Literature DB >> 20017549

Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids.

Bing-Feng Shi1, Yang-Hui Zhang, Jonathan K Lam, Dong-Hui Wang, Jin-Quan Yu.   

Abstract

Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acid substrates has been achieved through the use of monoprotected chiral amino acid ligands. The absolute configuration of the resulting olefinated products is consistent with that of a proposed C-H insertion intermediate.

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Year:  2010        PMID： 20017549      PMCID： PMC2806936          DOI： 10.1021/ja909571z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  16 in total

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  53 in total

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9.  Iridium-Catalyzed, β-Selective C(sp3)-H Silylation of Aliphatic Amines To Form Silapyrrolidines and 1,2-Amino Alcohols.

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