Literature DB >> 16608321

Characterization of the terminal iron(IV) imides [[PhBP(t)(Bu)2(pz')]Fe(IV)NAd]+.

Christine M Thomas1, Neal P Mankad, Jonas C Peters.   

Abstract

New hybrid bis(phosphine)(pyrazole)borate tripodal ligands ([PhBPtBu2(pz')]-) are reported that support pseudotetrahedral iron in the oxidation states +1, +2, +3, and +4. The higher oxidation states are stabilized by a terminal FeNR linkage. Of particular interest is the generation and thorough characterization of an S = 1 FeIVNR+ imide cation using this new ligand system. The latter species can be observed electrochemically and spectroscopically, and its solid-state crystal structure is reported.

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Year:  2006        PMID： 16608321      PMCID： PMC2888259          DOI： 10.1021/ja0604358

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  16 in total

1.  The elusive terminal imido of manganese(v).

Authors:  Rebecca A Eikey; Saeed I Khan; Mahdi M Abu-Omar
Journal:  Angew Chem Int Ed Engl       Date:  2002-10-04       Impact factor: 15.336

2.  Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers.

Authors:  Miguel A Casado; Verena Hack; José A Camerano; Miguel A Ciriano; Cristina Tejel; Luis A Oro
Journal:  Inorg Chem       Date:  2005-12-12       Impact factor: 5.165

3.  Catalytic copolymerization of CO and ethylene with a charge neutral palladium(II) zwitterion.

Authors:  Connie C Lu; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2002-05-15       Impact factor: 15.419

4.  Terminal amido and imido complexes of three-coordinate nickel.

Authors:  D J Mindiola; G L Hillhouse
Journal:  J Am Chem Soc       Date:  2001-05-16       Impact factor: 15.419

5.  Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex.

Authors:  Jan-Uwe Rohde; Jun-Hee In; Mi Hee Lim; William W Brennessel; Michael R Bukowski; Audria Stubna; Eckard Münck; Wonwoo Nam; Lawrence Que
Journal:  Science       Date:  2003-02-14       Impact factor: 47.728

6.  Terminal cobalt(III) imido complexes supported by tris(carbene) ligands: imido insertion into the cobalt-carbene bond.

Authors:  Xile Hu; Karsten Meyer
Journal:  J Am Chem Soc       Date:  2004-12-22       Impact factor: 15.419

7.  Preparation of iron amido complexes via putative Fe(IV) imido intermediates.

Authors:  Robie L Lucas; Douglas R Powell; A S Borovik
Journal:  J Am Chem Soc       Date:  2005-08-24       Impact factor: 15.419

8.  [Me2NN]Co(eta6-toluene): O=O, N=N, and O=N bond cleavage provides beta-diketiminato cobalt mu-oxo and imido complexes.

Authors:  Xuliang Dai; Pooja Kapoor; Timothy H Warren
Journal:  J Am Chem Soc       Date:  2004-04-21       Impact factor: 15.419

9.  Hydrogenolysis of [PhBP3]Fe[triple bond]N-p-tolyl: probing the reactivity of an iron imide with H2.

Authors:  Steven D Brown; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2004-04-14       Impact factor: 15.419

10.  Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms.

Authors:  Theodore A Betley; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2003-09-10       Impact factor: 15.419
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  25 in total

1.  High-Spin Iron Imido Complexes Competent for C-H Bond Amination.

Authors:  Matthew J T Wilding; Diana A Iovan; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2017-08-18       Impact factor: 15.419

2.  Characterization of Iron-Imido Species Relevant for N-Group Transfer Chemistry.

Authors:  Diana A Iovan; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2016-02-04       Impact factor: 15.419

3.  Direct Manipulation of Metal Imido Geometry: Key Principles to Enhance C-H Amination Efficacy.

Authors:  Yunjung Baek; Elisabeth T Hennessy; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2019-10-10       Impact factor: 15.419

4.  M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).

Authors:  Caroline T Saouma; Jonas C Peters
Journal:  Coord Chem Rev       Date:  2011-04       Impact factor: 22.315

5.  Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.

Authors:  Ryan E Cowley; Nathan J DeYonker; Nathan A Eckert; Thomas R Cundari; Serena DeBeer; Eckhard Bill; Xavier Ottenwaelder; Christine Flaschenriem; Patrick L Holland
Journal:  Inorg Chem       Date:  2010-07-05       Impact factor: 5.165

6.  Unprecedented Five-Coordinate Iron(IV) Imides Generate Divergent Spin States Based on the Imide R-Groups.

Authors:  Markus R Anneser; Gaya R Elpitiya; Jacob Townsend; Elizabeth J Johnson; Xian B Powers; Joseph F DeJesus; Konstantinos D Vogiatzis; David M Jenkins
Journal:  Angew Chem Int Ed Engl       Date:  2019-05-07       Impact factor: 15.336

7.  A Mononuclear Nonheme Iron(V)-Imido Complex.

Authors:  Seungwoo Hong; Kyle D Sutherlin; Anil Kumar Vardhaman; James J Yan; Sora Park; Yong-Min Lee; Soojeong Jang; Xiaoyan Lu; Takehiro Ohta; Takashi Ogura; Edward I Solomon; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2017-06-23       Impact factor: 15.419

8.  Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.

Authors:  Marc-Etienne Moret; Jonas C Peters
Journal:  Angew Chem Int Ed Engl       Date:  2011-01-26       Impact factor: 15.336

9.  Synthesis and Structures of Dimeric Iron(III)-Oxo and -Imido Complexes Containing Intramolecular Hydrogen Bonds.

Authors:  Matthew K Zart; Douglas Powell; A S Borovik
Journal:  Inorganica Chim Acta       Date:  2007-05-02       Impact factor: 2.545

10.  H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2.

Authors:  Daniel L M Suess; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2013-03-20       Impact factor: 15.419
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