Literature DB >> 3580537

Selection of molecular chirality by extremely weak chiral interactions under far-from-equilibrium conditions.

D K Kondepudi.   

Abstract

A general formalism for chiral symmetry breaking in far-from-equilibrium chemical systems is presented. It is pointed out that slow passage through the transition point makes the system sensitive to very weak, but systematic, chiral influences. The general implications of this process for the origin of biomolecular chirality is discussed.

Mesh:

Year:  1987        PMID: 3580537     DOI: 10.1016/0303-2647(87)90022-0

Source DB:  PubMed          Journal:  Biosystems        ISSN: 0303-2647            Impact factor:   1.973


  11 in total

1.  Parity violation energy of biomolecules--I: polypeptides.

Authors:  Francesco Faglioni; Alessio Passalacqua; Paolo Lazzeretti
Journal:  Orig Life Evol Biosph       Date:  2005-10       Impact factor: 1.950

Review 2.  The origin and amplification of biomolecular chirality.

Authors:  W A Bonner
Journal:  Orig Life Evol Biosph       Date:  1991       Impact factor: 1.950

3.  Evaluation of coupled perturbed and density functional methods of computing the parity-violating energy difference between enantiomers.

Authors:  A J MacDermott; G O Hyde; A J Cohen
Journal:  Orig Life Evol Biosph       Date:  2009-03-17       Impact factor: 1.950

4.  Enantioselective autocatalysis. IV. Implications for parity violation effects.

Authors:  W A Bonner
Journal:  Orig Life Evol Biosph       Date:  1996-02       Impact factor: 1.950

5.  Electroweak enantioselection and the origin of life.

Authors:  A J MacDermott
Journal:  Orig Life Evol Biosph       Date:  1995-06       Impact factor: 1.950

6.  Electroweak parity-violating energy shifts of amino acids: the "conformation problem".

Authors:  A J MacDermott; T Fu; G O Hyde; R Nakatsuka; A P Coleman
Journal:  Orig Life Evol Biosph       Date:  2009-03-17       Impact factor: 1.950

7.  Spontaneous chiral symmetry breaking in early molecular networks.

Authors:  Ran Kafri; Omer Markovitch; Doron Lancet
Journal:  Biol Direct       Date:  2010-05-27       Impact factor: 4.540

8.  What's left in asymmetry?

Authors:  Sherry Aw; Michael Levin
Journal:  Dev Dyn       Date:  2008-12       Impact factor: 3.780

9.  Parity-violating energy shifts of Murchison L-amino acids are consistent with an electroweak origin of meteorite L-enantiomeric excesses.

Authors:  A J MacDermott; T Fu; R Nakatsuka; A P Coleman; G O Hyde
Journal:  Orig Life Evol Biosph       Date:  2009-03-24       Impact factor: 1.950

Review 10.  Synthesis and Self-Assembly of Chiral Cylindrical Molecular Complexes: Functional Heterogeneous Liquid-Solid Materials Formed by Helicene Oligomers.

Authors:  Nozomi Saito; Masahiko Yamaguchi
Journal:  Molecules       Date:  2018-01-29       Impact factor: 4.411

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