2.  Substrate recognition by "password" in p-hydroxybenzoate hydroxylase.

Authors:  B A Palfey; G R Moran; B Entsch; D P Ballou; V Massey
Journal:  Biochemistry       Date:  1999-01-26       Impact factor: 3.162

3.  Purification and characterization of a tungsten-containing formate dehydrogenase from Desulfovibrio gigas.

Authors:  M J Almendra; C D Brondino; O Gavel; A S Pereira; P Tavares; S Bursakov; R Duarte; J Caldeira; J J Moura; I Moura
Journal:  Biochemistry       Date:  1999-12-07       Impact factor: 3.162

4.  Metal vs ligand reduction in complexes of 1,3-dimethylalloxazine (DMA) with copper(I), ruthenium(II), and tungsten(VI). Crystal structures of (DMA)WO2Cl2 and (bis(1-methylimidazol-2-yl)ketone)WO2Cl2.

Authors:  F M Hornung; O Heilmann; W Kaim; S Zalis; J Fiedler
Journal:  Inorg Chem       Date:  2000-09-04       Impact factor: 5.165

5.  Quantitative evaluation of Lewis acidity of metal ions derived from the g values of ESR spectra of superoxide: metal ion complexes in relation to the promoting effects in electron transfer reactions.

Authors:  S Fukuzumi; K Ohkubo
Journal:  Chemistry       Date:  2000-12-15       Impact factor: 5.236

6.  Change in spin state and enhancement of redox reactivity of photoexcited states of aromatic carbonyl compounds by complexation with metal ion salts acting as Lewis acids. Lewis acid-catalyzed photoaddition of benzyltrimethylsilane and tetramethyltin via photoinduced electron transfer.

Authors:  S Fukuzumi; N Satoh; T Okamoto; K Yasui; T Suenobu; Y Seko; M Fujitsuka; O Ito
Journal:  J Am Chem Soc       Date:  2001-08-15       Impact factor: 15.419

7.  Quantitative evaluation of Lewis acidity of metal ions with different ligands and counterions in relation to the promoting effects of Lewis acids on electron transfer reduction of oxygen.

Authors:  Kei Ohkubo; Saija C Menon; Akihiro Orita; Junzo Otera; Shunichi Fukuzumi
Journal:  J Org Chem       Date:  2003-06-13       Impact factor: 4.354

8.  Crystal structure of the xanthine oxidase-related aldehyde oxido-reductase from D. gigas.

Authors:  M J Romão; M Archer; I Moura; J J Moura; J LeGall; R Engh; M Schneider; P Hof; R Huber
Journal:  Science       Date:  1995-11-17       Impact factor: 47.728

9.  Structural and electronic effects resulting from metal-flavin ligation.

Authors:  M J Clarke; M G Dowling; A R Garafalo; T F Brennan
Journal:  J Biol Chem       Date:  1980-04-25       Impact factor: 5.157

10.  Proton-coupled electron transfer in ruthenium(II)-pterin complexes: formation of ruthenium-coordinated pterin radicals and their electronic structures.

Authors:  Soushi Miyazaki; Takahiko Kojima; Taisuke Sakamoto; Tetsuya Matsumoto; Kei Ohkubo; Shunichi Fukuzumi
Journal:  Inorg Chem       Date:  2007-11-30       Impact factor: 5.165
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  8 in total

1.  The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.

Authors:  Young Jun Park; Joseph W Ziller; A S Borovik
Journal:  J Am Chem Soc       Date:  2011-05-31       Impact factor: 15.419

2.  Proton-coupled electron transfer of ruthenium(III)-pterin complexes: a mechanistic insight.

Authors:  Soushi Miyazaki; Takahiko Kojima; James M Mayer; Shunichi Fukuzumi
Journal:  J Am Chem Soc       Date:  2009-08-19       Impact factor: 15.419

3.  Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxyl-ato-κ(3) O (4),N (5),O (6))aqua-(1,10-phenanthroline-κ(2) N,N')zinc trihydrate.

Authors:  Siddhartha S Baisya; Baidyanath Ghosh; Parag S Roy
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-08-12

4.  Photoredox Catalysis in Organic Chemistry.

Authors:  Megan H Shaw; Jack Twilton; David W C MacMillan
Journal:  J Org Chem       Date:  2016-08-01       Impact factor: 4.354

5.  Modulating catalytic activity of a modified flavin analogue via judicially positioned metal ion toward aerobic sulphoxidation.

Authors:  M S S Vinod Mouli; Ashutosh Kumar Mishra
Journal:  RSC Adv       Date:  2022-02-01       Impact factor: 3.361

6.  (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl-ato-κ(3)O(4),N(5),O(6))aqua-(ethane-1,2-diamine-κ(2)N,N')nickel(II) dihydrate.

Authors:  Siddhartha S Baisya; Parag S Roy
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-01-12

7.  (2-Amino-7-methyl-4-oxido-pteridine-6-carboxyl-ato-κ(3) O (4),N (5),O (6))aqua(1,10-phen-an-thro-line-κ(2) N,N')cobalt(II) trihydrate.

Authors:  Siddhartha S Baisya; Samir Sen; Parag S Roy
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-12-22

8.  (2-Amino-7-methyl-4-oxidopteridine-6-carboxyl-ato-κ(3) O (4),N (5),O (6))(ethane-1,2-diamine-κ(2) N,N')(1H-imidazole-κN (3))nickel(II) dihydrate.

Authors:  Siddhartha S Baisya; Parag S Roy
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-03-09
  8 in total

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