Literature DB >> 18663711

Biaryl phosphane ligands in palladium-catalyzed amination.

David S Surry1, Stephen L Buchwald.   

Abstract

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses the application of these catalysts in C-N cross-coupling reactions in the synthesis of heterocycles and pharmaceuticals, in materials science, and in natural product synthesis.

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Year:  2008        PMID: 18663711      PMCID: PMC3517088          DOI: 10.1002/anie.200800497

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  158 in total

1.  The azaallylic anion as a synthon for pd-catalyzed synthesis of heterocycles: domino two- and three-component synthesis of indoles.

Authors:  José Barluenga; Agustín Jiménez-Aquino; Carlos Valdés; Fernando Aznar
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

2.  Pd-catalyzed Kumada-Corriu cross-coupling reactions at low temperatures allow the use of Knochel-type Grignard reagents.

Authors:  Ruben Martin; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2007-03-13       Impact factor: 15.419

3.  Selective palladium-catalyzed arylation of ammonia: synthesis of anilines as well as symmetrical and unsymmetrical di- and triarylamines.

Authors:  David S Surry; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2007-08-02       Impact factor: 15.419

4.  An improved method for the palladium-catalyzed amination of aryl iodides.

Authors:  M H Ali; S L Buchwald
Journal:  J Org Chem       Date:  2001-04-20       Impact factor: 4.354

5.  Efficient access to cyclic ureas via Pd-catalyzed cyclization.

Authors:  Mark McLaughlin; Michael Palucki; Ian W Davies
Journal:  Org Lett       Date:  2006-07-20       Impact factor: 6.005

6.  Novel method for the synthesis of enamines by palladium catalyzed amination of alkenyl bromides.

Authors:  José Barluenga; M Alejandro Fernández; Fernando Aznar; Carlos Valdés
Journal:  Chem Commun (Camb)       Date:  2002-10-21       Impact factor: 6.222

7.  Synthesis of bulky and electron-rich MOP-type ligands and their applications in palladium-catalyzed C-N bond formation.

Authors:  Xiaomin Xie; Tony Y Zhang; Zhaoguo Zhang
Journal:  J Org Chem       Date:  2006-08-18       Impact factor: 4.354

8.  Monoligated palladium species as catalysts in cross-coupling reactions.

Authors:  Ute Christmann; Ramón Vilar
Journal:  Angew Chem Int Ed Engl       Date:  2005-01-07       Impact factor: 15.336

9.  Addition of alkynes to aldehydes and activated ketones catalyzed by rhodium-phosphine complexes.

Authors:  Pawan K Dhondi; Patrick Carberry; Lydia B Choi; John D Chisholm
Journal:  J Org Chem       Date:  2007-11-14       Impact factor: 4.354

10.  Rapid and efficient microwave-assisted synthesis of aryl aminobenzophenones using Pd-catalyzed amination.

Authors:  Thomas A Jensen; Xifu Liang; David Tanner; Niels Skjaerbaek
Journal:  J Org Chem       Date:  2004-07-23       Impact factor: 4.354

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  151 in total

1.  Cross-Coupling Reactions of Alkenylsilanols with Fluoroalkylsulfonates: Development and Optimization of a Mild and Stereospecific Coupling Process.

Authors:  Scott E Denmark; Christopher S Regens
Journal:  Tetrahedron Lett       Date:  2011-04-27       Impact factor: 2.415

2.  Use of aryl chlorides as electrophiles in Pd-catalyzed alkene difunctionalization reactions.

Authors:  Brandon R Rosen; Joshua E Ney; John P Wolfe
Journal:  J Org Chem       Date:  2010-04-16       Impact factor: 4.354

3.  Concise palladium-catalyzed synthesis of dibenzodiazepines and structural analogues.

Authors:  Dmitry Tsvelikhovsky; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2011-08-22       Impact factor: 15.419

4.  Pd-catalyzed arylation of linear and angular spirodiamine salts under aerobic conditions.

Authors:  Sean W Reilly; Nikaela W Bryan; Robert H Mach
Journal:  Tetrahedron Lett       Date:  2016-12-23       Impact factor: 2.415

5.  Asymmetric Pd-Catalyzed Alkene Carboamination Reactions for the Synthesis of 2-Aminoindane Derivatives.

Authors:  Derick R White; Johnathon T Hutt; John P Wolfe
Journal:  J Am Chem Soc       Date:  2015-08-27       Impact factor: 15.419

6.  Highly diastereoselective Pd-catalyzed carboetherification reactions of acyclic internal alkenes. Stereoselective synthesis of polysubstituted tetrahydrofurans.

Authors:  Amanda F Ward; John P Wolfe
Journal:  Org Lett       Date:  2010-03-19       Impact factor: 6.005

7.  Influence of hydroxylamine conformation on stereocontrol in Pd-catalyzed isoxazolidine-forming reactions.

Authors:  Georgia S Lemen; Natalie C Giampietro; Michael B Hay; John P Wolfe
Journal:  J Org Chem       Date:  2009-03-20       Impact factor: 4.354

8.  Metal-Free Direct Amidation of Naphthoquinones Using Hydroxamic Acids as an Amide Source: Application in the Synthesis of an HDAC6 Inhibitor.

Authors:  Cheng Zhang; C James Chou
Journal:  Org Lett       Date:  2016-10-19       Impact factor: 6.005

9.  Rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated alkenes.

Authors:  Xiaoqiang Shen; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2010       Impact factor: 15.336

10.  Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature.

Authors:  Tokutaro Ogata; John F Hartwig
Journal:  J Am Chem Soc       Date:  2008-09-24       Impact factor: 15.419

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