Literature DB >> 14532684

2-[(2-hydroxy-4-nitrophenyl)aminomethylene]cyclohexa-3,5-dien-1(2H)-one.

Cem Cüneyt Ersanli1, Cigdem Albayrak, Mustafa Odabaşoglu, Ahmet Erdönmez.   

Abstract

The title compound, C(13)H(10)N(2)O(4), adopts the keto-amine tautomeric form and displays an intramolecular N-H...O [N...O = 2.579 (2) A] and three intermolecular O-H...O [O...O = 2.561 (2) A] and C-H...O [C...O = 3.274 (2) and 3.318 (2) A] hydrogen bonds. The keto-amine structure is favoured by through-molecule conjugation between the hydroxy O atom and imine N atom. The dihedral angle between the planes of the two aromatic rings is 10.79 (4) degrees.

Entities:  

Year:  2003        PMID: 14532684     DOI: 10.1107/s0108270103018456

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  5 in total

1.  (Z)-6-[(5-Chloro-2-hydroxy-anilino)-methyl-ene]-4-methoxy-cyclo-hexa-2,4-dienone 0.25-hydrate.

Authors:  Arzu Ozek; Orhan Büyükgüngör; Ciğdem Albayrak; Mustafa Odabaşoğlu
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-04-25

2.  (Z)-6-[(5-Chloro-2-hydroxy-phenyl)-aminomethyl-ene]-2-ethoxy-cyclo-hexa-2,4-dienone.

Authors:  Arzu Ozek; Ciğdem Albayrak; Orhan Büyükgüngör
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-08-15

3.  (E)-2-[(2-Hydr-oxy-5-nitro-phen-yl)iminiometh-yl]phenolate.

Authors:  Yousef M Hijji; Belygona Barare; Ray J Butcher; Jerry P Jasinski
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-02-11

4.  (E)-2-[(2-Hydr-oxy-5-nitro-phen-yl)iminiometh-yl]-4-nitro-phenolate.

Authors:  Yousef M Hijji; Belygona Barare; Ray J Butcher; Jerry P Jasinski
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-01-14

5.  3-Diethyl-amino-6-[(Z)-(4-hy-droxy-anilino)methyl-idene]cyclo-hexa-2,4-dienone.

Authors:  Erkan Soydemir; Orhan Büyükgüngör; Ciğdem Albayrak
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-11-13
  5 in total

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