Literature DB >> 15467843

A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction.

Philip Coppens1, Oksana Gerlits, Ivan I Vorontsov, Andrey Yu Kovalevsky, Yu-Sheng Chen, Tim Graber, Milan Gembicky, Irina V Novozhilova.   

Abstract

A very large Rh-Rh contraction of approximately 0.85 A occurs on excitation of the [Rh(2)(1,8-diisocyano-p-menthane)(4)](2+) ion to its triplet state.

Entities:  

Year:  2004        PMID： 15467843     DOI： 10.1039/b409463h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Time-resolved synchrotron diffraction and theoretical studies of very short-lived photo-induced molecular species.

Authors:  Philip Coppens; Jason Benedict; Marc Messerschmidt; Irina Novozhilova; Tim Graber; Yu-Sheng Chen; Ivan Vorontsov; Stephan Scheins; Shao-Liang Zheng
Journal:  Acta Crystallogr A       Date:  2010-02-18       Impact factor: 2.290

2.  Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4.

Authors:  Jason B Benedict; Anna Makal; Jesse D Sokolow; Elzbieta Trzop; Stephan Scheins; Robert Henning; Timothy Graber; Philip Coppens
Journal:  Chem Commun (Camb)       Date:  2011-01-06       Impact factor: 6.222

3.  The dramatic development of X-ray photocrystallography over the past six decades.

Authors:  Philip Coppens
Journal:  Struct Dyn       Date:  2017-02-01       Impact factor: 2.920

4.  Solid-state interconversions: unique 100 % reversible transformations between the ground and metastable states in single-crystals of a series of nickel(II) nitro complexes.

Authors:  Mark R Warren; Timothy L Easun; Simon K Brayshaw; Robert J Deeth; Michael W George; Andrew L Johnson; Stefanie Schiffers; Simon J Teat; Anna J Warren; John E Warren; Chick C Wilson; Christopher H Woodall; Paul R Raithby
Journal:  Chemistry       Date:  2014-03-18       Impact factor: 5.236

5.  Perspective: On the relevance of slower-than-femtosecond time scales in chemical structural-dynamics studies.

Authors:  Philip Coppens
Journal:  Struct Dyn       Date:  2015-02-24       Impact factor: 2.920
  5 in total

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