| Literature DB >> 34498848 |
Tanner C Jankins1, Raul Martin-Montero2, Phillippa Cooper1, Ruben Martin2,3, Keary M Engle1.
Abstract
A tungsten-catalyzed hydroboration of unactivated alkenes at distal C(sp3)-H bonds aided by native directing groups is described herein. The method is characterized by its simplicity, exquisite regio- and chemoselectivity, and wide substrate scope, offering a complementary site-selectivity pattern to other metal-catalyzed borylation reactions and chain-walking protocols.Entities:
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Year: 2021 PMID： 34498848 PMCID： PMC8958473 DOI： 10.1021/jacs.1c07162
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 16.383