| Literature DB >> 17958433 |
Marleen Körner1, Martin Hiersemann.
Abstract
The enantioselective synthesis of the C8-C20 fragment of curvicollide C has been accomplished. A catalytic asymmetric Claisen rearrangement (CAC), a diastereoselective methyl cupration of an alkynoate, and a Julia-Kocienski olefination served as key C/C-connecting transformations.Entities:
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Year: 2007 PMID: 17958433 DOI: 10.1021/ol702092h
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005