| Literature DB >> 19308669 |
A J MacDermott1, T Fu, R Nakatsuka, A P Coleman, G O Hyde.
Abstract
In 1996, four alpha-methyl amino acids in the Murchison meteorite--L-isovaline, L-alpha-methylnorvaline, L-alpha-methyl-allo-isoleucine and L-alpha-methyl-isoleucine--were found to show significant enantiomeric excesses of the L form, ranging from 2% to 9%. Their deuterium to hydrogen isotope ratios suggest they formed in the pre-solar interstellar gas cloud rather than during a later aqueous processing phase on the asteroid parent body. In this paper we apply the techniques of the preceding two papers to compute the parity-violating energy shifts of these amino acids. We find that, in the gas phase, the PVESs of the neutral L forms of all four Murchison alpha-methyl amino acids are decisively negative, and there is even some correlation between the magnitudes of the L-excesses and the magnitudes of the PVESs--all of which is at least consistent with an electroweak origin of the Murchison enantiomeric excesses.Entities:
Mesh:
Substances:
Year: 2009 PMID: 19308669 DOI: 10.1007/s11084-009-9162-9
Source DB: PubMed Journal: Orig Life Evol Biosph ISSN: 0169-6149 Impact factor: 1.950