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Literature DB >> 23472709

H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2.

Abstract

The synthesis and characterization of Fe-diphosphineborane complexes are described in the context of N2 functionalization chemistry. Iron aminoimides can be generated at room temperature under 1 atm N2 and are shown to react with E-H bonds from PhSiH3 and H2. The resulting products derive from delivery of the E fragment to Nα and the H atom to B. The flexibility and lability of the Fe-BPh interactions in these complexes engender this reactivity.

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Year: 2013 PMID： 23472709 PMCID： PMC3770781 DOI： 10.1021/ja400836u

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

33 in total

1. Transition-metal complexes featuring Z-type ligands: agreement or discrepancy between geometry and d(n) configuration?

Authors: Marie Sircoglou; Sébastien Bontemps; Maxime Mercy; Nathalie Saffon; Masashi Takahashi; Ghenwa Bouhadir; Laurent Maron; Didier Bourissou
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

2. Side-on end-on bound dinitrogen: an activated bonding mode that facilitates functionalizing molecular nitrogen.

Authors: Michael D Fryzuk
Journal: Acc Chem Res Date: 2009-01-20 Impact factor: 22.384

3. Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex.

Authors: Donald J Knobloch; Emil Lobkovsky; Paul J Chirik
Journal: Nat Chem Date: 2009-12-13 Impact factor: 24.427

4. On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species.

Authors: Michael P Hendrich; William Gunderson; Rachel K Behan; Michael T Green; Mark P Mehn; Theodore A Betley; Connie C Lu; Jonas C Peters
Journal: Proc Natl Acad Sci U S A Date: 2006-11-07 Impact factor: 11.205

5. Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes.

Authors: Caroline T Saouma; R Adam Kinney; Brian M Hoffman; Jonas C Peters
Journal: Angew Chem Int Ed Engl Date: 2011-03-10 Impact factor: 15.336

6. N=N bond cleavage by a low-coordinate ironII hydride complex.

Authors: Jeremy M Smith; Rene J Lachicotte; Patrick L Holland
Journal: J Am Chem Soc Date: 2003-12-24 Impact factor: 15.419

7. Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions.

Authors: Masahiro Yuki; Hiromasa Tanaka; Kouitsu Sasaki; Yoshihiro Miyake; Kazunari Yoshizawa; Yoshiaki Nishibayashi
Journal: Nat Commun Date: 2012 Impact factor: 14.919

8. Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex.

Authors: Jaime A Pool; Emil Lobkovsky; Paul J Chirik
Journal: Nature Date: 2004-02-05 Impact factor: 49.962

9. Hydrosilylation of a dinuclear tantalum dinitrogen complex: cleavage of N2 and functionalization of both nitrogen atoms.

Authors: Michael D Fryzuk; Bruce A MacKay; Brian O Patrick
Journal: J Am Chem Soc Date: 2003-03-19 Impact factor: 15.419

10. Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms.

Authors: Theodore A Betley; Jonas C Peters
Journal: J Am Chem Soc Date: 2003-09-10 Impact factor: 15.419

9 in total

1. Effects of N₂ Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex.

Authors: Sean F McWilliams; Eckhard Bill; Gudrun Lukat-Rodgers; Kenton R Rodgers; Brandon Q Mercado; Patrick L Holland
Journal: J Am Chem Soc Date: 2018-06-29 Impact factor: 15.419

2. Electronic Structures of an [Fe(NNR₂)]^+/0/- Redox Series: Ligand Noninnocence and Implications for Catalytic Nitrogen Fixation.

Authors: Niklas B Thompson; Paul H Oyala; Hai T Dong; Matthew J Chalkley; Jiyong Zhao; E Ercan Alp; Michael Hu; Nicolai Lehnert; Jonas C Peters
Journal: Inorg Chem Date: 2019-02-14 Impact factor: 5.165

H-H and Si-H bond addition to Fe≡NNR2 intermediates derived from N2.

1. Transition-metal complexes featuring Z-type ligands: agreement or discrepancy between geometry and d(n) configuration?

2. Side-on end-on bound dinitrogen: an activated bonding mode that facilitates functionalizing molecular nitrogen.

3. Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex.

4. On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species.

5. Transformation of an [Fe(η2-N2H3)]+ species to π-delocalized [Fe2(μ-N2H2)](2+/+) complexes.

6. N=N bond cleavage by a low-coordinate ironII hydride complex.

7. Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions.

8. Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex.

9. Hydrosilylation of a dinuclear tantalum dinitrogen complex: cleavage of N2 and functionalization of both nitrogen atoms.

10. Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms.

1. Effects of N₂ Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex.

2. Electronic Structures of an [Fe(NNR₂)]^+/0/- Redox Series: Ligand Noninnocence and Implications for Catalytic Nitrogen Fixation.

Review 3. Activation of Dinitrogen by Polynuclear Metal Complexes.

4. Heterolytic H₂ Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane.

5. A CO-derived iron dicarbyne that releases olefin upon hydrogenation.

Review 6. Dinitrogen binding and cleavage by multinuclear iron complexes.

7. Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides.

8. Reversible addition of ethylene to a pincer-based boryl-iridium unit with the formation of a bridging ethylidene.

9. Binding of dinitrogen to an iron-sulfur-carbon site.