Literature DB >> 20420453

Structure-selective modification of aromatic side chains with dirhodium metallopeptide catalysts.

Brian V Popp1, Zachary T Ball.   

Abstract

The combination of peptide molecular recognition and residue-selective dirhodium catalysis allows modification of aromatic side chains that is selective for coil structures. A rate enhancement of >10(3) relative to nonselective dirhodium modification was observed. The increased reactivity of this approach creates the first selective chemical modification of the phenylalanine residue.

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Year:  2010        PMID： 20420453     DOI： 10.1021/ja101456c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  26 in total

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Journal:  Org Biomol Chem       Date:  2020-05-06       Impact factor: 3.876
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