Literature DB >> 19685873

Rhodium-catalyzed highly enantioselective direct intermolecular hydroacylation of 1,1-disubstituted alkenes with unfunctionalized aldehydes.

Yu Shibata1, Ken Tanaka.   

Abstract

We have established that a cationic rhodium(I)/(R,R)-QuinoxP* complex catalyzes the highly enantioselective direct intermolecular hydroacylation of alpha-substituted acrylamides with unfunctionalized aliphatic aldehydes to yield the corresponding gamma-ketoamides in high yields with excellent ee values.

Entities:  

Year:  2009        PMID： 19685873     DOI： 10.1021/ja905908z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

1.  Intermolecular Markovnikov-Selective Hydroacylation of Olefins Catalyzed by a Cationic Ruthenium-Hydride Complex.

Authors:  Junghwa Kim; Chae S Yi
Journal:  ACS Catal       Date:  2016-04-19       Impact factor: 13.084

2.  Hydroacylation of alpha,beta-unsaturated esters via aerobic C-H activation.

Authors:  Vijay Chudasama; Richard J Fitzmaurice; Stephen Caddick
Journal:  Nat Chem       Date:  2010-06-06       Impact factor: 24.427

3.  Enantioselective hydroacylation of olefins with rhodium catalysts.

Authors:  Stephen K Murphy; Vy M Dong
Journal:  Chem Commun (Camb)       Date:  2014-11-18       Impact factor: 6.222

4.  Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates.

Authors:  Yujing Zhou; Jeffrey S Bandar; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2017-06-06       Impact factor: 15.419

5.  Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids.

Authors:  Bing-Feng Shi; Yang-Hui Zhang; Jonathan K Lam; Dong-Hui Wang; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2010-01-20       Impact factor: 15.419

6.  Rhodium(I)-Catalyzed Intermolecular Hydroacylation of α-Keto Amides and Isatins with Non-Chelating Aldehydes.

Authors:  Kevin G M Kou; Lauren E Longobardi; Vy M Dong
Journal:  Adv Synth Catal       Date:  2015-07-14       Impact factor: 5.837

7.  Theoretical investigation of Co(0)-catalyzed intramolecular hydroacylation of 4-pentenal.

Authors:  Qingxi Meng; Fen Wang; Ming Li
Journal:  J Mol Model       Date:  2013-01-31       Impact factor: 1.810

8.  Substrate-directed hydroacylation: rhodium-catalyzed coupling of vinylphenols and nonchelating aldehydes.

Authors:  Stephen K Murphy; Achim Bruch; Vy M Dong
Journal:  Angew Chem Int Ed Engl       Date:  2014-01-29       Impact factor: 15.336

Review 9.  Teaching Aldehydes New Tricks Using Rhodium- and Cobalt-Hydride Catalysis.

Authors:  Ryan T Davison; Erin L Kuker; Vy M Dong
Journal:  Acc Chem Res       Date:  2021-02-03       Impact factor: 22.384

10.  α- and β-Functionalized Ketones from 1,3-Dienes and Aldehydes: Control of Regio- and Enantioselectivity in Hydroacylation of 1,3-Dienes.

Authors:  Mahesh M Parsutkar; T V RajanBabu
Journal:  J Am Chem Soc       Date:  2021-08-05       Impact factor: 15.419
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