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Literature DB >> 24476124

A mild Ni/Cu-catalyzed silylation via C-O cleavage.

Abstract

A Ni/Cu-catalyzed silylation of unactivated C-O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp(2))-O and even C(sp(3))-O bonds with similar efficiency.

Entities: Chemical

Year: 2014 PMID： 24476124 DOI： 10.1021/ja412107b

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

12 in total

1. Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future.

Authors: Louis-Charles Campeau; Nilay Hazari
Journal: Organometallics Date: 2018-11-27 Impact factor: 3.876

2. Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki-Miyaura Coupling with Benzylic Esters: A Computational Study.

Authors: Shuo-Qing Zhang; Buck L H Taylor; Chong-Lei Ji; Yuan Gao; Michael R Harris; Luke E Hanna; Elizabeth R Jarvo; K N Houk; Xin Hong
Journal: J Am Chem Soc Date: 2017-09-07 Impact factor: 15.419

3. Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization-Hydroboration of Unactivated Alkenes.

Authors: Tanner C Jankins; Raul Martin-Montero; Phillippa Cooper; Ruben Martin; Keary M Engle
Journal: J Am Chem Soc Date: 2021-09-09 Impact factor: 16.383

4. Transesterification of (hetero)aryl esters with phenols by an Earth-abundant metal catalyst.

Authors: Jianxia Chen; E Namila; Chaolumen Bai; Menghe Baiyin; Bao Agula; Yong-Sheng Bao
Journal: RSC Adv Date: 2018-07-13 Impact factor: 4.036

5. Silicon-Carbon Bond Formation via Nickel-Catalyzed Cross-Coupling of Silicon Nucleophiles with Unactivated Secondary and Tertiary Alkyl Electrophiles.

Authors: Crystal K Chu; Yufan Liang; Gregory C Fu
Journal: J Am Chem Soc Date: 2016-05-17 Impact factor: 15.419

6. Nickel-Catalyzed Borylation of Benzylic Ammonium Salts: Stereospecific Synthesis of Enantioenriched Benzylic Boronates.

Authors: Corey H Basch; Kelsey M Cobb; Mary P Watson
Journal: Org Lett Date: 2015-12-17 Impact factor: 6.005

7. Catalyst-controlled regiodivergent ring-opening C(sp³)-Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis.

Authors: Youhei Takeda; Kaoru Shibuta; Shohei Aoki; Norimitsu Tohnai; Satoshi Minakata
Journal: Chem Sci Date: 2019-07-31 Impact factor: 9.825