| Literature DB >> 21210070 |
Jason B Benedict1, Anna Makal, Jesse D Sokolow, Elzbieta Trzop, Stephan Scheins, Robert Henning, Timothy Graber, Philip Coppens.
Abstract
The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) Å is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.Entities:
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Year: 2011 PMID: 21210070 PMCID: PMC3129623 DOI: 10.1039/c0cc04997b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222