Literature DB >> 18834125

Synthesis of 1,2- and 1,3-dicarboxylic acids via Pd(II)-catalyzed carboxylation of aryl and vinyl C-H bonds.

Ramesh Giri1, Jin-Quan Yu.   

Abstract

A Pd(II)-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivatives to form dicarboxylic acids has been developed. The reaction conditions are also applicable for the carboxylation of vinyl C-H bonds. The first C-H insertion Pd-aryl complex from carboxylic acids has been characterized by X-ray crystallography.

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Year:  2008        PMID: 18834125     DOI: 10.1021/ja8063827

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  40 in total

1.  Weak coordination as a powerful means for developing broadly useful C-H functionalization reactions.

Authors:  Keary M Engle; Tian-Sheng Mei; Masayuki Wasa; Jin-Quan Yu
Journal:  Acc Chem Res       Date:  2011-12-14       Impact factor: 22.384

2.  Heterocycle Formation via Palladium-Catalyzed C-H Functionalization.

Authors:  Tian-Sheng Mei; Lei Kou; Sandy Ma; Keary M Engle; Jin-Quan Yu
Journal:  Synthesis (Stuttg)       Date:  2012-05-25       Impact factor: 3.157

3.  Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide.

Authors:  Ya Du; Todd K Hyster; Tomislav Rovis
Journal:  Chem Commun (Camb)       Date:  2011-10-17       Impact factor: 6.222

4.  Aminoquinoline-directed, cobalt-catalyzed carbonylation of sulfonamide sp2 C-H bonds.

Authors:  Tung Thanh Nguyen; Liene Grigorjeva; Olafs Daugulis
Journal:  Chem Commun (Camb)       Date:  2017-05-04       Impact factor: 6.222

5.  Intermolecular Heck Coupling with Hindered Alkenes Directed by Potassium Carboxylates.

Authors:  Tucker R Huffman; Yebin Wu; Alexis Emmerich; Ryan A Shenvi
Journal:  Angew Chem Int Ed Engl       Date:  2019-01-25       Impact factor: 15.336

6.  Room-temperature palladium-catalyzed C-H activation: ortho-carbonylation of aniline derivatives.

Authors:  Chris E Houlden; Marc Hutchby; Chris D Bailey; J Gair Ford; Simon N G Tyler; Michel R Gagné; Guy C Lloyd-Jones; Kevin I Booker-Milburn
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

7.  Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groups.

Authors:  Gang Li; Li Wan; Guofu Zhang; Dasheng Leow; Jillian Spangler; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2015-03-24       Impact factor: 15.419

8.  Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids.

Authors:  Bing-Feng Shi; Yang-Hui Zhang; Jonathan K Lam; Dong-Hui Wang; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2010-01-20       Impact factor: 15.419

9.  Copper-catalyzed ortho-acylation of phenols with aryl aldehydes and its application in one-step preparation of xanthones.

Authors:  Jun Hu; Enoch A Adogla; Yong Ju; Daping Fan; Qian Wang
Journal:  Chem Commun (Camb)       Date:  2012-10-15       Impact factor: 6.222

10.  Dehydrogenative alkenylation of uracils via palladium-catalyzed regioselective C-H activation.

Authors:  Yi-Yun Yu; Gunda I Georg
Journal:  Chem Commun (Camb)       Date:  2013-03-25       Impact factor: 6.222

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