Literature DB >> 17887684

Trans-dioxo manganese(V) porphyrins.

Ning Jin1, Mohammed Ibrahim, Thomas G Spiro, John T Groves.   

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Year:  2007        PMID： 17887684      PMCID： PMC2773832          DOI： 10.1021/ja0761737

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


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5.  Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.

Authors:  Rui Zhang; John H Horner; Martin Newcomb
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6.  Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.

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7.  Electronic structure and reactivity of isomeric oxo-Mn(V) porphyrins: effects of spin-state crossing and pKa modulation.

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8.  Modeling the haloperoxidases: reversible oxygen atom transfer between bromide ion and an oxo-Mn(V) porphyrin.

Authors:  Dorothée Lahaye; John T Groves
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9.  17O NMR study of oxo metalloporphyrin complexes: correlation with electronic structure of M=O moiety.

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10.  Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification.

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