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Literature DB >> 21344552

Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.

Marc-Etienne Moret¹, Jonas C Peters.

Abstract

Entities: Chemical Disease Gene Species

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Year: 2011 PMID： 21344552 PMCID： PMC4165522 DOI： 10.1002/anie.201006918

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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33 in total

1. Nitrogenase MoFe-protein at 1.16 A resolution: a central ligand in the FeMo-cofactor.

Authors: Oliver Einsle; F Akif Tezcan; Susana L A Andrade; Benedikt Schmid; Mika Yoshida; James B Howard; Douglas C Rees
Journal: Science Date: 2002-09-06 Impact factor: 47.728

2. Electron-precise coordination modes of boron-centered ligands.

Authors: Holger Braunschweig; Rian D Dewhurst; Achim Schneider
Journal: Chem Rev Date: 2010-07-14 Impact factor: 60.622

3. Reactivity of the metal-->BX3 dative sigma-bond: 1,2-addition reactions of the Fe-->BX3 moiety of the ferraboratrane complex [kappa4-B(mimBu t)3]Fe(CO)2.

Authors: Joshua S Figueroa; Jonathan G Melnick; Gerard Parkin
Journal: Inorg Chem Date: 2006-09-04 Impact factor: 5.165

4. Synthesis and structural characterization of [kappa3-B,S,S-B(mimR)3]Ir(CO)(PPh3)H (R = Bu(t), Ph) and [kappa4-B(mim(Bu(t))3]M(PPh3)Cl (M = Rh, Ir): analysis of the bonding in metal borane compounds.

Authors: Victoria K Landry; Jonathan G Melnick; Daniela Buccella; Keliang Pang; Joseph C Ulichny; Gerard Parkin
Journal: Inorg Chem Date: 2006-03-20 Impact factor: 5.165

5. Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds.

Authors: Mark P Mehn; Steven D Brown; David M Jenkins; Jonas C Peters; Lawrence Que
Journal: Inorg Chem Date: 2006-09-04 Impact factor: 5.165

6. On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species.

Authors: Michael P Hendrich; William Gunderson; Rachel K Behan; Michael T Green; Mark P Mehn; Theodore A Betley; Connie C Lu; Jonas C Peters
Journal: Proc Natl Acad Sci U S A Date: 2006-11-07 Impact factor: 11.205

Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.

1. Nitrogenase MoFe-protein at 1.16 A resolution: a central ligand in the FeMo-cofactor.

2. Electron-precise coordination modes of boron-centered ligands.

3. Reactivity of the metal-->BX3 dative sigma-bond: 1,2-addition reactions of the Fe-->BX3 moiety of the ferraboratrane complex [kappa4-B(mimBu t)3]Fe(CO)2.

4. Synthesis and structural characterization of [kappa3-B,S,S-B(mimR)3]Ir(CO)(PPh3)H (R = Bu(t), Ph) and [kappa4-B(mim(Bu(t))3]M(PPh3)Cl (M = Rh, Ir): analysis of the bonding in metal borane compounds.

5. Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds.

6. On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIV[triple bond]N, and related species.

Review 7. Mid- to high-valent imido and nitrido complexes of iron.

8. Synthesis and characterization of manganese and iron complexes supported by multidentate [N2P2] ligands.

9. Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms.

10. Thermodynamics of hydrogen atom transfer to a high-valent iron imido complex.

1. High-Spin Iron Imido Complexes Competent for C-H Bond Amination.

2. Characterization of Iron-Imido Species Relevant for N-Group Transfer Chemistry.

Review 3. Catalytic N₂-to-NH₃ (or -N₂H₄) Conversion by Well-Defined Molecular Coordination Complexes.

4. N2 functionalization at iron metallaboratranes.

5. Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.

6. CO Reduction to CH₃OSiMe₃: Electrophile-Promoted Hydride Migration at a Single Fe Site.

7. Evaluating molecular cobalt complexes for the conversion of N2 to NH3.

8. Characterization of an Fe≡N-NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3.

9. Conversion of Fe-NH2 to Fe-N2 with release of NH3.

10. A Triad of Highly Reduced, Linear Iron Nitrosyl Complexes: {FeNO}(8-10).

Review 7. Mid- to high-valent imido and nitrido complexes of iron.

Review 3. Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes.

Review 3. Catalytic N₂-to-NH₃ (or -N₂H₄) Conversion by Well-Defined Molecular Coordination Complexes.