| Literature DB >> 21230061 |
Pavol Kalinay1, Jerome K Percus.
Abstract
Mapping of the diffusion equation in a channel of varying cross section onto the longitudinal coordinate is already a well studied procedure for a slowly changing radius. We examine here the mapping of diffusion in a channel with abrupt change of diameter. In two dimensions, our considerations are based on solution of the exactly solvable geometry with abruptly doubled width at x=0. We verify the surmise of Berezhkovskii [J. Chem. Phys. 131, 224110 (2009)] that one-dimensional diffusion behaves as free in such channels everywhere except at the point of change, which looks like a local trap for the particles. Applying the method of "sewing" of solutions, we show that this picture is valid also for three-dimensional symmetric channels.Year: 2010 PMID: 21230061 DOI: 10.1103/PhysRevE.82.031143
Source DB: PubMed Journal: Phys Rev E Stat Nonlin Soft Matter Phys ISSN: 1539-3755