Literature DB >> 16967197

Synthesis of functionalized 5-imino-2,5-dihydro-furans through the reaction of isocyanides with activated acetylenes in the presence of ethyl bromopyruvate.

Issa Yavari1, Zinatossadat Hossaini, Maryam Sabbaghan.   

Abstract

The reaction between alkyl(aryl) isocyanides and dibenzoylacetylene in the presence of ethyl bromopyruvate leads to ethyl 3,4-dibenzoyl-2-bromomethyl-5-alkyl(aryl)imino-2,5-dihydro-furan-2-carboxylates in high yields. Dialkyl acetylenedicarboxylates react with tert-butyl isocyanide and ethyl bromopyruvate to produce 3,4-dialkyl 2-ethyl 2-bromomethyl-5-tert-butylimino-2,5-dihydro-furan-2,3,4-tricarboxylates.

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Year:  2006        PMID： 16967197     DOI： 10.1007/s11030-006-9034-4

Source DB:  PubMed          Journal:  Mol Divers        ISSN： 1381-1991            Impact factor:   2.943


  3 in total

1.  Multicomponent Reactions with Isocyanides.

Authors: 
Journal:  Angew Chem Int Ed Engl       Date:  2000-09-15       Impact factor: 15.336

Review 2.  Recent developments in isocyanide based multicomponent reactions in applied chemistry.

Authors:  Alexander Dömling
Journal:  Chem Rev       Date:  2006-01       Impact factor: 60.622

3.  Strategies for heterocyclic construction via novel multicomponent reactions based on isocyanides and nucleophilic carbenes.

Authors:  Vijay Nair; C Rajesh; A U Vinod; S Bindu; A R Sreekanth; J S Mathen; Lakshmi Balagopal
Journal:  Acc Chem Res       Date:  2003-12       Impact factor: 22.384
  3 in total
  12 in total

Review 1.  Recent progress of isocyanide-based multicomponent reactions in Iran.

Authors:  Ahmad Shaabani; Ali Maleki; Ali Hossein Rezayan; Afshin Sarvary
Journal:  Mol Divers       Date:  2010-07-29       Impact factor: 2.943

2.  Diastereoselective synthesis of fused [1,3]oxazines from ethyl pyruvate, activated acetylenes and N-heterocycles.

Authors:  Issa Yavari; Anvar Mirzaei; Zinatosadat Hossaini; Sanaz Souri
Journal:  Mol Divers       Date:  2009-07-04       Impact factor: 2.943

3.  One-pot synthesis of γ -spiroiminolactones and γ -dispiroiminolactones using N,N'-disubstituted parabanic acid and thioparabanic acid derivatives.

Authors:  Sakineh Asghari; Mohammad Qandalee; Amir Ali Sarmadi
Journal:  Mol Divers       Date:  2016-09-20       Impact factor: 2.943

4.  A novel four-component reaction for the synthesis of disubstituted 1,3,4-oxadiazole derivatives.

Authors:  Ali Ramazani; Nahid Shajari; Amir Mahyari; Yavar Ahmadi
Journal:  Mol Divers       Date:  2010-09-03       Impact factor: 2.943

5.  Domino Michael-O-alkylation: one-pot synthesis of dialkyl 4-oxo-2,3-dihydro-2,3-furandicarboxylates.

Authors:  Issa Yavari; Mehdi Sirouspour; Sanaz Souri
Journal:  Mol Divers       Date:  2010-09-10       Impact factor: 2.943

6.  Diastereoselective synthesis of fused [1,3]thiazolo[1,3]oxazins and [1,3]oxazino[2,3-b][1,3]benzothiazoles.

Authors:  Issa Yavari; Zinatossadat Hossaini; Sanaz Souri; Samereh Seyfi
Journal:  Mol Divers       Date:  2009-03-13       Impact factor: 2.943

7.  One-pot synthesis of functionalized 4-oxo-2-thioxo-1,3-thiazinanes from primary amines, CS(2), and itaconic anhydride.

Authors:  Issa Yavari; Mehdi Sirouspour; Sanaz Souri
Journal:  Mol Divers       Date:  2009-09-11       Impact factor: 2.943

8.  A synthesis of phosphorylated dioxohexahydropyrimidines from N,N'-dimethylurea, activated acetylenes, and trialkyl phosphites.

Authors:  Issa Yavari; Manijeh Nematpour; Zinatossadat Hossaini
Journal:  Mol Divers       Date:  2009-09-11       Impact factor: 2.943

9.  Multicomponent reactions of dimethyl methoxymalonate and dialkyl acetylenedicarboxylate in the presence of N-nucleophiles: one-pot synthesis of 2H-pyridinyl-2-butenedioates in water.

Authors:  Mohammad A Khalilzadeh; Zinatossadat Hossaini; Samaneh Kharian
Journal:  Mol Divers       Date:  2009-09-11       Impact factor: 2.943

10.  Efficient and green synthesis of tetrasubstituted pyrroles promoted by task-specific basic ionic liquids as catalyst in aqueous media.

Authors:  Issa Yavari; Elaheh Kowsari
Journal:  Mol Divers       Date:  2009-04-21       Impact factor: 2.943
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